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化学进展 2008, Vol. 20 Issue (0708): 1037-1043 前一篇   后一篇

• 综述与评论 •

纯与掺杂CeO2的氧化还原性质及其催化领域的应用*

颜志鹏 崇明本 程党国** 陈丰秋 詹晓力   

  1. （浙江大学化学工程与生物工程学系 杭州 310027）
  • 收稿日期:2007-08-28 修回日期:2007-12-04 出版日期:2008-08-24 发布日期:2008-08-24
  • 通讯作者: 程党国
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Redox Properties of Pure and Doped Ceria and Their Application in Catalysis

Yan Zhipeng; Chong Mingben; Cheng Dangguo**; Chen Fengqiu; Zhan Xiaoli

  

  1. （Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China）
  • Received:2007-08-28 Revised:2007-12-04 Online:2008-08-24 Published:2008-08-24
  • Contact: Cheng Dangguo
概述了纯与掺杂CeO2氧化还原性质的研究状况及CeO2单独/主成分使用方式在催化领域中的应用。由于CeO2具有优异的储放氧性能，以及吸附气体和反应中间物能与几个Ce3+同时作用，其在氧化还原、合成气生产、有机合成和有机污染物降解等反应过程中呈现出良好的催化性能，而通过恰当的掺杂往往能使之得到进一步提高。最后，结合现状对其未来研究方向进行了展望。
关键词： CeO2, 氧化还原性质, 掺杂
The redox properties of pure and doped ceria and their application in catalysis are summarized. CeO2 plays an important role in catalyzing many reactions, including redox reactions, synthesis gas production, organic synthesis, catalytic abatement of organic pollutants and so on. This arises from the ability of ceria to store and release oxygen depending upon the conditions. Several Ce3+ interacting with reactants and intermediate retentions at the same time can make some contribution as well. Furthermore, the catalytic performance of ceria can be improved by doping other oxides. The research tendencies for promoting development of the applications of pure and doped ceria in catalysis are proposed.
Key words: ceria, redox properties, dope

中图分类号: 

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[ 1 ] Li M, Liu Z G, Hu Y H. J . Rare Earths , 2003 , 21 (6) : 654 —656
[ 2 ] Trovarelli A , Leitenburg C D , Boaro M. Catal . Today , 1999 ,50 : 353 —367
[ 3 ] Campbell C T , Peden C H F. Science , 2005 , 309 : 713 —714
[ 4 ] 王敏炜(Wang M W) , 魏文龙(Wei W L) , 罗来涛(Luo L T) .化工进展(Chemical Industry and Engineering Progress) , 2006 ,25(5) : 517 —519
[ 5 ] Mogensen M, Sammes N M, Tompsett G A. Solid State Ionic ,2000 , 129 : 63 —94
[ 6 ] 郑修成(Zheng X C) , 王向宇(Wang X Y) , 于丽华(Yu L H)等. 化学进展(Progress in Chemistry) , 2006 , 18 (2P3) : 159 —167
[ 7 ] Esch F , Fabris S , Zhou L. Science , 2005 , 309 : 752 —755
[ 8 ] Nolan M, Parker S C , Watson G W. Surf . Sci . , 2005 , 595 :223 —232
[ 9 ] Zaki M I , Hasan M A , Al2Sagheer F A , et al . Colloids and Surfaces A: Physicochem. Eng. Aspects , 2001 , 190 : 261 —267
[10] Qiu L M, Liu F , Zhao L Z , et al . Appl . Surf . Sci . , 2006 , 252 :4931 —4935
[11] Li R , Yabe S , Yamashita M, et al . Solid State Ionics , 2002 ,151 : 235 —241
[12] Etsell T H , Flengas S N. Chem. Rev. , 1970 , 70(3) : 339 —376
[13] Chavan S V , Patwe S J , Tyagi A K. J . Alloys. Comp. , 2003 ,360 : 189 —192
[14] Kang C H Y, Kusaba H , Yahiro H. Solid State Ionics , 2006 ,177 : 1799 —1802
[15] Dikmen S , Shuk P , Greenblatt M. Solid State Ionics , 1999 , 126 :89 —95
[16] Dikmen S , Shuk P , Greenblatt M. Solid State Ionics , 1998 , 112 :299 —307
[17] Dikmena S , Shuk P , Greenblatt M, et al . Solid State Ionics ,2002 , 4(5) : 585 —590
[18] Chavan S V , Mathews M D , Tyagi A K. Mater. Res. Bull . ,2005 , 40 : 1558 —1568
[19] Yoshimura M, Tani E , Sōmiya S. Solid State Ionics , 1981 , 3/4 :477 —481
[20] Wu L J , Wiesmann H J , Moodenbaugh A R. Phys. Rev. B ,2004 , 69 : art . No. 125415
[21] Inaba H , Nakajima T , Tagawa H. Solid State Ionics , 1998 , 106 :263 —268
[22] Hasan M A , Zaki M I , Pasupulety L. J . Phys. Chem. B , 2002 ,106(49) : 12747 —12756
[23] Kennedy E M, Noel W C. Appl . Catal . A , 1992 , 87(2) : 171 —183
[24] 徐法强(Xu F Q) , 沈师孔(Shen S K) , 薛锦珍(Xue J Z) . 分子催化(J . Mol . Catal . China) , 1993 , 7(4) : 311 —316
[25] Wilkes M F , Hayden P , Bhattacharya A K. J . Catal . , 2003 ,219 : 286 —294
[26] Shapovalov V , Metiu H. J . Catal . , 2007 , 245 (1) : 205 —214
[27] Zhang Y W, Si R , Liao C S , et al . J . Phys. chem. B , 2003 ,107(37) : 10159 —10167
[28] Setiabudi A , Chen J L , Mul G. Appl . Catal . B , 2004 , 51 :9 —19
[29] Atribak I , Such-Basáìez I , Bueno-López A. J . Catal . , 2007 ,250 : 75 —84
[30] Bueno-López A , Krishna K, Makkee M. J . Catal . , 2005 , 230 :237 —248
[31] Krishna K, Bueno-López A , Makkee M, et al . Appl . Catal . B ,2007 , 75 : 191 —202
[32] Sakata Y, Ponec V. Appl . Catal . A , 1998 , 166 : 173 —184
[33] Chong M B , Cheng D G, Liu L , et al . Catal . Lett . , 2007 , 114(3/4) : 198 —201
[34] Cheng D G, Chong M B , Chen F Q , et al . Catal . Lett . , 2008 ,120(1/2) : 82 —85
[35] 崇明本(Chong MB) , 刘璐(Liu L) , 程党国(Cheng D G) 等.浙江大学学报(工学版) (J . Zhejiang Univ. Sci . ) , in press
[36] 刘璐(Liu L) . 浙江大学硕士学位论文( Master Dissertation of Zhejiang University) , 2007
[37] Zhao S , Gorte R J . Appl . Catal . A , 2003 , 248 : 9 —18
[38] Zhao S , Gorte R J . Appl . Catal . A , 2004 , 277 : 129 —136
[39] Liu W, Flytzani-Stephanopoulos M. J . Catal . , 1995 , 153 (2) :304 —316
[40] Wilkes M F , Hayden P , Bhattacharya A K. J . Catal . , 2003 ,219 : 295 —304
[41] Kundakovic L , Flytzani-Stephanopoulos M. J . Catal . , 1998 , 179(1) : 203 —221
[42] Laosiripojana N , Assabumrungrat S. J . Power Sources , 2006 ,158 : 1348 —1357
[43] Laosiripojana N , Assabumrungrat S. Appl . Catal . B , 2005 , 60 :107 —116
[44] Ferrizz R M, Wong G S , Egami T. Langmuir , 2001 , 17 :2464 —2470
[45] Li C , Domen K, Maruya K, et al . J . Catal . , 1993 , 141 (2) :540 —547
[46] Hennings U , Reimert R. Appl . Catal . A , 2007 , 325 ( 1 ) :41 —49
[47] Assabumrungrata S , Laosiripojana N , Pavarajarn V , et al . J .Power Sources , 2005 , 139 : 55 —60
[48] Ramirez-Cabrera E , Laosiripojana N , Atkinson A. Catal . Today ,2003 , 78 : 433 —438
[49] Laosiripojana N , Assabumrungratb S. Chem. Eng. Sci . , 2006 ,61 : 2540 —2549
[50] Laosiripojana N , Assabumrungrat S. Appl . Catal . B , 2006 , 66 :29 —39
[51] Laosiripojana N , Assabumrungrat S , Charojrochkul S. Appl .Catal . A , 2007 , 327 : 180 —188
[52] Idriss H , Diagne C , Hindermann J P , et al . J . Catal . , 1995 ,155 : 219 —237
[53] Sato S , Takahashi R , Sodesawa T , et al . Catal . Commun. ,2003 , 4 : 77 —81.
[54] Sato S , Takahashi R , Sodesawa T , et al . J . Mol . Catal . A:Chemical , 2004 , 221 : 177 —183
[55] Igarashi A , Sato S , Takahashi R. Catal . Commun. , 2007 , 8 :807 —810
[56] Igarashi A , Ichikawa N , Sato S. Appl . Catal . A , 2006 , 300 :50 —57
[57] Ichikawa N , Sato S , Takahashi R , et al . J . Mol . Catal . A:Chemical , 2005 , 31 : 181 —189
[58] Ichikawa N , Sato S , Takahashi R. J . Catal . , 2006 , 239 :13 —22
[59] Akashi T , Sato S , Takahashi R , et al . Catal . Commun. , 2003 ,4 : 411 —416
[60] Nagashima O , Sato S , Takahashi R. Appl . Catal . A , 2006 ,312 : 175 —180
[61] Zaki1 M I , Hussein G A M, El-Ammawy H A , et al . J . Mol .Catal . , 1990 , 57(3) : 367 —378
[62] Kamimura Y, Sato S , Takahashi R. Appl . Catal . A , 2003 , 252 :399 —410
[63] Stubenrauch J , Brosha E , Vohs J M. Catal . Today , 1996 , 28 :431 —441
[64] Nagashima O , Sato S , Takahashi R , et al . J . Mol . Catal . A:Chemical , 2005 , 227 : 231 —239
[65] Velu S , Swamy C S. Appl . Catal . A , 1994 , 119(2) : 241 —252
[66] Grabowska H , Kaczmarczyk W, Wrzyszcz J , et al . Appl . Catal . ,1989 , 47(2) : 351 —355
[67] Rao V V , Chary K V R , Durgakumari V , et al . Appl . Catal . ,1990 , 61(1) : 89 —97
[68] Sato S , Koizumi K, Nozaki F. Appl . Catal . A , 1995 , 133 :L7 —LI0
[69] Kobune M, Sato S , Takahashi R. J . Mol . Catal . A: Chemical ,2008 , 279 (1) : 10 —19
[70] Sato S , Takahashi R , Sodesawa T , et al . J . Catal . , 1999 , 184 :180 —188
[71] Corma A , Atienzar P , García H , et al . Nature Mater. , 2004 , 3 :394 —397
[72] 李小忠(Li X Z) , 王连军(Wang L J ) , 赵铭(Zhao M) 等. 环境化学(Environmental Chemistry) , 2006 , 25(2) : 149 —153
[73] Coronado J M, Maira A J , Martínez-Arias A. et al . J .Photochem. Photobiol . A , 2002 , 150 : 213 —221
[74] Hernández-Alonso M D , Hungría A B , Martínez-Arias A , et al .Appl . Catal . B , 2004 , 50 : 167 —175
[75] Borker P , Salker A V. Mater. Chem. Phys. , 2007 , 103 :366 —370
[76] Matatov-Meytal Y I , Sheintuch M. Ind. Eng. Chem. Res. ,1998 , 37 : 309 —326
[77] Hoǒevar S , Kraˇsovec U O , Orel B , et al . Appl . Catal . B , 2000 ,28 : 113 —125
[78] Wang C H , Lin S S. Appl . Catal . A , 2004 , 268 : 227 —233
[79] Neri G, Pistone A , Milone C , et al . Appl . Catal . B , 2002 , 38 :321 —329
[80] Silvaa A M T , Castelo-Brancoa I M, Quinta-Ferreiraa R M, et al .Chem. Eng. Sci . , 2003 , 58 : 963 —970
[81] Gross M D , Vohs J Mand , Gorte R J . J . Mater. Chem. , 2007 ,17 : 3071 —3077
[82] Park S , Vohs J M, Gorte R J . Nature , 2000 , 404 ( 16 ) :265 —266
[83] Goodenough J B , Huang Y H. J . Power Sources , 2007 , 173 :1 —10
[84] Lin B , Sun W P , Xie K, et al . J . Alloys and Compounds , doi :10. 1016Pj . jallcom. 2007. 10. 063
[85] Hui S Q , Roller J , Yick S , et al . J . Power Sources , 2007 , 172 :493 —502
[86] Muthukkumaran K, Bokalawela R , Mathews T , et al . J . Mater.Sci . , 2007 , 42 : 7461 —7466
[87] Li M, Liu Z G, Hu Y H , et al . Colloids Surf . A Physicochem.Eng. Aspects , 2007 , 301 : 153 —157
[88] Ishida T , Iguchi F , Sato K, et al . Solid State Ionics , 2005 , 176 :2417 —2421
[89] Rambabum B , Ghosh S , Jena H. J . Mater. Sci . , 2006 , 41 :7530 —7536
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