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化学进展 2008, Vol. 20 Issue (05): 644-649 前一篇   后一篇

• 综述与评论 •

手性光学开关研究*

郭培志1,2** 刘鸣华3** 赵修松1,2   

  1. （1. 青岛大学纤维新材料与现代纺织实验室多功能材料研究所 青岛 266071； 2. 青岛大学化学化工与环境学院 青岛 266071； 3. 中国科学院化学研究所胶体、界面与化学热力学院重点实验室 北京 100080）

  • 收稿日期:2007-06-11 修回日期:2007-06-25 出版日期:2008-05-24 发布日期:2008-05-24
  • 通讯作者: 郭培志;刘鸣华
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Studies of Chiroptical Switch

Guo Peizhi1,2** Liu Minghua3** Zhao Xiusong1,2   

  1. (1. Institute of Multifunctional Materials, Laboratory of New Fibrous Materials and Moden Textile, Qingdao University, Qingdao 266071, China; 2. School of Chemistry, Chemical Engineering and Environment, Qingdao University, Qingdao 266071, China; 3. CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China)
  • Received:2007-06-11 Revised:2007-06-25 Online:2008-05-24 Published:2008-05-24
  • Contact: Guo Peizhi; Liu Minghua
手性是自然界的普遍现象，有关超分子手性的研究由于超分子体系中分子间非共价相互作用的可调性逐渐引起了人们的研究兴趣。本文综述了手性光学开关研究的最新进展，介绍了如何设计分子体系,由手性分子制备手性光学开关；基于超分子思想,介绍了由非手性分子参与形成的手性光学开关，并最终制备出完全由非手性分子组装得到的手性光学开关。
关键词： 超分子手性, 超分子组装体, 手性光学开关
Chirality can be observed on various levels in Nature and the research related to supramolecular chirality has been received increasing interest due to the tunability of the non-covalent intermolecular interactions in supramolecular systems. The recent progress in the studies of chiroptical switch is reviewed. Chioptical switch could be fabricated not only by chiral molecules, but also by the combination of chiral and achiral molecules. In some particular cases, chiroptical switch exclusively from achiral molecules has been realized.
Key words: supramolecular chirality, supramolecular assembly, chiroptical switch

中图分类号: 

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[ 1 ] Lough W J , Wainer I W. Chirality in Nature and Applied Science. Oxford : CRC Press , 2002
[ 2 ] Berova N , Nakanishi K, Woody R W. Circular Dichroism Principles and Applications , 2nd ed. New York : Wiley2VCH ,2000
[ 3 ] Ueshima R , Asami T. Nature , 2003 , 425 : 679 —679
[ 4 ] Nelson J C , Saven J G, Moore J S , et al . Science , 1997 , 277 :1793 —1796
[ 5 ] 周公度( Zhou G D) , 段连运(Duan L Y) . 结构化学基础(Fundamentals of Structural Chemistry) . 北京: 北京大学出版社(Beijing : Peking University Press) ,1995
[ 6 ] Mateos-Timoneda MA , Crego-Calama M, Reinhoudt D N. Chem.Soc. Rev. , 2004 , 33 : 363 —372
[ 7 ] Irie M ( ed. ) . Photochromism: Memories and Switches. Chem.Rev. , 2000 , 100 (special issue) : 1683 —1890
[ 8 ] Green MM, Park J , Sato T , et al . Angew. Chem. Int . Ed. ,1999 , 38 : 3138 —3154
[ 9 ] Yashima E , Maeda K, Nishimura T. Chem. Eur. J . , 2004 , 10 :42 —51
[10] Cheuk K, Lam J , Lai L , et al . Macromolecules , 2003 , 36 :9752 —9762
[11] Bellacchio E , Lauceri R , Gurrieri S , et al . J . Am. Chem. Soc. ,1998 , 120 : 12353 —12354
[12] Mizuno Y, Aida T , Yamaguchi K. J . Am. Chem. Soc. , 2000 ,122 : 5278 —5285
[13] Prins L J , de Jong F , Timmerman P , et al . Nature , 2000 , 408 :181 —184
[14] Terpin AJ , Ziegler M, Johnson D W, et al . Angew. Chem. Int .Ed. , 2001 , 40 : 157 —160
[15] Yashima E , Maeda K, Okamoto Y. Nature , 1999 , 399 : 449 —451
[16] Link D R , Natale G, Shao R , et al . Science , 1997 , 278 :1924 —1927
[17] Prins L J , Huskens J , de Jong F , et al . Nature , 1999 , 398 :498 —502
[18] Yuan J , Liu M. J . Am. Chem. Soc. , 2003 , 125 : 5051 —5056
[19] Huang X, Li C , Jiang S , et al . J . Am. Chem. Soc. , 2004 ,126 : 1322 —1323
[20] Zhang L , Lu Q , Liu M. J . Phys. Chem. B , 2003 , 107 : 2565 —2569
[21] Guo P , Liu M. Colloids &Surfaces A , 2006 , 284P285 : 70 —73
[22] Ribo J M, Crusats J , Sagues F , et al . Science , 2001 , 292 :2063 —2066
[23] Pawlik A , Kirstein S. J . Phys. Chem. B , 1997 , 101 : 5646 —5651
[24] Sans M Q , Belser P. Coordin. Chem. Rev. , 2002 , 229 : 59 —66
[25] Fujiki M. J . Organomet . Chem. , 2003 , 685 : 15 —34
[26] Feringa L B. Molecular Switches. Weinheim: Wiley-VCH , 2001
[27] Watanabe J , Okamoto S , Satoh K, et al . Macromolecules , 1996 ,29 : 7084 —7088
[28] Sakajiri K, Satoh K, Kawauchi S , et al . J . Mol . Struct . , 1999 ,476 : 1 —8
[29] Bouman M M, Meijer E W. Adv. Mater. , 1995 , 7 : 385 —387
[30] Ohira A , Okoshi K, Fujiki M, et al . Adv. Mater. , 2004 , 16 :1645 —1650
[31] Fujiki M. J . Am. Chem. Soc. , 2000 , 122 : 3336 —3343
[32] Borovkov V V , Hembury G. A , Inoue Y. Angew. Chem. Int .Ed. , 2003 , 42 : 5310 —5314
[33] Goto H , Yashima E. J . Am. Chem. Soc. , 2002 , 124 : 7943 —7949
[34] Feringa B L , Jager W F , de Lange B , et al . J . Am. Chem.Soc. , 1991 , 113 : 5468 —5470
[35] Delange B , Jager W F , Feringa B L. Mol . Cryst . Liq. Cryst . ,1992 , 216 : 397 —400
[36] Jager W F , Delange B , Feringa B L. Mol . Cryst . Liq. Cryst . ,1992 , 216 : 401 —406
[37] Jager W F , de Lang J C , de Lange B , et al . Angew. Chem. Int .Ed. , 1995 , 34 : 348 —350
[38] Ziegler M, Davis A V , Johnson D W, et al . Angew. Chem. ,Int . Ed. , 2003 , 42 : 665 —668
[39] Okamoto Y, Nakano T. Chem. Rev. , 1994 , 94 : 349 —372
[40] Fenniri H , Deng B , Ribbe A E. J . Am. Chem. Soc. , 2002 ,124 : 11064 —11072
[41] Nakashima H , Koe J R , Torimitsu K, et al . J . Am. Chem.Soc. , 2001 , 123 : 4847 —4848
[42] Napoli M, Nardis S , Paolesse R , et al . J . Am. Chem. Soc. ,2004 ; 126 : 5934 —5935
[43] Saito B , Egami H , Katsuki T. J . Am. Chem. Soc. , 2007 , 129 :1978 —1986
[44] Wender P A , Haustedt L O , LimJ , et al . J . Am. Chem. Soc. ,2006 , 128 : 6302 —6303
[45] Van As B A C , van Buijtenen J , Heise A , et al . J . Am. Chem.Soc. , 2005 , 127 : 9964 —9965
[46] Van Nostrum C F , Bosman A W, Gelinck G H , et al . J . Chem.Soc. Chem. Commun. , 1993 , 1120 —1122
[47] Schwartz D K, Viswanathan R , Zasadzinski J A N. Phys. Rev.Lett . , 1993 , 70 : 1267 —1270
[48] Berlepsch H V , Bottcher C , Quart A , et al . J . Phys. Chem. B ,2000 , 104 : 5255 —5262
[49] Verbiest T , van Elshocht S , Kauranen M, et al . Science , 1998 ,282 : 913 —915
[50] Lin W, Ma L , Wang Z. J . Am. Chem. Soc. , 1999 , 121 :11249 —11250
[51] Rmaile H H , Schlenoff J B. J . Am. Chem. Soc. , 2003 , 125 :6602 —6603
[52] Aoki T , Shinohara K, Kaneko T , et al . Macromolecules , 1996 ,29 : 4192 —4198
[53] Huang J , Egan V M, Guo H , et al . Adv. Mater. , 2003 , 15 :1158 —1161
[54] Barbera J , Iglesias R , Serrano J L , et al . J . Am. Chem. Soc. ,1998 , 120 : 2908 —2918
[55] Tabei J , Nomura R , Sanda F , et al . Macromolecules , 2004 , 37 :1175 —1179
[56] Su S , Takeishi M, Kuramoto N. Macromolecules , 2002 , 35 :5752 —5757
[57] Li J , Schuster G B , Cheon K, et al . J . Am. Chem. Soc. ,2000 , 122 : 2603 —2612
[58] Asakawa M, Brancato G, Fanti M, et al . J . Am. Chem. Soc. ,2002 , 124 : 2939 —2950
[59] Nakashima H , Fujiki M, Koe J R , et al . J . Am. Chem. Soc. ,2001 , 123 : 1963 —1969
[60] Birau M M, Wang Z. Tetrahedron Lett . , 2000 , 41 : 4025 —4028
[61] Pieraccini S , Gottarelli G, Labruto R , et al . Chem. Eur. J . ,2004 , 10 : 5632 —5639
[62] Wang Z , Todd E K, Meng X, et al . J . Am. Chem. Soc. , 2005 ,127 : 11552 —11553
[63] Harata K, Uedaira H. Bull . Chem. Soc. Jpn. , 1975 , 48 :375 —378
[64] Zhang X, Gramlich G, Wang X, et al . J . Am. Chem. Soc. ,2002 , 124 : 254 —263
[65] Murakami H , Kawabuchi A , Matsumoto R , et al . J . Am. Chem.Soc. , 2005 , 127 : 15891 —15899
[66] Ishikawa M, Maeda K, Yashima E. J . Am. Chem. Soc. , 2002 ,124 : 7448 —7458
[67] Zahn S , Canary J W. Angew. Chem. Int . Ed. , 1998 , 37 :305 —307
[68] Zahn S , Canary J W. Science , 2000 , 288 : 1404 —1407
[69] Jiang S , Liu M. Chem. Mater. , 2004 , 16 : 3985 —3987
[70] Suárez M, Branda N , Lehn J M, et al . Helv. Chim. Acta ,1998 , 81 : 1 —13
[71] RibóJ M, Crusats J , Sagués F , et al . Science , 2001 , 292 :2063 —2066
[72] Viswanathan R , Zasadzinski J A , Schwartz D K. Nature , 1994 ,368 : 440 —443
[73] Guo P , Liu M. Langmuir , 2005 , 21 : 3410 —3412
[74] Guo P , Zhang L , Liu M. Adv. Mater. , 2006 , 18 : 177 —180
[75] Liu Y, Liu M. Thin Solid Films , 2002 , 415 : 248 —252
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手性光学开关研究*