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化学进展 2008, Vol. 20 Issue (04): 558-564 前一篇   后一篇

• 综述与评论 •

全共轭型二茂铁基聚合物*

石建兵1 支俊格2 佟斌1 赵玮1 申进波1 董宇平1**   

  1. (1. 北京理工大学材料科学与工程学院 北京 100081;2. 北京理工大学理学院 北京 100081)
  • 收稿日期:2007-05-14 修回日期:2007-06-05 出版日期:2008-04-24 发布日期:2008-04-24
  • 通讯作者: 董宇平

Full-Conjugated Ferrocene-Based Polymers

Shi Jianbing1; Zhi Junge2; Tong Bin1; Zhao Wei1; Shen Jinbo1; Dong Yuping1**   

  1. (1. College of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China;
    2. College of Science, Beijing Institute of Technology, Beijing 100081, China)
  • Received:2007-05-14 Revised:2007-06-05 Online:2008-04-24 Published:2008-04-24
  • Contact: Dong Yuping
由于二茂铁独特的夹心结构使含二茂铁基聚合物具有独特的电、磁、催化以及氧化还原性能。全共轭型二茂铁基聚合物由于其特殊的π-π电子结构,使其在电学、光学等方面的表现出优越的性质。本文从3个方面(主链型、侧链型和超支化型)介绍了近年来含有二茂铁基团全共轭聚合物的合成及其性能方面的研究进展,讨论了聚合物的结构对溶解性、氧化还原性等方面的影响,并探讨了这一领域存在的问题及可能的发展方向。

This review focuses on the synthesis and properties of the special classe of full-conjugated ferrocenyl polymers with excellent properties, such as electrochemistry, redox, magnetism, catalysis, thermal-stability and so on. Due to their specialities of π-π electron structure, the full-conjugated ferrocenyl polymers have extensive applications in in optical, electronic and magnetic fields. The three types of polymers are described: full-conjugated main-chain ferrocenyl polymer, full-conjugated side-chain ferrocenyl polymer and full-conjugated hyperbranched ferrocenyl polymer. The influences of the polymer structures on solubility and redox behavior are discussed. Problems and possible prospects are also discussed.

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摘要

全共轭型二茂铁基聚合物*