联吡啶钌修饰电极固相电致化学发光*

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化学进展 ›› 2008, Vol. 20 ›› Issue (0203) : 362-367.

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陶颖,林志杰,陈晓梅,陈曦. 联吡啶钌修饰电极固相电致化学发光^[J]. 化学进展, 2008, 20(0203): 362-367 Tao Ying¹\|Lin Zhijie¹\|Chen Xiaomei¹\|Chen Xi^1,2. Solid-state Electrochemiluminescence on Tris(2,2'-bipyridine)ruthenium(II) Modified Electrode[J]. Progress in Chemistry*, 2008, 20(0203): 362-367

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联吡啶钌修饰电极固相电致化学发光^*

陶颖¹ 林志杰¹ 陈晓梅¹ 陈曦^1,2**

作者信息 +

Solid-state Electrochemiluminescence on Tris(2,2'-bipyridine)ruthenium(II) Modified Electrode

Tao Ying¹; Lin Zhijie¹; Chen Xiaomei¹; Chen Xi^1,2**

Author information +

文章历史 +

摘要

由于电致化学发光（ECL）的连续可测性、高灵敏度、稳定、方法简单，被广泛应用于分子生物学、药学、化学和环保等领域。而将可电化学再生的ECL试剂固定于电极表面, 可获得ECL传感器, 从而减少分析过程中试剂的消耗和简化实验装置。联吡啶钌及其衍生物在电极表面的固定化研究成为ECL研究的重要方向。本文综述了2004年以来联吡啶钌及其衍生物修饰电极的固相ECL的研究进展, 并简要介绍了各种固定方法及其相关的应用情况。

Abstract

Electrochemiluminescence (ECL) which has been widely used in biological, pharmic, chemical and environmental applications due to its continuance, sensitivity, reproducibility and relative easy to control. The ECL sensor can be assembled by immobilizing electrochemically reproducible ECL reagents on an electrode surface. This approach will reduce the reagents consuming and simplify the detection apparatus. Recently, the studies on the immobilization of tris(2,2'-bipyridine)ruthenium(II) [Ru(bpy)₃²⁺] and its derivations have becoming an attractive research field. This review summaries the solid-state ECL development of Ru(bpy)₃²⁺ and its derivations since 2004. The approaches for reagent immobilizations as well as the relative applications are also discussed.

关键词

固相电致化学发光 / 联吡啶钌 / 修饰电极

Key words

solid-state electrochemiluminescence / tris(2,2’-bipyridine)ruthenium(II) / modified electrodes

中图分类号： O657.3

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