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化学进展 2008, Vol. 20 Issue (0203): 326-338 前一篇   后一篇

• 综述与评论 •

超支化有机硅基聚合物*

张国彬1 范晓东1** 孔 杰1 刘郁杨1 解云川2   

  1. (1.西北工业大学理学院应用化学系 西安 710072; 2.西安交通大学理学院应用化学系 西安710049)
  • 收稿日期:2007-04-16 修回日期:2007-06-01 出版日期:2008-03-24 发布日期:2008-03-24
  • 通讯作者: 范晓东
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Hyperbranched Organosilicon Polymers

Zhang Guobin1; Fan Xiaodong1; Kong Jie1; Liu Yuyang1; Xie Yunchuan2   

  1. (1. Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710072, China; 2. Department of Applied Chemistry, School of Science, Xi'an Jiaotong University, Xi'an 710049, China )
  • Received:2007-04-16 Revised:2007-06-01 Online:2008-03-24 Published:2008-03-24
  • Contact: Fan Xiaodong
超支化有机硅基聚合物（HBOSP）是一类新型功能性半有机半无机聚合物，在催化剂载体、陶瓷前驱体、发光材料和耐热材料等领域都有非常广阔的应用前景。本文概述了近10年来利用ABx、A2-Bx或A2-B'Bx-1以及Bf-ABx型单体制备新型结构HBOSP的进展，以及对这类聚合物的分子量及其分布和支化度调控的研究进展；着重总结了近年来针对该类聚合物的端基功能化改性及其应用情况，并在此基础上展望了今后该类聚合物研究的发展趋势。
关键词： 超支化硅基聚合物, 分子量分布, 支化度, 端基改性
Hyperbranched organosilicon polymers (HBOSP), a new kind of functional semi-orgnic polymers are of great potential to be applied in catalysts carriers, ceramic precursors, electroluminescent polymers, heat-resistant elastomer etc. In this paper, new methods in recent 10 years for syntheses of HBOSP from new monomers, including ABx monomer, A2-Bx or A2-B'Bx-1 monomer pair and Bf-ABx monomers pair, are summarized. Particularly, the research progress on regulation of macromolecular weight and its distribution as well as degree of branching, are discussed. The emphasis is also put on their terminal functional modifications as well as corresponding applications. Finally, new research trends are reviewed based on the progress of HBOSP.
Key words: hyperbranched organosilicon polymers, molecular weight distribution, degree of branching, terminal modification

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摘要

超支化有机硅基聚合物*