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化学进展 2007, Vol. 19 Issue (9): 1413-1418 前一篇   后一篇

• 综述与评论 •

异丁烯二聚反应

徐泽辉1,2* 房鼎业2   

  1. 1.上海石油化工股份公司化工研究所 上海 200540; 2. 华东理工大学化学工程系 上海 200237

  • 收稿日期:2005-09-20 修回日期:2006-11-01 出版日期:2007-09-24 发布日期:2007-09-25
  • 通讯作者: 徐泽辉

Dimerization reaction of isobutene

Xu Zehui1,2* Fang Dingye2   

  1. 1. Chemical Research Institute, Shanghai Petrochemical Company Limited, Shanghai 200540, China; 2. Department of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

  • Received:2005-09-20 Revised:2006-11-01 Online:2007-09-24 Published:2007-09-25
  • Contact: Xu Zehui
由于甲基叔丁基醚(MTBE)对水源的污染,它作为汽油添加剂的应用受到环保限制,并对其生产和应用前景带来消极影响。MTBE经裂解、二聚和加氢生产异辛烷成为国外现有MTBE装置转产的主要途径。本文对异丁烯二聚催化剂、反应活性位、机理及动力学研究成果进行了综述,试图解释在异丁烯二聚时,加入的叔丁醇对二聚反应选择性提高的作用机理,为今后二聚反应的研究提供参考。
Because Methyl tert-butyl ether (MTBE) is soluble in water and has been occasionally found its way into ground water from leaking storage tanks, MTBE was environmentally limited as gasoline additive and its production and application prospects is negatively affected. Producing isooctane by MTBE decomposition, dimerization of isobutene(IB) and hydrogenation of diisobutene became the main way for the exiting MTBE units abroad to produce other products. The catalyst for IB dimerization, reactive site, reactive mechanism and dynamics research date was reviewed in this paper and try to explain the mechanism of selectivity enhancing by adding Tertiary butyl alcohol during IB dimerization and provide reference for the study of dimerization afterwards.

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摘要

异丁烯二聚反应