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化学进展 2007, Vol. 19 Issue (9): 1393-1399 前一篇   后一篇

• 综述与评论 •

电场敏感的智能性水凝胶*

尚婧 陈新** 邵正中   

  1. 聚合物分子工程教育部重点实验室 复旦大学高分子科学系 上海 200433
  • 收稿日期:2005-09-26 修回日期:2006-10-30 出版日期:2007-09-24 发布日期:2007-09-25
  • 通讯作者: 陈新
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The Electric-Field-Sensitive Hydrogels

Shang Jing;Chen Xin**;Shao Zhengzhong   

  1. Key Laboratory of Molecular Engineering of Polymers,Ministry of Education,Department of Macromolecular Science,Fudan University,Shanghai 200433,China
  • Received:2005-09-26 Revised:2006-10-30 Online:2007-09-24 Published:2007-09-25
  • Contact: Chen Xin
电场敏感水凝胶是一类在电刺激下可以溶胀、收缩或弯曲的智能性水凝胶，其主要特点是可以将电能转化为机械能。本文对近年来已见报道的电场敏感水凝胶的研究进行了较为详细的综述。同时，对电场敏感水凝胶的响应机理、影响水凝胶响应性的因素以及其在能量转换装置、人工肌肉等方面的应用也作了相应的介绍。
关键词： 环境敏感, 聚电解质, 渗透压, 离子, 弯曲
Electric-field-sensitive hydrogel is one kind of intelligent hydrogels that exhibits swelling, shrinking or bending behavior on the application of an electric field. The main advantage of such a kind of hydrogel is that it can transform electrical energy into mechanical energy. In this paper, the recent research on electric-field-sensitive hydrogels is reviewed, in which the preparation and deformation mechanism of hydrogels are introduced. It is generally thought that the deformation of the hydrogel in an electric field is due to the change of osmotic pressure based upon the voltage-induced motion of ions in the electrolyte solution and may be influenced by a number of factors, including pH, ionic strength of the bath solution, as well as the electric potential imposed across the hydrogels. At last, the applications of such an electric-field-sensitive hydrogel, for example, in the fields of energy transducing devices, artificial muscles, and controlled drug delivery system are also presented.
Key words: environment-sensitive, polyelectrolytes, osmotic pressure, ions, bending

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摘要

电场敏感的智能性水凝胶*