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化学进展 2007, Vol. 19 Issue (9): 1381-1392 前一篇   后一篇

• 综述与评论 •

荧光聚合物研究进展*

武照强1** 孟令芝2   

  1. 1. 中南民族大学化学与材料科学学院 催化材料科学湖北省重点实验室 武汉 430074;

    2. 武汉大学化学与分子科学学院 武汉 430072

  • 收稿日期:2006-10-23 修回日期:2007-01-22 出版日期:2007-09-24 发布日期:2007-09-25
  • 通讯作者: 武照强

Progress in Fluorescent Polymers

Wu Zhaoqiang1**; Meng Lingzhi2   

  1. 1. Key Laboratory of Catalysis and Materials Science of Hubei Province, College of Chemistry and Material Sciences, South-Central University for Nationalities, Wuhan 430074, China;
    2. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
  • Received:2006-10-23 Revised:2007-01-22 Online:2007-09-24 Published:2007-09-25
  • Contact: Wu Zhaoqiang
本文总结了近年来荧光聚合物的研究进展,主要介绍了荧光聚合物的分类:按其溶解性能可分为非水溶性、水溶性和两亲荧光聚合物三大类;荧光聚合物的合成:荧光化合物为引发剂、荧光化合物为链转移剂、荧光功能单体聚合、荧光化合物与聚合物的化学键合、非荧光功能单体聚合等五种制备荧光聚合物的设计合成方法;荧光聚合物的应用:荧光聚合物在荧光化学传感器、荧光分子温度计、荧光造影、药物载体、荧光探针等方面的应用研究。
During the past two decades, research on fluorescent polymers has attracted increasing interests because of their important application prospect in the fields of life science and medicine. The latest research progress in fluorescent polymers is summarized as follows.(1) Classification of fluorescent polymers.Although there are different methods to classify fluorescent polymers, according to its solubility, fluorescent polymers can be divided into three types which is hydrophobic, hydrophilic and amphiphilic, individually; (2) Five methods of design and synthesis of fluorescent polymers: fluorescent polymers can be synthesized by using fluorescent compounds as initiator, fluorescent compounds as chain transfer agents, polymerization of fluorescent functional monomer, chemical bonds between fluorescent compounds and polymers, polymerization of none fluorescent functional monomer; (3) Applications of fluorescent polymers: fluorescent polymers are functional macromolecules with important application prospect. Their applications in the fields of fluorescent chemosensor, fluorescent molecular thermometers, fluorescent imaging, drug delivery carriers and fluorescent probe are briefly introduced in this paper.

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[ 1 ] Martínez-Máìez R , Sancenón F. Chem. Rev. , 2003 , 103 (11) :4419 —4476
[ 2 ] Guo X, Lu J M, Li H , et al . J . Appl . Polym. Sci . , 2005 , 97 :2067 —2071
[ 3 ] Klok H A , Becker S , Schuch F , et al . Macromol . Chem. Phys. ,2002 , 203 (8) : 1106 —1113
[ 4 ] Campo L F , Rodembusch F S , Stefani V. J . Appl . Polym. Sci . ,2006 , 99 : 2109 —2116
[ 5 ] Campo L F , Corrêa D S , de Araùjo M A , et al . Macromol . Rapid Commun. , 2000 , 21(12) : 832 —836
[ 6 ] Teramoto A , Hiratsuka S , Nishijima Y. J . Polym. Sci . Pol .Phys. , 1967 , 5(1) : 37 —45
[ 7 ] Teramoto A , Morimoto M, Nishijima Y. J . Polym. Sci . Pol .Chem. , 1967 , 5(5) : 1021 —1032
[ 8 ] Nishijima Y, Teramoto A , Yamamoto M, et al . J . Polym. Sci .Pol . Phys. , 1967 , 5(1) : 23 —35
[ 9 ] Kimura I , Kagiyama M, Nomura S , et al . J . Polym. Sci . Pol .Phys. , 1969 , 7(4) : 709 —724
[10] Cagnoli R , Mucci A , Parenti F , et al . Polymer , 2006 , 47 :775 —784
[11] Huang H M, Wang K M, Tan W H , et al . Angew. Chem. Int .Ed. , 2004 , 43 : 5635 —5638
[12] Kwak G, Fujiki M, Sakaguchi T , et al . Macromolecules , 2006 ,39 : 319 —323
[13] Li C , Numata M, Takeuchi M, et al . Angew. Chem. Int . Ed ,2005 , 44(39) : 6371 —6374
[14] Disney M D , Zheng J , Swager T M, et al . J . Am. Chem. Soc. ,2004 , 126 (41) : 13343 —13346
[15] Costa T , Miguel M G, Lindman B , et al . J . Phys. Chem. B ,2005 , 109 (8) : 3243 —3251
[16] Itoh Y, Shirai H. Polym. Adv. Technol . , 2002 , 13 : 40 —45
[17] Nguyen C A , Allémannl E , Schwach G, et al . Eur. J . Pharm.Sci . , 2003 , 20 : 217 —222
[18] 叶宇(Ye Y) , 李子臣(Li Z C) , 唐廷基(Tang T J) 等. 化学学报(Acta Chimica Sinica) , 2002 , 60(5) : 931 —938
[19] Lu F Z , Meng J Q , Du F S , et al . Macromol . Chem. Phys. ,2005 , 206 : 513 —520
[20] Elce E , Dao J L , Volksen W, et al . Macromolecules , 1996 , 29(7) : 2686 —2688
[21] Ringsdorf H , Venzmer J , Winnik F M. Macromolecules , 1991 ,24(7) : 1678 —1686
[22] Engel P S , Wu H F , Smith W B. Org. Lett . , 2001 , 3 (20) :3145 —3148
[23] Chen M, Ghiggino K P , Mau A W H , et al . Macromolecules ,2005 , 38(8) : 3475 —3481
[24] Mertoglu M, Laschewsky A , Skrabania K, et al . Macromolecules ,2005 , 38(9) : 3601 —3614
[25] Bojinov V , Grabchev I. Dyes and Pigments , 2001 , 51 : 57 —61
[26] Grabchev I , Bojinov V. J . Photochem. Photobio. A: Chem. ,2001 , 139 : 157 —160
[27] Grabchev I , Betcheva R. J . Photochem. Photobio. A: Chem. ,2001 , 142 : 73 —78
[28] Grabchev I. Dyes and Pigments , 1998 , 38(4) : 219 —226
[29] Grabchev I , Bojinov V. Polym. Degrad. Stabil . , 2000 , 70 :147 —153
[30] Grabchev I , Bojinovb V , Petkovc C. Dyes and Pigments , 2001 ,51 : 1 —8
[31] Patrick L G F , Whiting A. Dyes and Pigments , 2002 , 55 : 123 —132
[32] Patrick L G F , Whiting A. Dyes and Pigments , 2002 , 52 : 137 —143
[33] Bojinov V , Panova I , Grabchev I. Polym. Degrad. Stabil . ,2005 , 88 : 420 —427
[34] Grabchev I , Chovelon J M. Polym. Adv. Technol . , 2003 , 14 :601 —608
[35] Grabchev I , Petkov C , Bojinov V. Macromol . Mater. Eng. ,2002 , 287 (12) : 904 —908
[36] Grabchev I , Philipova T. Angew. Mark. Chem. , 1999 , 269 :49 —53
[37] Bojinov V , Grabchev I. Polym. Degrad. Stabil . , 2004 , 85 :789 —797
[38] Relégio P , Martinho J M G, Farinha J P S. Macromolecules ,2005 , 38(26) : 10799 —10811
[39] Li N J , Lu J M, Yao S C , et al . Mater. Lett . , 2004 , 58 :3115 —3118
[40] Wang K C , Huang W, Xia P , et al . Reactive & Function Polym. , 2002 , 52 : 143 —148
[41] 夏平(Xia P) , 黄卫(Huang W) , 王康成(Wang K C) 等. 高分子学报(Acta Polymerica Sinica) , 2002 , 3 : 385 —388
[42] 王康成(Wang K C) , 黄卫(Huang W) , 夏平(Xia P) 等. 感光科学与光化学( Photographic Sci . Photochem. ) , 2002 , 20(3) : 161 —168
[43] Yamazaki A , Winnik F M, Cornelius R M, et al . Biochimica et Biophys. Acta-Biomembranes , 1999 , 1421 : 103 —115
[44] Polozova A , Yamazaki A , Brash J L , et al . Colloids Surf . A:Physicochem. Eng. Aspects , 1999 , 147 : 17 —25
[45] Yamazaki A , Song J M, Winnik F M, et al . Macromolecules ,1998 , 31 : 109 —115
[46] Julea E , Yamamotoa Y, Thouvenina M, et al . J . Control .Release , 2004 , 97 : 407 —419
[47] Sousa A T R E , Castanheira E M S , Fedorov A , et al . J . Phys.Chem. A , 1998 , 102 (32) : 6406 —6411
[48] Ravindranath R , Ajikumar P K, Muhammad H N B , et al .Chem. Mater. , 2006 , 18(5) : 1213 —1218
[49] Dinakaran K, Hsiao S M, Chou C H , et al . Macromolecules ,2005 , 38(25) : 10429 —10435
[50] Pilston R L , McCullough R D. Synthetic Met . , 2000 , 111/112 :433 —436
[51] Fahiman M, Birgersson J , Kaeriyama K, et al . Synthetic Met . ,1995 , 75 : 223 —228
[52] Ler’e-Porte J P , Moreau J J E , Serein-Spirau F , et al . J . Mater.Chem. , 2000 , 10 : 927 —932
[53] Yang R Q , Tian R Y, Hou Q , et al . Macromolecules , 2003 , 36(20) : 7453 —7460
[54] Gao S H , Wang W, Wang B H. Bioorg. Chem. , 2001 , 29 :308 —320
[55] Liao Y, Wang W, Wang B H. Bioorg. Chem. , 1999 , 27 : 463 —476
[56] Kubo H , Yoshioka N , Takeuchi T. Org. Lett . , 2005 , 7 (3) :359 —362
[57] Béra-Abérem M, Hoang-Anh H , Leclerc M. Tetrahedron , 2004 ,60 : 11169 —11173
[58] Leung M K P , Chow C F , Lam M H W. J . Mater. Chem. ,2001 , 11 : 2985 —2991
[59] Fan L J , Zhang Y, Wayne E. et al . Macromolecules , 2005 , 38(7) : 2844 —2849
[60] Tang Y L , He F , Yu M H , et al . Macromol . Rapid Commun. ,2006 , 27 : 389 —392
[61] Grabchev I , Qian X H , Bojinov V , et al . Polymer , 2002 , 43 :5731 —5736
[62] Aldridge S , Bresner C , Fallis I A , et al . Chem. Commun. ,2002 , 740 —741
[63] Kim T H , Swager T M. Angew. Chem. , 2003 , 115 : 4951 —4954
[64] Tong H , Wang L X, Jing X B , et al . Macromolecules , 2003 , 36(8) : 2584 —2586
[65] Kimura E , Sakonaka A. J . Am. Chem. Soc. , 1982 , 104 :4984 —4985
[66] Wu Z Q , Meng L Z , Li C , et al . J . Appl . Polym. Sci . , 2006 ,101(4) : 2371 —2376
[67] Fan C H , Plaxco K W, Heeger A J . J . Am. Chem. Soc. , 2002 ,124(20) : 5642 —5643
[68] Kanekiyo Y, Sato H , Tao H. Macromol . Rapid Commun. , 2005 ,26 : 1542 —1546
[69] 沈永行(Shen Y H) . 光学学报(Acta Optica Sinica) , 2000 ,20(1) : 83 —87
[70] Iwai K, Matsumura Y, Uchiyama S , et al . J . Mater. Chem. ,2005 , 15 : 2796 —2800
[71] Uchiyama S , Matsumura Y, de Silva A P , et al . Anal . Chem. ,2004 , 76(6) : 1793 —1798
[72] Uchiyama S , Matsumura Y, de Silva A P , et al . Anal . Chem. ,2003 , 75(21) : 5926 —5935
[73] Kim J M, Chang T E , Kang J H , et al . Angew. Chem. Int .Ed. , 2000 , 39 : 1780 —1782
[74] Tian H , Gan J A , Chen K C , et al . J . Mater. Chem. , 2002 ,12 : 1262 —1267
[75] Gan J N , Tian H , Chen K C. Polym. Adv. Technol . , 2002 , 13 :584 —588
[76] Lee C W, Yuan Z Z , Ahn K D , et al . Chem. Mater. , 2002 , 14(11) : 4572 —4575
[77] Moona B , Hoyea T R , Macosko C W. Polymer , 2002 , 43 :5501 —5509
[78] Schulze J S , Moona B , Lodge T P , et al . Macromolecules , 2001 ,34(2) : 200 —205
[79] Moona B , Hoye T R , Macosko C W. J . Polym. Sci . Pol .Chem. , 2000 , 38 : 2177 —2185
[80] Maliakal A , Greenaway H , Shaughnessy B , et al .Macromolecules , 2003 , 36(16) : 6075 —6080
[81] Tong Z , Ren B Y, Gao F. Polymer , 2001 , 42 : 143 —149
[82] Liaw D J , Huang C C , Wang T S. Polymer , 2002 , 43 : 6221 —6229
[83] Yusa S , Sakakibara A K, Yamamoto T , et al . Macromolecules ,2002 , 35(27) : 10182 —10188
[84] Haag R. Angew. Chem. Int . Ed. , 2004 , 43(3) : 278 —283
[85] Rèsler A , Vandermeulen G W M, Klok H A. Adv. Drug.Delivery Rev. , 2001 , 53(1) : 95 —108
[86] Torchilin V P. J . Control . Release , 2001 , 73(2) : 137 —172
[87] Gillies E R , Frechet J M J . Chem. Commun. , 2003 , 14 :1640 —1641
[88] Bellomo E G, Wyrsta M D , Pakstis L , et al . Nat . Mater. , 2004 ,3 (4) : 244 —248
[89] Schilli C M, Zhang M F , Rizzardo E , et al . Macromolecules ,2004 , 37(21) : 7861 —7866
[90] Napoli A , Valentini M, Tirelli N , et al . Nat . Mater. , 2004 , 3(3) : 183 —189
[91] Wu Z Q , Yang S , Liao W Y. Chinese J . Polym. Sci . , 2006 , 24(3) : 315 —321
[92] Jiang J Q , Tong X, Zhao Y. J . Am. Chem. Soc. , 2005 , 127(23) : 8290 —8291
[93] Jiang H L , Zhu K J . Biomaterials , 2002 , 23 : 2345 —2351
[94] Chen D , Jiang H L , Zhu K J . Eur. Polym. J . , 2005 , 41 :107 —113
[95] Fan J , Jiang H L , Chen D , et al . J . Appl . Polym. Sci . , 2006 ,100 : 1214 —1221
[96] Wu Z Q , Gong S L , Li C , et al . Eur. Polym. J . , 2005 , 41(9) :1985 —1992
[97] Wang W, Wan W, Stachiw A , et al . Biochemistry , 2005 , 44(32) : 10751 —10756.
[98] Kim I B , Dunkhorst A , Bunz U H F. Langmuir , 2005 , 21(17) :7985 —7989

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摘要

荧光聚合物研究进展*