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化学进展 2007, Vol. 19 Issue (11): 1633-1645   后一篇

• 特约稿 •

基元化学反应态态动力学研究*

戴东旭 杨学明**   

  1. (中国科学院大连化学物理研究所分子反应动力学国家重点实验室 大连 116023)
  • 收稿日期:2007-08-06 修回日期:1900-01-01 出版日期:2007-11-14 发布日期:2007-11-25
  • 通讯作者: 杨学明
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Recent Advances in State-state Chemical Reaction Dynamics

Dai Dongxu; Yang Xueming**   

  1. (State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China)
  • Received:2007-08-06 Revised:1900-01-01 Online:2007-11-14 Published:2007-11-25
  • Contact: Yang Xueming
化学反应动力学是化学领域最基础的学科之一，量子态分辨的基元化学反应动力学在最为基本的原子与分子的层次上对化学反应的机制提供深刻的理解。该领域的科学家们通过精心设计的实验和高精度的理论计算，使得态态反应动力学在过去的半个多世纪中取得了长足的进步，实验和理论的相互结合极大地促进了我们对化学反应本质的认识。本文从实验研究的角度，通过对实验技术的发展和对H2O光解离、H+H2、F+H2、Cl+H2、OH+H2、F+CH4等具体实例的态态动力学研究的简介，概况介绍了过去二十年里态态化学反应动力学研究所取得的进展，希望借此为读者提供对化学反应动力学领域的一个概略认识。
关键词： 化学反应, 反应动力学, 反应散射, 态态动力学
Chemical reaction dynamics is one of the fundamental research fields in chemistry. Quantum state resolved reaction dynamics has provided remarkable insights into the microscopic world of chemical reactions. By improving the experimental and theoretical methods, researchers have made great advances in state-to-state chemical dynamics in recent years. Strong interactions between theory and experiment have significantly enhanced our understandings of the chemical reactivity at the most fundamental level. This article reviews the progress made in the studies of some benchmark reaction systems over last ten years or so from an experimental point of view. We hope this review can provide a overview of the modern trends of chemical reaction dynamics at the state-to-state level.
Key words: chemical reaction, reaction dynamics, reactive scattering, state-to-state dynamics

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摘要

基元化学反应态态动力学研究*