English
新闻公告
More
化学进展 2007, Vol. 19 Issue (0708): 1147-1152 前一篇   后一篇

• 专题论坛 •

提高纤维素酶水解效率和降低水解成本*

苏东海1;孙君社2**   

  1. 1.北京电子科技职业学院 北京 100029;

    2. 中国农业大学食品科学与营养工程学院 北京 100083

  • 收稿日期:2007-05-28 修回日期:1900-01-01 出版日期:2007-08-17 发布日期:2007-08-17
  • 通讯作者: 孙君社

Enhancing Hydrolysis Efficiency of Cellulase and Reducing the Cost of Saccharification

Su Donghai1;Sun Junshe2**   

  1. 1.Beijing Electronic Science and Technology Vocational College,Beijing 100029,China;

    2.College of Food Science and Nutritional Engineering,China Agriculture University,Beijing 100083,China

  • Received:2007-05-28 Revised:1900-01-01 Online:2007-08-17 Published:2007-08-17
在我国可大量转化乙醇的是纤维质材料。纤维质材料转化乙醇的关键问题是纤维质转化为糖的过程,提高纤维素酶转化效率的方法有:(1)对纤维质材料进行预处理;(2) 研究纤维素酶的最适作用条件;(3)纤维素酶的重复利用;(4)合理的发酵工艺等。本文分析了纤维素的结构以及纤维素酶的作用方式,总结目前研究比较多的几种纤维质材料预处理方法,这几种方法对纤维素酶水解率的影响,并对研究纤维素酶的最适作用条件、纤维素酶的重复利用以及合理的发酵工艺进行了综述和分析。
In China the biomass that could be used to produce ethanol in large quantity is lignocellulose. The main challenges of ethanol production from lignocellulosic materials are the saccharification process by which lignocellulosic was transformed into sugar. The methods of enhancing hydrolysis efficiency of cellulase are as follows: (1) the lignocellulose is pretreated, (2) the optimal condition of cellulase hydrolysis is studied, (3) cellulase recycle use is conducted, (4) the reasonable fermentation process is adopted, and so on. The structures of cellulose and hydrolysis way of cellulase are analyzed. The progress in research on a few focused pretreatment and the effect of different pretreatment method on hydrolysis efficiency are mainly reviewed in this paper, at the same time the optimal condition of cellulase hydrolysis, cellulase recycle use, and the reasonable fermentation process are analyzed.

中图分类号: 

()

[ 1 ] 邓良伟(Deng L W) . 食品与发酵工业(Food and Fermentation Industries) , 1995 , 5 : 60 —72
[ 2 ] Wu Z , Lee Y Y. Biotechnology letters , 1997 , 19 : 977 —979
[ 3 ] Reese E G, Siu G H , Levinson H S. J . Bacteriol . , 1950 , 59 :485 —495
[ 4 ] Wood TM. Biotechnol . Bioeng. Symp. , 1975 , 5 : 111 —137
[ 5 ] 曲音波(Qu Y B) , 高培基(Gao P J) , 赵昕(Zhao X) 等. 纤维素科学与技术(Journal of Cellulose Science and Technology) ,1997 , 5(2) : 1 —9
[ 6 ] George T T. Advanced Biochemical Engineering , 1987 , 79 —101
[ 7 ] Schell DJ , Ruth M, Tucker M P. Appl . Microbiol . Biotechnol . ,1999 , 77 : 400 —407
[ 8 ] Lynd L R , Elander R T , Wyman C E. Appl . Biochem.Biotechnol . , 1996 , 57P58 : 741 —761
[ 9 ] Duff S J B , Murray W D. Bioresour. Technol . , 1996 , 55 : 1 —33
[10] Wright J D. Chem. Eng. Prog. , 1998 , 84(8) : 62 —74
[11] Gong C S , Chen C S , Che L F. Appl . Biochem. Biotechnol . ,1993 , 39/40 : 83 —88
[12] MesHartree M, Hogan C M, Saddler J N. Biotechnol . Bioeng. ,1987 , 30 : 558 —564
[13] Schell D , Nguyen Q , Tucker M, et al . Appl . Biochem.Biotechnol . , 1998 , 70 : 17 —24
[14] Wong K K Y, Deverell K F , Mackie K L , et al . Biotechnol .Bioeng. , 1988 , 31 : 447 —456
[15] Tatsumoto K, Baker J O , Tucker M P , et al . Appl . Biochem.Biotechnol . , 1988 , 18 : 159 —174
[16] Palonen H , Tjerneld F , Zacchi G, et al . J . Biotechnology , 2003 ,107 : 65 —72
[17] Shevchenko S M, Beatson R P , Saddler J N. Appl . Biochem.Biotechnol . , 1999 , 77 : 867 —876
[18] Van Walsum G P , Allen S G, Spencer M J , et al . Appl .Biochem. Biotechnol . , 1996 , 54/55 : 157 —170
[19] Sivers M V , Zacchi G. Bioresour. Technol . , 1995 , 51 : 43 —52
[20] Hinman N D , Schell D J , Riley C J , et al . Appl . Biochem.Biotechnol . , 1992 , 34/35 : 639 —649
[21] Brennan A H , Hoagland W, Schell D J . Biotechnol . Bioeng.Symp. , 1986 , 17 : 53 —70
[22] Converse A O , Kwarteng I K, Grethlein H E , et al . Appl .Biochem. Biotechnol . , 1989 , 20/21 : 63 —78
[23] Cahela D R , Lee Y Y, Chambers R P. Biotechnol . Bioeng. ,1983 , 25 : 3 —17
[24] Esteghlalian A , Hashimoto A G, Fenske J J , et al . Bioresour.Technol . , 1997 , 59 : 129 —136
[25] Hsu T A. Handbook on Bioethanol Production and Utilization.Applied Energy Technology Series (ed. Wyman C E) . Washington DC: Taylor &Francis , 1996. Chapter 10
[26] Garrote G, Dominguez H , Parajo J C. Journal of Chemical Technology and Biotechnology , 1999 , 74 (11) : 1101 —1109
[27] Siver M V , Zacchi G. Bioresour. Technol . , 1995 , 51 : 43 —52
[28] Vlasenko E Y, Ding H , Labavitch J M, et al . Bioresour.Technol . , 1997 , 59 : 109 —119
[29] Mes-Hartree M, Dale B E , Craig W K. Appl . Microbiol .Biotechnol . , 1988 , 29 : 462 —468
[30] Dale B E , Henk L L , Shiang M. Dev. Ind. Microbiol . , 1984 ,26 : 223 —233
[31] Chosdu R , Hilmy N , Erizal T B , et al . Phys. Chem. , 1993 ,42 : 695 —698
[32] Dale B E , Moreira M J . Biotechnol . Bioeng. Symp. , 1982 , 12 :31 —43
[33] Gollapalli L E , Dale B E , Rivers D M. Appl . Biochem.Biotechnol . , 2002 , 98/100 : 23 —35
[34] Mitchell D J , Grohmann K, Himmel M E , et al . Journal of Wood Science and Technology , 1990 , 10 (1) : 111 —121
[35] Dale B E , Leong C K, Pham T K, et al . Bioresource Technology ,1996 , 56 : 111 —116
[36] Moniruzzaman M, Dale B E , Hespell R B , et al . Appl .Biochem.Biotechnol . , 1997 , 67 : 113 —126
[37] Iyer P V , Wu Z W, Kim S B , et al . Appl . Biochem.Biotechnol . , 1996 , 57/58 : 121 —132
[38] Chang V S , Nagwani M, Holtzapple M T. Appl . Biochem.Biotechnol . , 1998 , 74 : 135 —159
[39] Chang V S , Burr B , Holtzapple M T. Appl . Biochem.Biotechnol . , 1997 , 63/65 : 3 —19
[40] 余兴莲(Yu X L) , 王 丽(Wang L) , 徐伟民(Xu W M) . 宁波大学学报(理工版) ( Journal of Ningbo University (Natural Science & Engineering Edition) ) , 2007 , 3 : 78 —82
[41] Ramos L P , Breuil C , Saddler J N. Enzyme Microb. Technol . ,1993 , 15 : 19 —25
[42] Emmel A , Mathias A L , Wypych F , et al . Biores. Technol . ,2003 , 86 : 105 —115
[43] Kong F , Engler C R , Soltes E J . Appl . Biochem. Biotechnol . ,1992 , 34/35 : 23 —35
[44] Eklund R , Galbe M, Zacchi G. Enzyme Microb. Technol . ,1990 , 12 : 225 —228
[45] Lee D , Yu A H C , Saddler J N. Biotechnol . Bioeng. , 1995 , 45 :328 —336
[46] 汪家政(Wang J Z) , 范明( Fan M) . 蛋白质技术手册(Handbook of Protein Technology ) . 北京: 科学出版社(Beinjing : Science Press) , 2001. 189 —210
[47] Sun Y, Cheng J Y. Biores. Technol . , 2002 , 83 : 1 —11
[48] Philippidis G P , Smith T K, Wyman C E. Biotechnol . Bioeng. ,1993 , 41 : 846 ———853

[1] 黄秉乾, 王立艳, 韦漩, 徐伟超, 孙振, 李庭刚. 低共熔溶剂预处理木质纤维素生产生物丁醇[J]. 化学进展, 2020, 32(12): 2034-2048.
[2] 蒋叶涛, 宋晓强, 孙勇*, 曾宪海, 唐兴, 林鹿*. 基于木质生物质分级利用的组分优先分离策略[J]. 化学进展, 2017, 29(10): 1273-1284.
[3] 袁正求, 龙金星, 张兴华, 夏莹, 王铁军, 马隆龙. 木质纤维素催化转化制备能源平台化合物[J]. 化学进展, 2016, 28(1): 103-110.
[4] 周妍, 赵雪冰, 刘德华. 非离子型表面活性剂对木质纤维素酶催化水解的影响及机理[J]. 化学进展, 2015, 27(11): 1555-1565.
[5] 饶路, 姜艳霞, 张斌伟, 游乐星, 李崭虹, 孙世刚. 乙醇电催化氧化[J]. 化学进展, 2014, 26(05): 727-736.
[6] 张家仁, 邓甜音, 刘海超*. 油脂和木质纤维素催化转化制备生物液体燃料[J]. 化学进展, 2013, 25(0203): 192-208.
[7] 张超, 郎林, 阴秀丽, 吴创之. 生物乙醇重整制氢反应器[J]. 化学进展, 2011, 23(4): 810-818.
[8] 柳彦从 胥月兵 陆江银. ZSM-5催化乙醇制低碳烯烃*[J]. 化学进展, 2010, 22(04): 754-759.
[9] 金强 张红漫 严立石 黄和. 生物质半纤维素稀酸水解反应*[J]. 化学进展, 2010, 22(04): 654-662.
[10] 袁同琦 何静 许凤 孙润仓. 生物质资源研究的新视野——木质纤维素全溶体系*[J]. 化学进展, 2010, 22(0203): 472-481.
[11] 刘传富,张爱萍,李维英,孙润仓. 纤维素在新型绿色溶剂离子液体中的溶解及其应用*[J]. 化学进展, 2009, 21(09): 1800-1806.
[12] 郑勇,轩小朋,许爱荣,郭蒙,王键吉. 室温离子液体溶解和分离木质纤维素*[J]. 化学进展, 2009, 21(09): 1807-1812.
[13] 冯汝明,刘仲能,顾荣,曹勇,谢在库. 环氧乙烷胺化制乙醇胺* [J]. 化学进展, 2009, 21(0708): 1636-1643.
[14] 张名佳,苏荣欣,齐崴,何志敏. 木质纤维素酶解糖化* [J]. 化学进展, 2009, 21(05): 1070-1074.
[15] 胡湛波,柴欣生,王景全,孔海南. 以制浆造纸产业为平台的生物炼制新模式[J]. 化学进展, 2008, 20(09): 1439-1446.