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化学进展 2007, Vol. 19 Issue (0708): 1122-1128 前一篇   后一篇

• 专题论坛 •

秸秆生产乙醇预处理关键技术*

孙君社1**；苏东海2；刘莉1   

  1. 1 中国农业大学食品科学与营养工程学院 北京 100083；
    2 北京电子科技职业学院 北京 100029
  • 收稿日期:2007-04-03 修回日期:1900-01-01 出版日期:2007-08-17 发布日期:2007-08-17
  • 通讯作者: 孙君社
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Pretreatment Technology of Corn Stover for Ethanol Production

Sun Junshe1**；Su Donghai2；Liu Li1   

  1. 1. China Agricultural University, Beijing, 100083, China;

    2. Beijing Electronic Science and Technology Vocational College, Beijing 100029, China

  • Received:2007-04-03 Revised:1900-01-01 Online:2007-08-17 Published:2007-08-17
乙醇是一种很有希望替代有限石油的燃料，目前燃料乙醇在我国部分省市得到应用。我国目前燃料乙醇生产的材料是陈化粮，但我国陈化粮可用于燃料酒精生产的量十分有限。真正可大量转化乙醇的是纤维质材料，纤维质材料转化乙醇的挑战性问题是产量偏低、成本偏高，纤维质材料的预处理是转化乙醇过程中的关键步骤，可明显提高纤维素的水解率，进而降低乙醇的生产成本。本文总结了纤维质材料预处理的各种方法，并对各种方法的优缺点进行了综述和分析，并对生物质预处理的前景进行了展望。
关键词： 秸秆预处理, 纤维素水解, 乙醇生产
Ethanol is a promising alternative energy source for the limited crude oil. Now Ethanol, which mainly comes from grains, has been used for fuel in a few provinces in China. However,the aged grain which is used to produce ethanol is limited. In China the biomass that could be used to produce ethanol in large quantity is lignocellulose. The main challenges of ethanol production from lignocellulosic materials are the situation of low yield and high cost of the hydrolysis process. Pretreatment, the critical technology during the transformation of lignocellulosic materials into ethanol, can significantly enhance the hydrolysis of cellulose, and then reduce the cost of ethanol production. Progress in research and development of pretreatment is mainly reviewed in this paper, and the advantages and disadvantages of different method of pretreatment are summarized and analyzed in detail. And the prospect of pretreatment is also discussed.
Key words: stalke pretreatments, cellulose hydrolysis, ethanol production

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[ 1 ] Kim S , Dale B E. Biomass and Bioenergy , 2004 , 26 : 361 —375
[ 2 ] Mielenz J R. Current Opinion in Microbiology , 2001 , 4 : 324 —329
[ 3 ] Liu C G, Wyman C E. Appl . Biochem. Biotech. , 2004 , 113/116 : 977 —987
[ 4 ] 李怀义(Li H Y) . 国家行政学院学报(Journal of China National School of Administration) , 2003 , 6 : 84 —87
[ 5 ] Campbell C J , Laherrere J H. Scientific American. , 1998 , 278(3) : 77 —83
[ 6 ] 邹水平(Zou S P) . 中国石化(China Petrochemical Industry) ,2003 , 4 : 6 —8
[ 7 ] Wyman C E. Annual Review of Energy Environment , 1999 , 24 :189 —226
[ 8 ] Grethlein H E , Converse A O. Bioresour. Technol . , 1991 , 36 :77 —82
[ 9 ] Torget R , Hsu T A. Appl . Biochem. Biotechnol . , 1994 , 45/46 :5 —23
[10] Fan L T , Lee Y H , Gharpuray M M. Adv. Biochem. Eng. ,1982 , 23 : 158 —187
[11] Palmqvist E , HahnH? gerdal B. Bioresour Technol . , 2000 , 74 :25 —33
[12] Wilson J J , Deschatelets L , Nishikawa N K. Appl . Microbiol .Biotechnol . , 1989 , 31 : 592 —596
[13] Wyman C E. Bioresour. Technol . , 1994 , 50 : 3 —16
[14] Mosier N , Wyman C E , Dale B , et al . Bioresource Technology ,2005 , 96 (6) : 673 —686
[15] Wooley R , Ruth M, Glassner D , et al . Biotechnology Progress ,1999 , 15 : 794 —803
[16] Lynd L R , Elander R T , Wyman C E. Appl . Biochem.Biotechnol . , 1996 , 57/58 : 741 —761
[17] McMillan J D. Enzymatic Conversion of Biomass for Fuels Production. Washington , DC: American Chemical Society , 1994
[18] Mansfield S H , Mooney C , Saddler J N. Biotechnol . Prog. ,1999 , 15 : 804 —816
[19] Chernoglazov V M, Ermolova O V , Klyosov A A. Enzyme Microb. Technol . , 1988 , 10 : 503 —507
[20] Converse A O , Ooshima H , Burns D S. Appl . Biochem.Biotechnol . , 1990 , 24/25 : 67 —73
[21] Cadoche L , Lopez G D. Wastes , 1989 , 30 : 153 —157
[22] Duff S J B , Murray W D. Bioresour. Technol . , 1996 , 55 : 1 —33
[23] Wright J D. Chem. Eng. Prog. , 1998 , 84 (8) : 62 —74
[24] Holtzapple M T , Humphrey A E , Taylor J D. Bioeng. , 1989 ,33 : 207 —210
[25] MesHartree M, Hogan C M, Saddler J N. Biotechnol . Bioeng. ,1987 , 30 : 558 —564
[26] Schell D , Nguyen Q , Tucker M, et al . Appl . Biochem.Biotechnol . , 1998 , 70 : 17 —24
[27] Wong K K Y, Deverell K F , Mackie K L , et al . Biotechnol .Bioeng. , 1988 , 31 : 447 —456
[28] Tatsumoto K, Baker J O , Tucker M P , et al . Appl . Biochem.Biotechnol . , 1988 , 18 : 159 —174
[29] Palonen H , Tjerneld F , Zacchi G, et al . J . Biotechnology , 2003 ,107 : 65 —72
[30] Shevchenko S M, Beatson R P , Saddler J N. Appl . Biochem.Biotechnol . , 1999 , 77 : 867 —876
[31] Van Walsum G P , Allen S G, Spencer M J , et al . Appl .Biochem. Biotechnol . , 1996 , 54/55 : 157 —170
[32] 熊　(Xiong J) , 叶君(Ye J) , 梁文芷(Liang W Z) 等. 华南理工大学学报(Journal of South China University of Technology) ,2000 , 28(3) : 84 —89
[33] Sivers M V , Zacchi G. Bioresour. Technol . , 1995 , 51 : 43 —52
[34] Hinman N D , Schell D J , Riley C J , et al . Appl . Biochem.Biotechnol . , 1992 , 34/35 : 639 —649
[35] Brennan A H , Hoagland W, Schell D J . Biotechnol . Bioeng.Symp. , 1986 , 17 : 53 —70
[36] Converse A O , Kwarteng I K, Grethlein H E , et al . Appl .Biochem. Biotechnol . , 1989 , 20/21 : 63 —78
[37] Cahela D R , Lee Y Y, Chambers R P. Biotechnol . Bioeng. ,1983 , 25 : 3 —17
[38] Esteghlalian A , Hashimoto A G, Fenske J J , et al . Bioresour.Technol . , 1997 , 59 : 129 —136
[39] Hsu T A. Handbook on Bioethanol Production and Utilization.Washington DC: Taylor &Francis , 1996. Chapter 10
[40] Garrote G, Dominguez H , Parajo J C. Journal of Chemical Technology and Biotechnology , 1999 , 74 (11) : 1101 —1109
[41] Mackie K L , Brownell H H , West K L , et al . Journal of Wood Chemistry Technology , 1985 , 5 (3) : 405 —425
[42] Millet M A , Baker A J , Scatter L D. Biotech. Bioeng. Symp. ,1976 , 6 : 125 —153
[43] Bjerre A B , Olesen A B , Fernqvist T. Biotechnol . Bioeng. ,1996 , 49 : 568 —577
[44] Vlasenko E Y, Ding H , Labavitch J M, et al . Bioresour.Technol . , 1997 , 59 : 109 —119
[45] Avellar B K, Glasser W G. Biomass and Bioenergy , 1998 , 14(3) : 205 —218
[46] Shevchenko S M, Beatson R P , Saddler J N. Appl . Biochem.Biotechnol . , 1999 , 77 : 867 —876
[47] Dale B E , Henk L L , Shiang M. Dev. Ind. Microbiol . , 1984 ,26 : 223 —233
[48] MesHartree M, Hogan C M, Saddler J N. Biotech. Bioeng. ,1987 , 30 : 558 —564
[49] Chosdu R , Hilmy N , Erizal T B , et al . Radiat . Phys. Chem. ,1993 , 42 : 695 —698
[50] Dale B E , Moreira MJ . Biotechnol . Bioeng. Symp. , 1982 , 12 :31 —43
[51] Gollapalli L E , Dale B E , Rivers D M. Appl . Biochem.Biotechnol . , 2002 , 98/100 : 23 —35
[52] Mitchell D J , Grohmann K, Himmel M E , et al . Journal of Wood Science and Technology , 1990 , 10 (1) : 111 —121
[53] Dale B E , Leong C K, Pham T K, et al . Bioresour. Technol . ,1996 , 56 : 111 —116
[54] Moniruzzaman M, Dale B E , Hespell R B , et al . Appl .Biochem. Biotechnol , 1997 , 67 : 113 —126
[55] Iyer P V , Wu Z W, Kim S B , et al . Appl . Biochem.Biotechnol . , 1996 , 57/58 : 121 —132
[56] Chang V S , Nagwani M, Holtzapple M T. Appl . Biochem.Biotechnol . , 1998 , 74 : 135 —159
[57] Chang V S , Burr B , Holtzapple M T. Appl . Biochem.Biotechnol . , 1997 , 63/65 : 3 —19
[58] Gandi J , Holtzapple M T , Ferrer A , et al . Animal Feed Science Journal , 1997 , 5 : 195 —211
[59] Azzam A M. J . Environ. Sci . Health B , 1989 , 24 (4) : 421 —433
[60] Bjerre A B , Olesen A B , Fernqvist T. Biotechnol . Bioeng. ,1996 , 49 : 568 —577
[61] Chum H L , Johnsoon D K, Black S. Biotechnol . Bioeng. , 1988 ,31 : 643 —649
[62] Thring R W, Chorent E , Overend R. Biomass , 1990 , 23 : 289 —305
[63] Akin D E , Rigsby L L , Sethuraman A , et al . Appl . Environ.Microbiol . , 1995 , 61 : 1591 —1598
[64] Kirk T K, Farrell R L. Annu. Rev. Microbiol . , 1987 , 41 :465 —505
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秸秆生产乙醇预处理关键技术*