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化学进展 2007, Vol. 19 Issue (06): 860-871 前一篇   后一篇

• 综述与评论 •

超疏水表面的研究进展*

赵宁;卢晓英;张晓艳;刘海云;谭帅霞;徐坚**   

  1. 中国科学院化学研究所 高分子物理与化学国家重点实验室 北京 100080
  • 收稿日期:2006-08-29 修回日期:2006-10-15 出版日期:2007-06-24 发布日期:2007-06-24
  • 通讯作者: 徐坚
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Progress in Superhydrophobic Surfaces

Zhao Ning;Lu Xiaoying;Zhang Xiaoyan;Liu Haiyun;Tan Shuaixia;Xu Jian**   

  1. State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100080, China
  • Received:2006-08-29 Revised:2006-10-15 Online:2007-06-24 Published:2007-06-24
表面浸润性是决定材料应用的一个重要性质，许多物理化学过程，如吸附、润滑、黏合、分散和摩擦等均与表面的浸润性密切相关。近年来，由于超疏水性表面在自清洁表面、微流体系统和生物相容性等方面的潜在应用，有关超疏水表面的研究引起了极大的关注。本文综述了超疏水表面研究的新进展：简单介绍了表面浸润性的表征手段和影响因素，归纳了超疏水表面的制备方法和相关的理论分析，并对超疏水表面研究的发展进行了展望。
关键词： 超疏水, 仿荷叶, 多级结构, 滞后, 接触角, 滚动角
Surface wetting behavior is of great importance in determining the application of various materials. Many physicochemical processes, such as adsorption, lubrication, adhesion, dispersion, friction and so forth are closely related with the wettability of materials. In the last decade, surface with ultra hydrophobicity have aroused much research interests owing to their potential application in self-cleaning coatings, microfluidics and biocompatible materials and so on. The recent progress in the study of superhydrophobic surface is summarized in three parts: In the first part the characterization and influences of wettability are briefly introduced; In the second part new development of superhydrophobic surfaces is summearized from both experimental and theoretical aspects; In the third part the prospect in this field is proposed.
Key words: superhydrophobic, lotus-leaf-like, hierarchical structure, hysteresis, contact angle, sliding angle

中图分类号: 

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[ 1 ] Young T. Phil . Trans. R. Lond. , 1805 , 95 : 65 —87
[ 2 ] Johnson R E , Dettre R H. Contact Angle , Wettability and Adhesion. Washington D C: American Chemical Society , 1964.112 —144
[ 3 ] De Gennes P G. Rev. Mod. Phys. , 1985 , 57 : 827 —863
[ 4 ] Dussan V E B , Chow R T P. J . Fluid Mech. , 1983 , 137 : 1 —29
[ 5 ] Wenzel R N. Ind. Eng. Chem. , 1936 , 28 : 988 —994
[ 6 ] Wenzel R N. J . Phys. Chem. , 1949 , 53 : 1466 —1470
[ 7 ] Cassie A B D , Baxter S. Trans. Faraday Soc. , 1944 , 40 : 546 —551
[ 8 ] Cassie A B D. Discuss. Faraday Soc. , 1948 , 3 : 11 —15
[ 9 ] Extrand C W. Langmuir , 2003 , 19 : 3793 —3796
[10] Heng J Y Y, Williams D R. Langmuir , 2006 , 22 : 6905 —6909
[11] Drelich J , Wilbur J L , Whitesides G M, et al . Langmuir , 1996 ,12 : 1913 —1922
[12] Extrand C W. J . Colloid Interface Sci . , 1998 , 207 : 11 —19
[13] Extrand C W. J . Colloid Interface Sci . , 2002 , 248 : 136 —142
[14] Yoshida N , Abe Y, Nakajima A , et al . J . Am. Chem. Soc. ,2006 , 128 : 743 —747
[15] Barthlott W, Neinhuis C. Planta , 1997 , 202 : 1 —7
[16] Wagner T , Neinhuis C , Barthlott W. Acta Zool . , 1996 , 3 :213 —225
[17] Gao X F , Jiang L. Nature , 2004 , 432 : 36 —36
[18] Lee W, Jin M K, Lee J K, et al . Langmuir , 2004 , 20 : 7665 —7669
[19] Gu Z Z , Wei H , Zhang R , et al . Appl . Phys. Lett . , 2005 , 86 :art . no. 201915
[20] Gu Z Z , Uetsuka H , Fujishima A , et al . Angew. Chem. Int .Ed. , 2003 , 42 : 894 —897
[21] Feng L , Li S H , Jiang L , et al . Adv. Mater. , 2002 , 14 :1857 —1860
[22] Nakajima A , Hashimoto K, Watanabe T. Monatshefte für Chemie ,2001 , 132 : 31 —41
[23] Zhao B , Moore J S , Beebe D. Science , 2001 , 291 : 1023 —1026
[24] Blossey R. Nat . Mater. , 2003 , 2 : 301 —306
[25] Sun T L , Feng L , Gao X F , Jiang L. Acc. Chem. Res. , 2005 ,38 : 644 —652
[26] Callies M, Quéré D. Soft Matter , 2005 , 1 : 55 —61
[27] Khorasani M T , Mirzadeh H. J . Appl . Polym. Sci . , 2004 , 91 :2042 —2047
[28] Cottin-Bizonne C , Barrat J L , Charlaix E , et al . Nat . Mater. ,2003 , 2 : 237 —240
[29] Nun E , Oles M. US2003 147 9322A1 , 2003
[30] Chen W, Fadeev A Y, McCarthy T J , et al . Langmuir , 1999 ,15 : 3395 —3399
[31] Teare D O H , Spanos C G, Ridley P. Chem. Mater. , 2002 , 14 :4566 —4571
[32] Youngblood J P , McCarthy T J . Macromolecules , 1999 , 32 :6800 —6806
[33] Öner D , McCarthy T J . Langmuir , 2000 , 16 : 7777 —7782
[34] Bico J , Marzolin C , Quéré D. Europhys. Lett . , 1999 , 47 :220 —226
[35] Jin M H , Feng L , Jiang L. Macromol . Rapid Commun. , 2005 ,26 : 1805 —1809
[36] Kim S H , KimJ H , Kang B K, Uhm H S. Langmuir , 2005 , 21 :12213 —12217
[37] Rao A V , Kulkarni M M, Seth T , et al . J . Non2Crystalline Solids , 2003 , 330 : 187 —195
[38] Shirtcliffe N J , McHale G, Perry C C. Langmuir , 2003 , 19 :5626 —5631
[39] Lau K K S , Bico J , Gleason K K. Nano Lett . , 2003 , 3 : 1701 —1705
[40] Li S H , Jiang L , Zhu D , et al . J . Phys. Chem. B , 2002 , 106 :9274 —9276
[41] Genzer J , Efimenko K. Science , 2000 , 290 : 2130 —2133
[42] Zhang J L , Li J , Han Y C. Macromol . Rapid Commun. , 2004 ,25 : 1105 —1108
[43] Erbil H Y, Demirel A L , Avci Y, Mert O. Science , 2003 , 299 :1377 —1380
[44] Lu X Y, Zhang C C , Han Y C. Macromol . Rapid Commun. ,2004 , 25 : 1606 —1610
[45] Li X, Chen G, Ma Y M. Polymer , 2006 , 47 : 506 —509
[46] Peng M, Li H , Wu L , et al . J . Appl . Polym. Sci . , 2005 , 98 :1358 —1363
[47] Xie Q D , Xu J , Han C C. Adv. Mater. , 2004 , 16 : 302 —305
[48] Zhao N , Xie Q D , Xu J , et al . Macromolecules , 2005 , 38 :8996 —8999
[49] Vogelaar L , Lammertink R G H , Wessling M. Langmuir , 2006 ,22 : 3125 —3130
[50] Feng L , Li S , Jiang L , et al . Angew. Chem. Int . Ed. , 2002 ,41 : 1221 —1223
[51] FengL , Yang Z L , Jiang L , et al . Angew. Chem. Int . Ed. ,2003 , 42 : 4217 —4220
[52] Feng L , Song Y, Jiang L , et al . Angew. Chem. Int . Ed. ,2003 , 42 : 800 —802
[53] Lee W, Jin M Y, Yoo W C , Lee J K. Langmuir , 2004 , 20 :7665 —7669
[54] Jiang L , Zhao Y, Zhai J . Angew. Chem. Int . Ed. , 2004 , 43 :4338 —4341
[55] Acatay K, Simsek E , Menceloglu YZ , et al . Angew. Chem. Int .Ed. , 2004 , 43 : 5210 —5213
[56] Ma M, Hill R M, Rutledge G C , et al . Langmuir , 2005 , 21 :5549 —5554
[57] Ma M, Mao Y, Rutledge GC , et al . Macromolecules , 2005 , 38 :9742 —9748
[58] Singh A , Steely L , Allcock H. Langmuir , 2005 , 21 : 11604 —11607
[59] Zhu M F , Zou W, Yu H , et al . J . Mater. Sci . , 2006 , 41 :3793 —3797
[60] Zhang X, Shi F , Li X, et al . J . Am. Chem. Soc. , 2004 , 126 :3064 —3065
[61] Zhao N , Shi F , Zhang X, et al . Langmuir , 2005 , 21 : 4713 —4716
[62] Shi F , Song Y, Zhang X, et al . Chem. Mater. , 2006 , 18 :1365 —1368
[63] Yu X, Wang Z Q , Zhang X. Adv. Mater. , 2005 , 17 : 1289 —1293
[64] Jiang Y G, Wang Z Q , Zhang X, et al . Langmuir , 2005 , 21 :1986 —1990
[65] Li M, Zhai J , Jiang L , et al . J . Phys. Chem. B , 2003 , 107 :9954 —9957
[66] Zhang X, Sato O , Fujishima A. Langmuir , 2004 , 20 : 6065 —6067
[67] Jisr R M, Rmaile H H , Schlenoff J B. Angew. Chem. Int . Ed. ,2005 , 44 : 782 —785
[68] Zhai L , Cebeci F , Cohen R E , et al . Nano Lett . , 2004 , 4 :1349 —1353
[69] Han J T , Zheng Y, Cho K, et al . J . Phys. Chem. B , 2005 ,109 : 20773 —20778
[70] Ji J , Fu J , Sheng J . Adv. Mater. , 2006 , 18 : 1441 —1444
[71] Qian B T , Shen Z Q. Langmuir , 2005 , 21 : 9007 —9009
[72] Guo Z , Zhou F , Hao J , Liu W M. J . Am. Chem. Soc. , 2005 ,127 : 15670 —15671
[73] Nakajima A , Hashimoto K, Fujishima A , et al . Langmuir , 2000 ,16 : 7044 —7047
[74] Nakajima A , Fujishima A , Watanabe T , et al . Adv. Mater. ,1999 , 16 : 1365 —1367
[75] Hozumi A , Takai O. Thin Solid Films , 1997 , 303 : 222 —225
[76] WuY, Sugimura H , Inoue Y, Takai O. Chem. Vap. Depos. ,2002 , 8 : 47 —50
[77] Tadanaga K, Morinaga J , Minami T. Chem. Mater. , 2000 , 12 :590 —592
[78] Tadanaga K, Morinaga J , Matsuda A. J . Sol2Gel Sci . Tech. ,2000 , 19 : 211 —214
[79] Yabu H , Shimomura M. Chem. Mater. , 2005 , 17 : 5231 —5234
[80] Fresnais J , Chapel J P , Poncin-Epaillard F. Surf . Coat .Technol . , 2006 , 200 : 5296 —5305
[81] Onda T , Shibuichi T , Satoh N , Tsujii K. Langmuir , 1996 , 12 :2125 —2127
[82] Yoshimitsu Z , Nakajima A , Watanabe T , et al . Langmuir , 2002 ,18 : 5818 —5822
[83] Lafuma A , Quéré D. Nat . Mater. , 2003 , 2 : 457 —460
[84] He B , Patankar N A , Lee J . Langmuir , 2003 , 19 : 4999 —5003
[85] Patankar N A. Langmuir , 2004 , 20 : 7097 —7102
[86] Patankar N A. Langmuir , 2003 , 19 : 1249 —1253
[87] Zhang X F , Tan S X, Xu J , et al . ChemPhysChem, 2006 , 7 :2067 —2070
[88] Dupuis A , Yeomans J M. Langmuir , 2005 , 21 : 2624 —2629
[89] Patankar N A. Langmuir , 2004 , 20 : 8209 —8213
[90] Nosonovsky M, Bhushan B. Microsyst . Technol . 2005 , 11 :535 —549
[91] Marmur A. Langmuir , 2004 , 20 : 3517 —3519
[92] 郑黎俊(Zheng L J ) , 乌学东(Wu X D) , 楼增(Lou Z) . 科学通报(Chin. Sci . Bull . ) , 2004 , 49 : 1691 —1699
[93] Gao L C , McCarthy T J . J . Am. Chem. Soc. , 2006 , 128 :9052 —9053
[94] Richard D , Quéré D. Europhys. Lett . , 2000 , 50 : 769 —775
[95] Shibuichi S , Onda T , Tsujii K, et al . J . Colloid Interface Sci . ,1998 , 208 : 287 —294
[96] Li H , Wang X, Jiang L , et al . Angew. Chem. Int . Ed. , 2001 ,40 : 1743 —1746
[97] Yabu H , Tanaka M, Shimomura M, et al . Langmuir , 2005 , 21 :3235 —3237
[98] Sun T L , Wang G J , JiangL , et al . J . Am. Chem. Soc. , 2003 ,125 : 14996 —14997
[99] Shiu J , Kuo C , Chen P , Mou C. Chem. Mater. , 2004 , 16 :561 —564
[100] Minko S , Muller M, Stamm M, et al . J . Am. Chem. Soc. ,2003 , 125 : 3896 —3900
[101] Sun T L , Wang G J , Jiang L , et al . Angew. Chem. Int . Ed. ,2004 , 43 : 357 —360
[102] Feng X, Feng L , Jiang L , et al . J . Am. Chem. Soc. , 2004 ,126 : 62 —63
[103] Wang S , Feng X, Yao J , Jiang L. Angew. Chem. Int . Ed. ,2006 , 45 : 1264 —1267
[104] Xia F , Feng L , Jiang L , et al . Adv. Mater. , 2006 , 18 : 432 —436
[105] Xu L , Chen W, Yan Y, et al . Angew. Chem. Int . Ed. , 2005 ,44 : 6009 —6012
[106] Kunst L , Samuels A L. Progress in Lipid Research , 2003 , 42 :53 —80
[107] Zhu Y, Zhang J , FengL , et al . Adv. Funct . Mater. , 2006 , 16 :568 —574
[108] Ming W, Wu D , de With G, et al . Nano Lett . , 2005 , 5 :2298 —2301
[109] 粟常红(Su C H) , 肖怡(Xiao Y) , 陈庆民(Cheng Q M) 等.无机化学学报(Chin. J . Inorg. Chem. ) , 2006 , 22 : 785 —788
[110] Xie Q D , Fan G Q , Zhao N , Xu J , et al . Adv. Mater. , 2004 ,16 : 1830 —1833
[111] Zhao N , Xu J , Xie Q , et al . Macromol . Rapid Commun. , 2005 ,26 : 1075 —1080
[112] Zhao N , Weng L , Xu J , et al . ChemPhysChem, 2006 , 7 : 824 —827
[113] Furstner R , Barthlott W, Walzel P , et al . Langmuir , 2005 , 21 :956 —961
[114] Sun M M, Luo C X, Chen Y, et al . Langmuir , 2005 , 21 :8978 —8981
[115] Wang C , Song Y, Xia X H , et al . Surface Science , 2006 , 600 :38 —42
[116] Wu X, Shi GQ. Nanotechnology , 2005 , 16 : 2056 —2060
[117] Wang S T , Feng L , Jiang L. Adv. Mater. , 2006 , 18 : 767 —770
[118] 钱柏太(Qian B T) , 沈自求(Shen Z Q) . 无机材料学报(J .Inorg. Mater. ) , 2006 , 21 : 747 —752
[119] Quéré D. Rep. Prog. Phys. , 2005 , 68 : 2495 —2532
[120] Wier K A , McCarthy T J . Langmuir , 2006 , 22 : 2433 —2436
[121] Marmur A. Langmuir , 2006 , 22 : 1400 —1402
[122] Extrand C W. Langmuir , 2006 , 22 : 1711 —1714
[123] Toes G J , van Muiswinkel K W, van Oeveren W, et al .Biomaterials , 2002 , 23 : 255 —262
[124] Yan H , Shiga H , Tsujii K, et al . Colloids and Surfaces A:Physicochem. Eng. Aspects , 2006 , 284/285 : 490 —494
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摘要

超疏水表面的研究进展*