在复合金属氧化物催化剂上丙烷直接氧化制丙烯酸*

杨秀娟,冯汝明,李丽,季伟捷,陈懿

化学进展 ›› 2007, Vol. 19 ›› Issue (05) : 643-650.

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化学进展 ›› 2007, Vol. 19 ›› Issue (05) : 643-650.
综述与评论

在复合金属氧化物催化剂上丙烷直接氧化制丙烯酸*

  • 杨秀娟; 冯汝明; 李丽; 季伟捷**; 陈懿
作者信息 +

Direct Oxidation of Propane to Acrylic Acid over MoVTe(Sb)Nbo Mixed Metal Oxide Catalysts

  • Yang Xiujuan;Feng Ruming;Li Li;Ji Weijie**; Chen Yi
Author information +
文章历史 +

摘要

丙烷直接氧化制丙烯酸是近年来催化氧化的热点课题。MoVTe(Sb)NbO复合金属氧化物催化剂是该反应最重要的一类催化剂。本文对该类催化剂的制备化学包括活化方式以及决定催化性能的主要活性相结构等方面的新近认识进行了系统评述;依据丙烷催化转化的反应途径,总结了有关催化剂元素组分在反应中的作用与功能的最新进展,调变催化剂的粒子尺寸与形貌、晶相组成与结构、表面酸碱性与氧化还原性是获得优良催化性能的关键因素。

Abstract

The direct oxidation of propane to acrylic acid has become a hot spot in catalytic oxidation of light alkanes in recent years. The MoVTe(Sb)NbO mixed metal oxide catalysts are the most important catalysts for this reaction. This article intends to review recent progresses in preparation methodologies and in understanding vital crystalline structures which are closely related to catalytic performance. The latest knowledge on the functions of the constituent main elements in the catalysts is summarized in terms of the reaction pathway of propane oxidation. It is recognized that modification of particle size and morphology, phase composition and structure, surface acidity and redox property of catalyst are critical to achieve superb catalyst performance and stability.

关键词

丙烷 / 直接氧化 / 复合金属氧化物催化剂 / 丙烯酸

Key words

propane / direct oxidation / mixed metal oxide catalysts / acrylic acid

引用本文

导出引用
杨秀娟,冯汝明,李丽,季伟捷,陈懿. 在复合金属氧化物催化剂上丙烷直接氧化制丙烯酸*[J]. 化学进展, 2007, 19(05): 643-650
Yang Xiujuan,Feng Ruming,Li Li,Ji Weijie**|Chen Yi. Direct Oxidation of Propane to Acrylic Acid over MoVTe(Sb)Nbo Mixed Metal Oxide Catalysts[J]. Progress in Chemistry, 2007, 19(05): 643-650
中图分类号: O643.36    O621.25+4   

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