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化学进展 2007, Vol. 19 Issue (04): 557-566 前一篇   后一篇

• 综述与评论 •

基于环糊精包结络合作用的大分子自组装*

郭明雨;江明**   

  1. 复旦大学高分子科学系 聚合物分子工程教育部重点实验室 上海 200433
  • 收稿日期:2006-08-21 修回日期:2006-10-21 出版日期:2007-04-24 发布日期:2007-04-24
  • 通讯作者: 江明
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Macromolecular Self-Assembly Based on Inclusion Complexation of Cyclodextrins

Guo Mingyu;Jiang Ming**   

  1. Key Laboratory for Molecular Engineering of Polymers, Ministry of Education and Department of Macromolecular Science , Fudan University, Shanghai 200433, China
  • Received:2006-08-21 Revised:2006-10-21 Online:2007-04-24 Published:2007-04-24
本文综述了基于环糊精包结络合作用的大分子自组装的研究进展，包括：（1) 线型、梳型、多臂星型或超支化聚合物与环糊精或其二聚体自组装形成多聚轮烷（分子项链）、多聚准轮烷、双多聚（准）轮烷、分子管、双分子管、超分子凝胶及其应用；（2）桥联环糊精与桥联客体分子自组装制备线型或超支化超分子聚合物；（3）温度、pH值、光及客体分子刺激响应智能体系； （4) 通过亲水性的环糊精线型均聚物与含金刚烷的疏水性聚合物之间的包结络合作用来制备高分子胶束及其空心球等。
关键词： 环糊精, 自组装, 包结络合
The recent research progresses in molecular self-assembly based on the inclusion complexation between cyclodextrins and various guest macromolecules have been reviewed : (1) polyrotaxanes (molecular necklace), polypseudorotaxanes, bis(polypseudorotaxane) or bis(polyrotaxane)s), molecular tubes or bis(molecular tube)s and supramolecular hydrogels induced by the complexation between cyclodextrins or their dimers and the polymer guests including linear, comb, multi-arms star or hyperbranched ones. (2) linear or hyperbranched supramolecular polymers prepared by the self-assembly of bridged cyclodextrins and their bridged guest molecules; (3) intelligent systems showing stimuli responsive properties including temperature, pH, light or guest molecules; (4) polymeric micelles and hollow spheres made in water by the inclusion between a linear hydrophilic polymer containing cyclodextrin as side groups and a linear hydrophobic polymer with adamantine appendants. In addition the potential applications of the resultant assemblies are discussed.
Key words: cyclodextrin, self-assembly, inclusion complexation

中图分类号: 

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