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化学进展 2007, Vol. 19 Issue (0203): 377-384 前一篇   后一篇

• 综述与评论 •

化学电离质谱在大气痕量物种原位测量中的应用

董璨1,2;侯可勇1,2;王俊德1;李海洋1*   

  1. 1. 中国科学院大连化学物理研究所 大连 116023；
    2. 中国科学院研究生院 北京 100049
  • 收稿日期:2006-04-18 修回日期:2006-06-19 出版日期:2007-03-24 发布日期:2007-03-24
  • 通讯作者: 李海洋
下载PDF ( 1895 ) 引用
导出 被引次数 ( 4 | 1 )

Application of Chemical Ionization Mass Spectrometry in in situ Measurement of Atmospheric Trace Species

Dong Can1,2;Hou Keyong1,2; Wang Junde1; Li Haiyang1*   

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023，China
  • Received:2006-04-18 Revised:2006-06-19 Online:2007-03-24 Published:2007-03-24
  • Contact: Li Haiyang
本文简要介绍了化学电离质谱的基本原理、仪器构成及特点，总结了化学电离质谱在大气痕量物种，如无机酸H2SO4、HNO3，自由基OH、HO2、RO2，可挥发性有机物和气溶胶等的原位测量中取得的成果，最后对其未来的发展趋势作了展望。
关键词： 化学电离质谱, 质子转移, 痕量物种, 原位测量
The fundamental principle and advantages of chemical ionization mass spectrometry (CIMS) are summarized. New progresses in in situ measurement of transient species is reviewed in detail. Those species include inorganic acid, such asH2SO4、HNO3,free radicals，such as OH、HO2、RO2，and volatile organic compounds. Furthermore, the developmental trend of CIMS is also discussed.
Key words: chemical ionization mass spectrometry, proton transfer, transient species, in situ measurement

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