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化学进展 2007, Vol. 19 Issue (0203): 313-324 前一篇   后一篇

• 综述与评论 •

卤化富勒烯的研究进展*

谢劲松;魏先文**   

  1. 安徽师范大学化学与材料科学学院 安徽省功能性分子固体重点实验室 芜湖 241000
  • 收稿日期:2006-06-19 修回日期:2006-08-07 出版日期:2007-03-24 发布日期:2007-03-24
  • 通讯作者: 魏先文
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The Recent Progress in Halogenated Fullerenes

Xie jinsong;Wei xianwen**   

  1. College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Normal University, Wuhu 241000,China
  • Received:2006-06-19 Revised:2006-08-07 Online:2007-03-24 Published:2007-03-24
  • Contact: Wei xianwen
自从C60被发现并能被大量制备以来，富勒烯化学已成为有机化学学科发展最快的领域之一。富勒烯通过多加成反应形成具有独特结构和性能的富勒烯卤化物和全氟烷基化物，为设计合成新型富勒烯基功能材料开辟了新方向。本文综述了近几年来在卤化富勒烯和全氟烷基化物富勒烯的合成方法、结构及性能方面取得的最新进展，重点介绍了氟化富勒烯及其衍生化反应，并展望了该领域今后的发展趋势。
关键词： 卤化富勒烯, 全氟烷基化富勒烯, 多加成, 衍生物
Since the discovery and large scale preparation of C60, the chemistry of fullerenes has become one of the most developing fields in organic chemistry. Halogenated and perfluoroalkylated fullerenes formed by multi-addition reaction of the fullerene spheroid possessed unique structures and properties, which pioneer one of the new directions for the design of new pattern promising materials based on fullerenes. This paper reviews the progress on the synthetic methods, structures and general properties of halogenated and perfluoroalkylated fullerenes in recent years. Fluorinated fullerene and their derivatives are especially described. The research trends for the future are proposed.
Key words: halogenated fullerenes, perfluoroalkylated fullerenes, multi-addition, derivatives

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摘要

卤化富勒烯的研究进展*