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化学进展 2007, Vol. 19 Issue (0203): 234-242 前一篇   后一篇

• 综述与评论 •

过渡金属硫化物催化剂催化加氢作用机理*

柴永明; 安高军;柳云骐;刘晨光**   

  1. 中国石油大学（华东）化学化工学院 中国石油天然气集团公司催化重点实验室 重质油国家重点实验室 东营 257061
  • 收稿日期:2006-03-30 修回日期:2006-10-11 出版日期:2007-03-24 发布日期:2007-03-24
  • 通讯作者: 刘晨光
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Transition Metal Sulfides Catalysts: Active Phase Structure and Mechanism of the Catalytic Reaction

Chai Yongming; An Gaojun;Liu Yunqi;Liu Chenguang**   

  1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation, College of Chemistry & Chemical Engineering,China University of Petroleum,Dongying 257061, China，
  • Received:2006-03-30 Revised:2006-10-11 Online:2007-03-24 Published:2007-03-24
  • Contact: Liu Chenguang
负载型过渡金属（Co、Mo、Ni、W）硫化物催化剂广泛应用于石油炼制催化加氢过程。为了开发高性能的加氢催化剂，过渡金属硫化物催化剂活性相的结构与加氢脱硫性能的关系一直以来是催化研究的热点之一。本文从过渡金属硫化物催化剂活性相的结构和反应物在催化剂表面活性位上的吸附-催化反应机理两个方面阐述了过渡金属硫化物催化剂的催化作用研究进展，并对过渡金属硫化物催化剂催化机理研究存在的争论和未来的研究方向进行了分析。
关键词： 过渡金属硫化物, 催化作用机理, 活性相, 加氢脱硫
The supported catalysts of transition metal sulfides (TMS) are applied in the petroleum refining processes extensively. In order to aid the development of catalysts for hydrodesulfurization (HDS), there has been a strong emphasis in the past on establishing fundamental relationships between the structure of the catalyst and the HDS activity. In this paper, the progress of research is reviewed from two aspects ： the structure of the active phase and the mechanism of adsorption-to-reaction of reactants on the active sites on the surface of TMS catalysts.The controversies in the research of catalysis of transition metal sulfides and the directions in the future are also propounded.
Key words: transition metal sulfides(TMS), catalysis mechanism, active phase, hydrodesulfurization(HDS)

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