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化学进展 2007, Vol. 19 Issue (01): 80-86 前一篇   后一篇

• 综述与评论 •

烷氧基硅烷溶胶-凝胶反应机理*

吴翠明;徐铜文**;杨伟华   

  1. 中国科学技术大学化学系,合肥230026
  • 收稿日期:2006-03-07 修回日期:2006-06-14 出版日期:2007-01-24 发布日期:2011-08-31
  • 通讯作者: 徐铜文

The Kinetics of Alkoxysilane Sol-Gel Process

Wu Cuiming;Xu Tongwen*;Yang Weihua   

  1. Department of Chemistry, University of Science and Technology of China, Hefei, 230026,China
  • Received:2006-03-07 Revised:2006-06-14 Online:2007-01-24 Published:2011-08-31
  • Contact: Xu Tongwen

利用烷氧基硅烷作为前驱体之一,进行溶胶-凝胶(sol-gel)反应制备无机氧化物和有机-无机杂化材料,近几十年来一直是一个研究热点。对烷氧基硅烷的sol-gel反应过程,特别是起始的水解和初步缩合过程已有较多的研究。本文综述了烷氧基硅烷的sol-gel反应机理研究的进展,并对未来发展提出了看法。

Over the past decades, the preparation of inorganic and organic-inorganic hybrid materials by the sol-gel process of alkoxysilanes has continued to be an active research area. Among such researches, there has been much exploration on the sol-gel reaction kinetics, especially the hydrolysis and initial condensation processes. In this paper, the development of the study on kinetic of alkoxysilane sol-gel reaction is reviewed and the kinetic research are briefly prospected.

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摘要

烷氧基硅烷溶胶-凝胶反应机理*