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化学进展 2007, Vol. 19 Issue (01): 173-185 前一篇   后一篇

• 综述与评论 •

ATR-FTIR光谱技术在聚合物膜研究中的应用

江艳;沈怡;武培怡**   

  1. 复旦大学高分子科学系 聚合物分子工程教育部重点实验室 上海 200433
  • 收稿日期:2006-05-17 修回日期:2006-07-02 出版日期:2007-01-24 发布日期:2011-08-31
  • 通讯作者: 武培怡

Application of ATR-FTIR Spectroscopy in Polymer Film Study

Jiang Yan;Shen Yi;Wu Peiyi**   

  1. The Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, China
  • Received:2006-05-17 Revised:2006-07-02 Online:2007-01-24 Published:2011-08-31
红外光谱是聚合物研究中常用的一种表征手段,而衰减全反射红外光谱(ATR-FTIR)更是由于在研究聚合物薄膜方面具有显著的优势而被广泛使用。逐层组装(layer-by-layer Assembly)技术是一种常用的组装聚合物超薄膜的方法,ATR-FTIR光谱技术的引入可以在获取膜组装过程中相应信息的同时有效地避免表征过程中对样品的损害。另一方面,ATR-FTIR方法与二维相关光谱技术(two-dimensional correlation spectroscopy, 2D correlation spectroscopy)相结合也是研究小分子(主要是水分子)在聚合物薄膜中的渗透行为的有效手段。本文对ATR-FTIR的基本原理和显著特点作了介绍,并以实例阐述该方法在逐层组装技术和水分子在薄膜内渗透行为研究两方面的应用。
Attenuated total reflectance (ATR) - FTIR is widely used due to its distinct advantage in studies of polymer films. Layer-by-layer assembly technique is a popular method to prepare ultrathin functional films. ATR-FTIR spectroscopy is introduced here to investigate the structural information of the multilayers without any damage to the samples. Besides, the diffusion process of small molecules, especially water molecules, in the polymer films may be studied carefully by means of ATR-FTIR spectroscopy accompanied by two-dimensional (2D) correlation spectroscopy as a useful tool. In this review, the principle and advantage of ATR-FTIR are briefly introduced and the applications of this effective method in the field of both layer-by-layer assembly technique and diffusion behavior of water molecules in polymer films are discussed.

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[ 1 ] Kretschmann E. Zeitschrift Fuer Physik , 1971 , 241 (4) : 313 —324
[ 2 ] Otto A , Falge H J , Sohler W. Physica Status Solidi B : Basic Research. 1974 , 63(1) :259 —269
[ 3 ] 李维真(Li W Z) , 武培怡(Wu P Y) , 李善君(Li S J ) , 杨玉良(Yang Y L) . 化学学报(Acta Chimica Sinica) , 2004 , 62(17) : 1641 —1644
[ 4 ] Murphy D , Depinho MN. J . Mem. Sci . , 1995 , 106(3) : 245 —257
[ 5 ] Harrick NJ . Internal Reflection Spectroscopy. NY: Wiley , 1967.30
[ 6 ] 姜恒(Jiang H) , 张晓彤(Zhang X T) , 刘立军(Liu L J) , 宫红(Gong H) . 分析仪器(Analytical Instrumentation) , 2003 , 2 :26 —28
[ 7 ] Decher G. Science , 1997 , 277 (5330) : 1232 —1237
[ 8 ] Decher G, Hong J D. Makromolekulare Chemie2Macromolecular Symposia , 1991 , 46 : 321 —327
[ 9 ] Hammond P T. Curr. Opin. Colloid Interface Sci . , 1999 , 4(6) :430 —442
[10] Bertrand P , Jonas A , Laschewsky A , Legras R. Macromolecular Rapid Communications , 2000 , 21(7) : 319 —348
[11] Marechal Y. Faraday Discussions , 1996 , 103 : 349 —361
[12] Marechal Y, Chamel A. J . Phys. Chem. , 1996 , 100 ( 20) :8551 —8555
[13] 吴瑾光(Wu J G) 主编. 傅里叶变换红外光谱技术及应用( 上卷) ( Technology and Application of Fourier Infrared Spectroscopy) . 北京: 科学技术文献出版社( Beijing :Scientific and Technical Documents Publishing House) , 1994. 140
[14] Mark S S , Sandhyarani N , Zhu C C , Campagnolo C , Batt C A.Langmuir , 2004 , 20(16) : 6808 —6817
[15] Homola J . Analytical and Bioanalytical Chemistry , 2003 , 377(3) : 528 —539
[16] Snyder R G, Strauss HL , Elliger C A. J . Phys. Chem. , 1982 ,86(26) : 5145 —5150
[17] Colthup N B , Daly L H , Wiberley S E. Introduction to Infrared and Raman Spectroscopy. NY: Academic Press , 1975
[18] Muller M, Kessler B , Lunkwitz K. J . Phys. Chem. B , 2003 ,107(32) : 8189 —8197
[19] Muller M. Biomacromolecules , 2001 , 2(1) : 262 —269
[20] Greenfield N , Fasman GD. Biochemistry , 1969 , 8(10) : 4108 —4116
[21] Muller M, Rieser T , Lunkwitz K, et al . Macromolecular Rapid Communications , 1998 , 19(7) : 333 —336
[22] Fringeli U P. Encyclopedia of Spectroscopy and Spectrometry.NY: Academic Press , 2000
[23] Nevskaya N A , Chirgadze Y N. Biopolymer , 1976 , 15 ( 4 ) :637 —648
[24] Ebert G, Kim Y H. Prog. Colloid Polym. Sci . , 1983 , 68 :113 —121
[25] Gergely C , Bahi S , Szalontai B , et al . Langmuir , 2004 , 20(13) :5575 —5582
[26] Byler D M, Susi H. Biopolymers , 1986 , 25(3) : 469 —487
[27] Schwinte P , Voegel J C , Picart C , et al . J . Phys. Chem. B ,2001 , 105 (47) : 11906 —11916
[28] Fieldson G T , Barbari T A. Polymer , 1993 , 34(6) : 1146 —1153
[29] Cotugno S , Larobina D , Mensitieri G, et al . Polymer , 2001 ,42(15) : 6431 —6438
[30] Kitano H , Ichikawa K, Fukuda M, et al . J . Colloid and Interface Sci . , 2001 , 242 (1) : 133 —140
[31] Noda I , Dowrey A E , Marcott C. Springer Proceedings in Physics , 1992 , 68 : 331 —334
[32] Noda I. Applied Spectroscopy , 1993 , 47(9) : 1329 —1336
[33] Noda I , Dowrey A E , Marcott C , et al . Applied Spectroscopy ,2000 , 54(7) : 236A —248A
[34] Noda I. Applied Spectroscopy , 2000 , 54(7) : 994 —999
[35] Wu P Y, Siesler H W. Chemical Physics Letters , 2003 , 374 (1/2) : 74 —78
[36] Shen Y, Wu P Y. J . Phys. Chem. B , 2003 , 107 (18) : 4224 —4226
[37] Brooksby P A , Fawcett W R. J . Phys. Chem. A , 2000 , 104(35) : 8307 —8314
[38] Paul S O , Ford T A. J . Crystallogr. Spectrosc. Res. , 1986 , 16(6) : 811 —821
[39] Paul J B , Provencal R A , Chapo C , et al . J . Phys. Chem. A ,1999 , 103 (16) : 2972 —2974
[40] Mizuno K, Mabuchi K, Miyagawa T , et al . J . Phys. Chem. A ,1997 , 101 (7) : 1366 —1369
[41] Kusanagi H , Yukawa S. Polymer , 1994 , 35(26) : 5637 —5640
[42] Pusch W, Burghoff H G. J . Appl . Polym. Sci . , 1979 , 23 (2) :473 —484
[43] Maeda Y, Kitano H. Spectrochemica Acta Part A: Molecular and Biomolecular Spectroscopy , 1995 , 51(14) : 2433 —2446
[44] Liu M J , Wu P Y, Ding Y F , et al . Macromolecules , 2002 , 35(14) : 5500 —5507
[45] Gupta V B , Drzal L T. J . Appl . Polym. Sci . , 1985 , 30 (11) :4467 —4493
[46] Aronhime M T , Gillham J K. J . Appl . Polym. Sci . , 1986 , 32(2) : 3589 —3626
[47] Johncock P , Tudgey G F. Br. Polymer. J . , 1986 , 18 ( 5) :292 —302
[48] Bellenger V , Verdue J . J . Mater. Sci . , 1989 , 24(1) : 63 —68

[1] 沈怡,彭云,武培怡,杨玉良. 二维相关振动光谱技术*[J]. 化学进展, 2005, 17(03): 499-513.