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化学进展 2006, Vol. 18 Issue (11): 1489-1497 前一篇   后一篇

• 综述与评论 •

手性二茂铁类配体在钯催化不对称反应中的应用*

刘振德;何煦昌**   

  1. 中国科学院上海生命科学研究院 上海药物研究所 上海 201203
  • 收稿日期:2005-12-14 修回日期:2006-06-01 出版日期:2006-11-24 发布日期:2006-11-25
  • 通讯作者: 何煦昌

The Application of Chiral Ferrocene Ligands in Palladium-Catalyzed Asymmetric Reactions

Zhende Liu;Xuchang He**   

  1. Shanghai  Institute of Meteria Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, Shanghai 201203, China
  • Received:2005-12-14 Revised:2006-06-01 Online:2006-11-24 Published:2006-11-25
  • Contact: Xuchang He
本文综述了近10 年来手性二茂铁类配体在钯催化不对称烯丙基取代反应,包括各种不同底物
的烯丙基烷基化、烯丙基胺基化和烯丙基磺酰化反应中的应用,并对其在不对称Claisen 重排、不对称Diels-Alder 反应、不对称Heck 反应、不对称羰基化、不对称氢化硅烷化和不对称碳碳键断裂等反应中的应用进行了综述,对部分反应的机理和该领域的发展前景进行了讨论。
This article briefly describes recent progress on palladium2catalyzed asymmetric allylic substitution reactions using chiral ferrocene ligands , including allylic alkylation , allylic amination and allylic sulfonylation. The Claisen rearrangement , Diels-Alder reaction , Heck reaction , asymmetric carbonylation , asymmetric hydrosilylation and C-C bond cleavage using chiral ferrocene ligands as catalyst are also reviewed. Some reaction mechanisms and perspective are discussed.

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