PDF(469 KB)
PDF(469 KB)
PDF(469 KB)
介孔氧化铝的研究进展
- 李传润;冯乙巳*;杨庆华
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The Research Progress of Mesoporous Alumina
- Chuanrun Li;Yisi Feng*;Qinghua Yang
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文章历史
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摘要
介孔氧化铝（MA）是比表面积超过350m2/g，孔径在2－50nm之间且孔径分布较窄的多孔氧化铝。这一新型氧化铝有望在催化剂及其它化学领域得到广泛应用，对材料科学及其应用有着重要意义。本文较全面地综述了近年来MA研究的最新进展，讨论了MA的各种合成路径和后处理方法，包括中性合成路径、阴离子合成路径和阳离子合成路径；结合XRD、氮吸附平衡等温线、TEM、27Al魔角旋转核磁共振等图表对MA的结构和表征方法进行了阐述；探讨了MA作为催化剂载体和作为吸附剂的应用研究状况，并对今后的研究方向进行了展望。
Abstract
Surface areas exceeding 350m2/g,pore sizes ranging from 2 to 50nm and with a narrow pore size distribution are characteristics of mesoporous alumina(MA). The new kind of lacunaris alumina shows a certain potential in catalysis, and appears very challenging for material application. Recent advances in the field of mesoporous alumina is reviewed with 64 references. Various synthesis approaches including neutral, anionic and cationic toutes, characterization of structure by various experimental techniques including XRD,N2-sorption isotherms,TEM and 27Al MAS NMR, and their applications in catalysis and adsorption are discussed in detail. The development trend in this field is also elucidated.
关键词
介孔氧化铝 / 合成 / 催化 / 吸附 {{custom_keyword}} /
Key words
mesoporous alumina / synthesis / catalysis / adsorption {{custom_keyword}} /
中图分类号：
O611.4 O614.31 O643.
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