PDF(356 KB)
PDF(356 KB)
PDF(356 KB)
钯复合膜的研究进展*
- 刘伟;张宝泉**;刘秀凤
作者信息
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Progress in Palladium Composite Membranes
- Wei Liu;Baoquan Zhang**;Xiufeng Liu
Author information
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文章历史
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摘要
钯复合膜具有很高的透氢选择性以及良好的化学和热稳定性，一直是膜技术领域的研究热点。本文综述了近年来在钯复合膜透氢机理、钯膜制备方法以及钯膜反应器等方面的研究进展；着重讨论了近3年来钯复合膜制备方法的新进展，包括超临界条件下制备钯复合膜的新技术等内容；总结了钯复合膜在脱氢、部分氧化以及耦合反应过程中应用的一些代表性工作，并对钯复合膜制备与应用的发展趋势进行了展望。
Abstract
Palladium composite membranes have attracted wide attention in membrane technology because of their excellent permeability,perm-selectivity,as well as chemical and thermal stabilities. This review discusses the principle and influence factors of hydrogen permeation,the membrane synthesis and the applications. The progress over the last three years in the preparation of Pd-based membranes,particularly, the novel preparation technique at supercritical conditions, is emphasized. The representative researches are summarized on applications of palladium composite membranes in dehydrogenation, partial oxidation and coupling reactions. The trend in preparation and applications of palladium composite membranes is outlooked.
关键词
透氢 / 钯复合膜 / 超临界流体 / 膜反应器 {{custom_keyword}} /
Key words
hydrogen permeation / palladium composite membranes / supercritical fluids / membrane reactors {{custom_keyword}} /
中图分类号：
O614.82
TB331
O484.1
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