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化学进展 2006, Vol. 18 Issue (11): 1468-1481 前一篇   后一篇

• 综述与评论 •

钯复合膜的研究进展*

刘伟;张宝泉**;刘秀凤   

  1. 天津大学化工学院 天津  300072
  • 收稿日期:2005-12-02 修回日期:2006-01-02 出版日期:2006-11-24 发布日期:2006-11-25
  • 通讯作者: 张宝泉
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Progress in Palladium Composite Membranes

Wei Liu;Baoquan Zhang**;Xiufeng Liu   

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • Received:2005-12-02 Revised:2006-01-02 Online:2006-11-24 Published:2006-11-25
  • Contact: Baoquan Zhang
钯复合膜具有很高的透氢选择性以及良好的化学和热稳定性，一直是膜技术领域的研究热点。本文综述了近年来在钯复合膜透氢机理、钯膜制备方法以及钯膜反应器等方面的研究进展；着重讨论了近3年来钯复合膜制备方法的新进展，包括超临界条件下制备钯复合膜的新技术等内容；总结了钯复合膜在脱氢、部分氧化以及耦合反应过程中应用的一些代表性工作，并对钯复合膜制备与应用的发展趋势进行了展望。
关键词： 透氢, 钯复合膜, 超临界流体, 膜反应器
Palladium composite membranes have attracted wide attention in membrane technology because of their excellent permeability,perm-selectivity,as well as chemical and thermal stabilities. This review discusses the principle and influence factors of hydrogen permeation,the membrane synthesis and the applications. The progress over the last three years in the preparation of Pd-based membranes,particularly, the novel preparation technique at supercritical conditions, is emphasized. The representative researches are summarized on applications of palladium composite membranes in dehydrogenation, partial oxidation and coupling reactions. The trend in preparation and applications of palladium composite membranes is outlooked.
Key words: hydrogen permeation, palladium composite membranes, supercritical fluids, membrane reactors

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钯复合膜的研究进展*