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化学进展 2006, Vol. 18 Issue (11): 1452-1459 前一篇   后一篇

• 综述与评论 •

染料敏化太阳能电池中TiO2光阳极研究进展*

赵勇;盛显良;翟锦**   

  1. 中国科学院化学研究所有机固体实验室 北京 100080
  • 收稿日期:2005-12-22 修回日期:2006-02-21 出版日期:2006-11-24 发布日期:2006-11-25
  • 通讯作者: 翟锦
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Development of TiO2 Photo-Anodes in Dye-Sensitized Solar Cells

Yong Zhao;Xianliang Sheng;Jin Zhai**   

  1. Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China
  • Received:2005-12-22 Revised:2006-02-21 Online:2006-11-24 Published:2006-11-25
  • Contact: Jin Zhai
本文介绍了染料敏化太阳能电池中TiO2光阳极的研究与应用现状。对TiO2光阳极常用的制备方法进行了综述，详细地讨论了复合核壳结构、掺杂电极、优化材料以及多级结构等一系列新材料的引入和结构改进所引起的电池光电性能的提高。文章指出获得具有好的光收集效率、快速的电荷传输以及优越的抑制电荷复合性能的多孔膜将是未来TiO2光阳极研究的方向。
关键词： 纳米晶TiO2光阳极, 核壳结构, 掺杂电极, 材料优化, 多级结构
The development and application of TiO2 photo-anodes in dye-sensitized solar cells (DSSCs) are reviewed. The preparation methods for TiO2 photo-anodes are summarized. Improvements of the photo-electric characteristics induced by introduction of a series of advanced materials and structure, such as composite core-shell structure, doped TiO2 electrodes, optimized materials and hierarchical structures，are discussed in detail. Fabricating the TiO2 porous films with excellent light harvesting, quick charge transport and efficient suppression of charge recombination is the purpose of further development.
Key words: nano-crystalline TiO2 photo-anodes, core-shell structure, doped electrodes, optimization of materials, hierarchical structure

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[ 1 ] O’Regan B , Grätzel M. Nature , 1991 , 353 (6346) : 737 —740
[ 2 ] Hagfeldt A , Grätzel M. Accounts Chem. Res. , 2000 , 33 (5) :269 —277
[ 3 ] Grätzel M. J . Photochem. Photobiol . A: Chem. , 2004 , 164 :3 —14
[ 4 ] Kumara G R A , Konno A , Shiratsuchi K, Tsukahara J ,Tennakone K. Chem. Mater. , 2002 , 14 (3) : 954 —955
[ 5 ] Tan S X, Zhai J , Xue B , Wan M X, Meng Q B , Li Y L , Jiang L , Zhu D B. Langmuir , 2004 , 20(7) : 2934 —2937
[ 6 ] Tan S X, Zhai J , Wan M X, Meng Q B , Li Y L , Jiang L , Zhu D B. J . Phys. Chem. B , 2004 , 108 (48) : 18693 —18697
[ 7 ] Tan S X, Zhai J , Fang H J , Jiu T G, Ge J , Li YL , Jiang L ,Zhu D B. Chem. -Eur. J . , 2005 , 11(21) : 6272 —6276
[ 8 ] Wang H X, Li H , Xue B F , Wang Z X, Meng Q B , Chen L Q.J . Am. Chem. Soc. , 2005 , 127 (17) : 6394 —6401
[ 9 ] Li C Y, Li X P , Ma Y T. Chin. Chem. Lett . , 2005 , 16 (7) :967 —970
[10] Hu L H , Dai S Y, Wang KJ . Chin. Phys. Lett . , 2005 , 22(2) :493 —495
[11] Xia J B , Li F Y, Huang C H. Chin. J . Chem. , 2004 , 22(7) :687 —690
[12] 刘兆阅(Liu Z Y) , 潘凯( Pan K) , 杨敏( Yang M) , 王德军(Wang D J ) , 白玉白(Bai Y B) . 高等学校化学学报(Chemical Journal of Chinese Universities) , 2003 , 24(5) : 888 —891
[13] 李斌(Li B) , 邱勇(Qiu Y) . 感光科学与光化学(Photographic Science and Photochemistry) , 2000 , 18(4) : 336 —347
[14] 张东社(Zhang D S) , 刘尧(Liu Y) , 王维波(Wang W B) , 肖绪瑞(Xiao X R) . 科学通报(Chinese Science Bulletin) , 2000 ,45(9) : 929 —932
[15] 柳闽生(Liu M S) , 詹寿发(Zhan S F) , 帅敏(Shuai M) , 严晓华(Yan X H) , 蔡生民(Cai S M) , 郝彦忠(Hao YZ) . 高分子材料科学与工程( Polymer Materials Science and Engineering) ,2003 , 19(5) : 172 —175
[16] 范乐庆(Fan L Q) , 吴季怀(Wu J H) , 黄昀　(Huang Y F) ,林建明(Lin J M) . 感光科学与光化学( Photographic Science and Photochemistry) , 2003 , 21(3) : 231 —237
[17] 林原(Lin Y) , 谢普会(Xie P H) . 科学通报(Chinese Science Bulletin) , 2002 , 47(15) : 1145 —1147
[18] Rao T N , Bahadur L. J . Electrochem. Soc. , 1997 , 144 (1) :179 —185
[19] Kashyout A B , Soliman M, El Gamal M, FathyM. Mater. Chem.Phys. , 2005 , 90(2/3) : 230 —233
[20] Baxter J B , Aydil E S. Appl . Phys. Lett . , 2005 , 86 (5) : art .no. 053114
[21] Guo P , Aegerter MA. Thin Solid Films , 1999 , 351(1/2) : 290 —294
[22] Sayama K, Sugihara H , Arakawa H. Chem. Mater. , 1998 , 10(12) : 3825 —3832
[23] Bergeron B V , Marton A , Oskam G, Meyer GJ . J . Phys. Chem. B , 2005 , 109 (2) : 937 —943
[24] Chappel S , Zaban A. Sol . Energy Mater. Sol . Cells , 2002 , 71(2) : 141 —152
[25] 张莉(Zhang L) , 杨迈之(Yang M Z) , 乔学斌(Qiao X B) , 郝彦忠(Hao Y Z) , 王艳琴(Wang YQ) , 蔡生民(Cai S M) . 化学学报(Acta Chimica Sinica) , 1999 , 57 (10) : 1129 —1135
[26] Peng B , Jungmann G, Jager C , Haarer D , Schmidt H W,Thelakkat M. Coord. Chem. Rev. , 2004 , 248 (13/14) : 1479 —1489
[27] Kang T S , Moon S H , Kim K J . J . Electrochem. Soc. , 2002 ,149(5) : E155 —E158
[28] Kumara G R R A , Konno A , Senadeera G K R , Jayaweera P V V , de Silva D B R A , Tennakone K. Sol . Energy Mater. Sol .Cells , 2001 , 69(2) : 195 —199
[29] Barbe C J , Arendse F , Comte P , Jirousek M, Lenzmann F ,Shklover V , Gr? tzel M. J . Am. Chem. Soc. , 1997 , 80 (12) :3157 —3171
[30] 王瑞斌(Wang R B) , 戴松元(Dai S Y) , 王孔嘉(Wang K J) .功能材料(Journal of Functional Materials) , 2002 , 33 ( 3) :296 —298
[31] 高恩勤(Gao E Q) , 张莉(Zhang L) , 杨迈之(Yang M Z) , 蔡生民(Cai SM) . 物理化学学报(Acta Physico2Chimica Sinica) ,2001 , 17 (2) : 177 —180
[32] Natarajan C , Nogami G. J . Electrochem. Soc. , 1996 , 143 (5) :1547 —1550
[33] Yamamoto J , Tan A , Shiratsuchi R , Hayase S , Chenthamarakshan C R , Rajeshwar K. Adv. Mater. , 2003 , 15(21) : 1823 —1825
[34] Choy K L , Su B. J . Mater. Sci . Lett . , 1999 , 18 (12) : 943 —945
[35] Okuya M, Nakade K, Osa D , Nakano T , Kumara GR A , Kaneko S. J . Photochem. Photobiol . A: Chem. , 2004 , 164 ( 1/3 ) :167 —172
[36] Knodler R , Sopka J , Harbach F , Grunling H W. Sol . Energy Mater. Sol . Cells , 1993 , 30(3) : 277 —281
[37] Ma T L , Kida T , Akiyama M, Inoue K, Tsunematsu SJ , Yao K,Noma H , Abe E. Electrochem. Commun. , 2003 , 5 (4) : 369 —372
[38] Park N G, Kim K M, Kang M G, Ryu K S , Chang S H , Shin Y J . Adv. Mater. , 2005 , 17(19) : 2349 —2353
[39] Durr M, Schmid A , Obermaier M, Rosselli S , Yasuda A , Nelles G. Nat . Mater. , 2005 , 4(8) : 607 —611
[40] Srikanth K, Rahman M M, Tanaka H , Krishna K M, Soga T ,Mishra M K, Jimbo T , Umeno M. Sol . EnergyMater. Sol . Cells ,2001 , 65(1/4) : 171 —177
[41] Thelakkat M, Schmitz C , Schmidt H W. Adv. Mater. , 2002 , 14(8) : 577 —581
[42] Gomez M M, Lu J , Solis J L , Olsson E , Hagfeldt A , Granqvist C G. J . Phys. Chem. B , 2000 , 104 (36) : 8712 —8718
[43] Jiu J T , Wang F M, Sakamoto M, Takao J , Adachi M. J .Electrochem. Soc. , 2004 , 151 (10) : A1653 —A1658
[44] Takenaka S , Maehara Y, Imai H , Yoshikawa M, Shiratori S.Thin Solid Films , 2003 , 438 : 346 —351
[45] Diamant Y, Chen S G, Melamed O , Zaban A. J . Phys. Chem.B , 2003 , 107 (9) : 1977 —1981
[46] Chen S G, Chappel S , Diamant Y, Zaban A. Chem. Mater. ,2001 , 13(12) : 4629 —4634
[47] Wang Z S , Huang C H , Huang Y Y, Hou YJ , Xie P H , Zhang B W, Cheng H M. Chem. Mater. , 2001 , 13 (2) : 678 —682
[48] Yang S M, Huang Y Y, Huang C H , Zhao X S. Chem. Mater. ,2002 , 14(4) : 1500 —1504
[49] Liu Z Y, Pan K, Liu M, Wang M J , Lu Q , Li J H , Bai YB , Li TJ . Electrochim. Acta , 2005 , 50(13) : 2583 —2589
[50] Taguchi T , Zhang X T , Sutanto I , Tokuhiro K, Rao T N ,Watanabe H , Nakamori T , Uragami M, Fujishima A. Chem.Commun. , 2003 , 19 : 2480 —2481
[51] Jung H S , Lee J K, Nastasi M, Lee S W, Kim J Y, Park J S ,Hong K S , Shin H. Langmuir , 2005 , 21(23) : 10332 —10335
[52] Kim S S , Yum J H , Sung Y E. J . Photochem. Photobiol . A:Chem. , 2005 , 171 (3) : 269 —273
[53] Park N G, Kang M G, Kim KM, Ryu K S , Chang S H , Kim D K, van de Lagemaat J , Benkstein K D , Frank A J . Langmuir ,2004 , 20(10) : 4246 —4253
[54] Bandaranayake K M P , Senevirathna M K I , Weligamuwa P M G M P , Tennakone K. Coord. Chem. Rev. , 2004 , 248 (13/14) :1277 —1281
[55] Diamant Y, Chappel S , Chen S G, Melamed O , Zaban A.Coord. Chem. Rev. , 2004 , 248 (13/14) : 1271 —1276
[56] Diamant Y, Chen S G, Melamed O , Zaban A. J . Phys. Chem.B , 2003 , 107 (9) : 1977 —1981
[57] Ko K H , Lee Y C , Jung YJ . J . Colloid Interface Sci . , 2005 ,283(2) : 482 —487
[58] Lindgren T , Mwabora J M, Avendano E , Jonsson J , Hoel A ,Granqvist C G, Lindquist S E. J . Phys. Chem. B , 2003 , 107(24) : 5709 —5716
[59] Ma T L , Akiyama M, Abe E , Imai I. Nano Lett . , 2005 , 5(12) :2543 —2547
[60] Jang S R , Vittal R , Kim K J . Langmuir , 2004 , 20(22) : 9807 —9810
[61] Nazeeruddin M K, Humphry-Baker R , Liska P , Gr? tzel M. J .Phys. Chem. B , 2003 , 107 (34) : 8981 —8987
[62] Zeng L Y, Dai S Y, Wang K J , Pan X, Shi C W, Guo L. Chin.Chem. Lett . , 2004 , 21 (9) : 1835 —1837
[63] Wang Z S , Yamaguchi T , Sugihara H , Arakawa H. Langmuir ,2005 , 21(10) : 4272 —4276
[64] Huynh W U , Dittmer J J , Alivisatos A P. Science , 2002 , 295(5564) : 2425 —2427
[65] Law M, Greene L E , Johnson J C , Saykally R , Yang P D. Nat .Mater. , 2005 , 4(6) : 455 —459
[66] Uchida S , Chiba R , Tomiha M, Masaki N , Shirai M.Electrochemistry , 2002 , 70(6) : 418 —420
[67] Adachi M, Murata Y, Okada I , Yoshikawa S. J . Electrochem.Soc. , 2003 , 150 (8) : G488 —G493
[68] Adachi M, Murata Y, Takao J , Jiu J T , Sakamoto M, Wang F M. J . Am. Chem. Soc. , 2004 , 126 (45) : 14943 —14949
[69] Song M Y, Kim D K, Ihn K J , Jo S M, Kim D Y.Nanotechnology , 2004 , 15(12) : 1861 —1865
[70] Song M Y, Ahn Y R , Jo S M, Kim D Y, Ahn J P. Appl . Phys.Lett . , 2005 , 87(11) : art . no. 113113
[71] Usami A. Chem. Phys. Lett . , 1997 , 277 (1/3) : 105 —108
[72] Nishimura S , Abrams N , Lewis B A , Halaoui L I , Mallouk T E ,Benkstein KD , van de Lagemaat J , Frank A J . J . Am. Chem.Soc. , 2003 , 125 (20) : 6306 —6310
[73] Halaoui L I , Abrams N M, Mallouk T E. J . Phys. Chem. B ,2005 , 109 (13) : 6334 —6342
[74] Hore S , Nitz P , Vetter C , Prahl C , Niggemann M, Kern R.Chem. Commun. , 2005 , 2011 —2013
[75] Zukalova M, Zukal A , Kavan L , Nazeeruddin M K, Liska P ,Grätzel M. Nano Lett . , 2005 , 5(9) : 1789 —1792
[76] O’Regan B , Lenzamann F , Muis R , Wienke J . Chem. Mater. ,2002 , 14(12) : 5023 —5029
[77] 戴松元(Dai S Y) , 王孔嘉(Wang K J) , 隋毅峰(Sui Y F) , 翁坚(Weng J ) , 黄阳(Huang Y) , 胡林华(Hu L H) , 孔凡太(Kong F T) , 陈双宏(Chen S H) , 肖尚锋(Xiao S F) , 王卫国(Wang W G) , 潘旭(Pan X) , 史成武(Shi C W) , 郭力( Guo L) . 太阳能学报(Acta Energiae Solar Sinica) , 2004 , 25 (6) :807 —810
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