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化学进展 2006, Vol. 18 Issue (0708): 933-938 前一篇   后一篇

• 综述与评论 •

基于动物丝蛋白的人工纺丝*

周官强;陈新**;邵正中   

  1. 复旦大学高分子科学系 聚合物分子工程教育部重点实验室 上海 200433
  • 收稿日期:2005-08-01 修回日期:2005-10-01 出版日期:2006-08-24 发布日期:2006-08-24
  • 通讯作者: 陈新
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The Artificial Spinning Based on Silk Proteins

Guanqiang Zhou;Xin Chen**;Zhengzhong Shao   

  1. Key Laboratory of Molecular Engineering of Polymers of Ministry of Education, Department of Macromolecules Science, Fudan University, Shanghai 200433, China
  • Received:2005-08-01 Revised:2005-10-01 Online:2006-08-24 Published:2006-08-24
  • Contact: Xin Chen
动物丝，特别是蜘蛛丝近年来由于其优异的综合力学性能而备受关注。但是天然动物丝的应用由于种种原因而受到各种限制，因此人们期望通过人工纺丝获得性能与天然动物丝相近的人工丝纤维。本文就采用动物丝蛋白进行人工纺丝的历史和现状，从再生蜘蛛丝蛋白、重组蜘蛛丝蛋白和再生蚕丝蛋白等方面进行综述，比较了天然动物丝和人工丝纤维的力学性能，并且探讨了人工生物模拟纺丝制备高性能人工丝纤维(超级纤维)的前景。
关键词： 蜘蛛丝, 蚕丝, 湿法纺丝, 丝蛋白
Animal silks, especially spider silks attract considerable interest because of their excellent comprehensive mechanical properties. However, the applications of natural silks are restricted because of various reasons. Therefore, people expect to obtain artificial silk fibers that have similar performance as natural silks by artificial spinning. In this paper, the history and status quo of the artificial spinning based on silk proteins are reviewed. The mechanical properties between natural silk fibers and artificial silk fibers were also compared, and the future of the biomimic artificial spinning for the production of high-performance artificial silk fibers (superfibers) is discussed.
Key words: spider silk, silkworm silk, wet spinning methods, fibroin and spidroin

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摘要

基于动物丝蛋白的人工纺丝*