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化学进展 2006, Vol. 18 Issue (06): 727-733 前一篇   后一篇

• 综述与评论 •

稀土卤素气态配合物热力学性质的研究进展

孙艳辉;陈华妮*   

  1. 华南师范大学化学与环境学院 广州 510631 
  • 收稿日期:2005-07-29 修回日期:2005-11-01 出版日期:2006-06-24 发布日期:2006-06-24
  • 通讯作者: 陈华妮
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Progress in Thermodynamic Properties of the Vapor Rare Earth Complexes with Halogen Bridges

Huani Chen;Yanhui Sun*   

  1. College of Environment and Chemistry, South China Normal University, Guangzhou 510631, China
  • Received:2005-07-29 Revised:2005-11-01 Online:2006-06-24 Published:2006-06-24
  • Contact: Yanhui Sun
本文对稀土卤素气态配合物LnMnX3n+3(M = Al，Fe；X = Cl，Br)和ALnX4(A = 碱金属；X = Cl，I)的热力学性质、研究方法及其在稀土分离制备方面的应用进行了综述。并对其今后的研究及应用进行了展望。
关键词： 稀土, 卤素气态配合物, 热力学性质
Thermodynamic properties of the vapor rare earth complexes with halogen bridges LnMnX3n+3(M = Al，Fe；X = Cl，Br) and ALnX4(A = alkali metals；X = Cl，I) are reviewed in this paper. Moreover，the methods to investigating thermodynamic properties and their application in the preparation and separation of rare earth elements are also discussed.The future work on thermodynamic properties of the vapor complexes and their applications are briefly introduced.
Key words: rare earth, halogen vapor complexes, thermodynamic properties

中图分类号: 

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