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化学进展 2006, Vol. 18 Issue (0203): 281-289 前一篇   后一篇

• 综述与评论 •

苯炔体系大环合成、自组装及其应用*

王嬿嬿;马谆;范曲立;黄维**   

  1. 复旦大学先进材料研究院 上海 200433
  • 收稿日期:2005-02-01 修回日期:2005-07-01 出版日期:2006-03-24 发布日期:2006-03-24
  • 通讯作者: 黄维
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Syntheses, Self-Assembly and Applications of Arylene-Ethynylene Macrocycles

Yanyan Wang;Zhun Ma;Quli Fan;Wei Huang**   

  1. Institute of Advanced Materials, Fudan University, Shanghai 200433, China
  • Received:2005-02-01 Revised:2005-07-01 Online:2006-03-24 Published:2006-03-24
  • Contact: Wei Huang
含苯炔结构的大环（arylene ethynylene macrocycle, AEMs）体系具有独特的性质和潜在的应用前景，在过去的数年中被广泛研究和探索。本文系统地介绍了AEMs的合成方法，包括不同关环方法、固相合成、模板合成和聚集驱动关环法等。在研究AEMs性质方面，重点介绍了它们的自组装性能。同时也介绍了AEMs在构造三维纳米结构、液晶、管状通道、主客体复合物等超分子化学领域的应用。
关键词： AEMs, 固相合成, 模板合成, 自组装, 超分子化学
Macrocycles composed of arylene and ethynylene units (AEMs) have attracted great interest in recent years, due to their novel properties and potential applications. The advances in syntheses of AEMs, including different cyclization methods, solid-phase synthesis, template synthesis and aggregation driven cyclization are summarized. The progress that has been achieved for self-assembly of AEMs and its applications in supramolecule chemistry, including threedimensional nanostructures, discotic liquid crystals, extended tubular channels, guesthost complexes and porous organic solids, is also reviewed.
Key words: AEMs, solid-phase synthesis, template synthesis, self-assembly, supramolecule chemistry

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