English
往期目录
新闻公告
More
化学进展 2006, Vol. 18 Issue (01): 51-58 前一篇   后一篇

• 综述与评论 •

乙烯齐聚合成线性 α-烯烃镍系催化剂*

张宝军1,2;王延吉1**   

  1. 1. 河北工业大学化工学院 天津300130; 2. 中国石油大庆石化分公司研究院 大庆163714
  • 收稿日期:2004-11-01 修回日期:2005-03-01 出版日期:2006-01-24 发布日期:2006-01-24
  • 通讯作者: 王延吉
下载PDF ( 1347 ) 引用
导出

Nickel-Based Oligomerization Catalysts for Synthesis of Linear α-Olefins

Baojun Zhang1,2;Yanji Wang1**   

  1. 1. School of Chemical Engineering and Technology, Hebei University of Technology,Tianjin 300130, China;2. Research Institute of Daqing Petrochemical Company, CNPC, Daqing 163714, China
  • Received:2004-11-01 Revised:2005-03-01 Online:2006-01-24 Published:2006-01-24
  • Contact: Yanji Wang
利用SHOP型工艺由乙烯齐聚制备线性α-烯烃不仅具有工业应用价值，而且具有很高的学术意义。SHOP型工艺的工业化引起了人们对基于P∩O配位型及其他配位型镍催化剂的广泛的研究兴趣。镍系催化剂具有活性高、选择性好、产品分布可调、反应条件温和等优良性能。本文介绍了镍系催化剂的类型和性能等，并对影响催化性能的因素进行了分析。
关键词： 镍系催化剂, 乙烯齐聚, α-烯烃
The oligomerization of ethylene to linear α-olefins by the Shell higher olefins process (SHOP) is of industrial and academic interest and has stimulated intensive research on nickel catalysts with P∩O and related chelating ligands. Nickel-based catalysts possess high catalytic activity for ethylene oligomerization with high selectivity, easily-controlled oligomers distribution and moderate reaction conditions. The compositions, structures and mechanisms proposed for ethylene oligomerization are reviewed. The influence of the ligands and reaction conditions for the oligomerization is discussed.
Key words: nickel-based catalysts, ethylene oligomerization, α-olefins

中图分类号: 

()

[ 1 ] Johnson L K, Killian C M, Brookhart M. J . Am. Chem. Soc. ,1995 , 117 (23) : 6414 —6415
[2] Killian C M, Johnson L K, Brookhart M. Organometallics , 1997 ,16 (10) : 2005 —2007
[3] Keim W. New J . Chem. , 1994 , 18 (3) : 93 —96
[4] Britovsek G J P , Gibson V C , Wass D F. Angewandte Chemie International Edition , 1999 , 38 (4) : 428 —447
[5] Ittel S D , Johnson L K, Brookhart M. Chem. Rev. , 2000 , 100(4) : 1169 —1203
[6] Mecking S. Coordination Chemistry Reviews , 2000 , 203 ( 1) :325 —351
[7] Heinicke J , Kêhler M, Peulecke N , Keim W. Journal of Catalysis , 2004 , 225 (1) : 16 —23
[8] Wasserscheid P , Hilgers C , Keim W. Journal of Molecular Catalysis A: Chemical , 2004 , 214 (1) : 83 —90
[9] Komon Z J A , Bazan G C , Fang C , Bu X H. Inorganica Chimica Acta , 2003 , 345 : 95 —102
[10] 李达刚(Li D G) ,刘东兵(Liu D B) . 石油化工(Petrochem. Technol . ) , 1999 , 28 (5) : 297 —300
[11] Luo H K, Li D G. Appl . Organometal . Chem. , 2000 , 14 (7) :389 —393
[12] Tomov A , Kurtev K. Journal of Molecular Catalysis A: Chemical ,1995 , 103 (2) : 95 —103
[13] Desjardins S Y, Cavell K J , Hoare J L , Skelton B W, Sobolev A N , White A H , Keim W. Journal of Organometallic Chemistry ,1996 , 515 (1/2) : 233 —243
[14] Desjardins S Y, Cavell K J , Hoare J L , Skelton B W, Sobolev A N , White A H , Keim W. Journal of Organometallic Chemistry ,1997 , 544 (2) : 163 —174
[15] Younkin T R , Connor E F , Henderson J I , Friedrich S K, Grubbs R H , Bansleben D A. Science , 2000 , 287 (5452) : 460 —462
[16] Wang C , Friedrich S , Younkin T R , Li R T, Grubbs R H ,Bansleben D A , Day M M. Organometallics , 1998 , 17 (15) :3149 —3151
[17] Carlini C , Isola M, Liuzzo V , Galletti A M R , Sbrana G. Applied Catalysis A: General , 2002 , 231 (1/2) : 307 —320
[18] Chen L Y, Hou J X, Sun W H. Applied Catalysis A: General ,2003 , 246 (1) : 11 —16
[19] Sun W H , Zhang W, Gao T L , Tang X B , Chen L Y, Li Y, Jin XL. Journal of Organometallic Chemistry , 2004 , 689 (5) : 917 —929
[20] Speiser F , Braunstein P , Saussine L. Inorg. Chem. , 2004 , 43 :4234 —4240
[21] Zhao W, Qian Y L , Huang J L , Duan J J . Journal of Organometallic Chemistry , 2004 , 689 (16) : 2614 —2623
[22] Spencer L P , Altwer R , Wei P R , Gelmini L , Gauld J , Stephan D W. Organometallics , 2003 , 22 : 3841 —3854
[23] Yi J J , Huang X G, Zhang W, Hong X Y, Jing Z H. Journal of Natural Gas Chemistry , 2003 , 12 (2) : 98 —104
[24] Qian M X, Wang M, Zhang Y L , He R. Chinese Journal of Chemistry , 2002 , 20 (7) : 676 —680
[25] Brookhart M, Johnson L K, Killian C M, Mecking S , Tempel D.J . Polymer Prepr. (Am. Chem. Soc. , Div. Polym. Chem. ) ,1996 , 37 : 254 —255
[26] Brookhart M, Johnson L K, Killian C M. Abstracts of Papers ,210th National Meeting of the American Chemical Society.Washington DC: American Chemical Society , 1995. 252 —PMSE
[27] Killian C M, Tempel D J , Johnson L K, Brookhart M. J . Am.Chem. Soc. , 1996 , 118 (46) : 11664 —11665
[28] Britovsek G J P , Gibson V , Kimberley B S , Maddox P J ,McTavish S J , Solan GA , White A J P , Williams D. J . Chem.Commun. , 1998 , 7 : 849 —850
[29] Abu-Surrah A S , Rieger B. Angew. Chem. Int . Ed. Engl . ,1996 , 35 (21) : 2475 —2477
[30] 贾辉(Jia H) , 陈红霞(Chen H X) , 卢艳(Lu Y) , 姜涛(Jiang T) . 大庆石油学院学报( Journal of Daqing Petroleum Institute) , 2003 , 27 (4) : 36 —38
[31] Shao C X, Sun W H , Li Z L , Hu Y L , Han L Q. Catalysis Communications , 2002 , 3 (9) : 405 —410
[32] Li Z, Sun W H , Ma Z, Hu Y L , Shao C X. Chin. Chem. Lett . ,2001 , 12 (8) : 691 —692
[33] Li J T, Gao T L , Zhang W, Sun W H. Inorganic Chemistry Communications , 2003 , 6 (11) : 1372 —1374
[34] Tang X, Cui Y, Sun W H , Miao Z, Yan S. Polym. Int . , 2004 ,53 : 2155 —2161
[35] Helldêrfer M, Backhaus J , Alt H G. Inorganica Chimica Acta ,2003 , 351 : 34 —42
[36] Helldêrfer M, Milius W, Alt H G. Journal of Molecular Catalysis A: Chemical , 2003 , 197 (1/2) : 1 —13
[37] Helldêrfer M, Backhaus J , Milius W, Alt H G. Journal of Molecular Catalysis A: Chemical , 2003 , 193 (1/2) : 59 —70
[38] Bernardo-Gusm?o K, Queiroz L F T, Souza R F , Leca F , Loup C , Réau R. Journal of Catalysis , 2003 , 219 (1) : 59 —62
[39] Speiser F , Braunstein P , Saussine L , Welter R. Organometallics ,2004 , 23 (11) : 2613 —2624
[40] Daugulis O , Brookhart M. Organometallics , 2002 , 21 : 5926
[41] Chen H P , Liu Y H , Peng S M, Liu S T. Organometallics , 2003 ,22 (24) : 4893 —4899
[42] Chen J T, Liu S T, Zhao K Q. J . Chin. Chem. Soc. , 2000 , 47(1) : 279 —281
[43] Sun W H , Li Z, Hu H , Wu B , Yang H , Zhu N , Leng X, Wang H. New J . Chem. , 2002 , 26 (10) : 1474 —1478
[44] Speiser F , Braunstein P , Saussine L. Organometallics , 2004 , 23(11) : 2625 —2632
[45] Speiser F , Braunstein P , Saussine L. Organometallics , 2004 , 23(11) : 2633 —2640
[46] Speiser F , Braunstein P , Saussine L. J . Chem. Soc. , Dalton Trans. , 2004 , 10 : 1539 —1545
[47] Keim W. New J . Chem. , 1987 , 11 (7) : 531 —534
[48] Gates D P , Svejda S A , Onate E , Killian C M, Johnson L K,White P S , Brookhart M. Macromolecules , 2000 , 33 ( 7 ) :2320 —2334
[49] Svejda S A , Brookhart M. Organometallics , 1999 , 18 (1) : 65 —74
[50] Mason R F. US 3 686 351 , 1972
[1] 张君涛,张国利,冯霄. 乙烯齐聚制α-烯烃镍系催化剂[J]. 化学进展, 2008, 20(0708): 1032-1036.
[2] 沈昊宇,金国新. 新型后过渡金属烯烃聚合催化剂－－镍系烯烃聚合催化剂*[J]. 化学进展, 2003, 15(01): 60-.