English
往期目录
新闻公告
More
化学进展 2005, Vol. 17 Issue (06): 949-954   后一篇

• 综述与评论 •

富勒烯离子Jahn-Teller 畸变和光谱研究进展

滕启文*;吴师   

  1. 浙江大学化学系　杭州 310027
  • 收稿日期:2005-02-01 修回日期:2005-05-01 出版日期:2005-11-24 发布日期:2009-04-02
  • 通讯作者: 滕启文
下载PDF ( 1253 ) 引用
导出 被引次数 ( 18 | 2 )

Studies on Jahn-Teller Distortion and Spectra of Fullerene Ions

Teng Qiwen*;Wu Shi   

  1. Department of Chemistry,Zhejiang University,Hangzhou 310027,China
  • Received:2005-02-01 Revised:2005-05-01 Online:2005-11-24 Published:2009-04-02
  • Contact: Teng Qiwen
MxC60 (M= K、Cs、Rb) 具有的超导性启发人们对C60n- 和C70n- 展开了深入研究。本文综述了富勒烯离子C60n±、C70n±、C76n±、C78n±及C80n±的结构畸变和光谱研究进展,介绍了国内外近十几年来众多研究小组的有关工作,从实验检测到理论计算, 从结构探讨到谱学性质研究, 并结合作者在此方面的理论研究成果,进一步探索富勒烯离子Jahn-Teller 畸变的特点和产生原因以及其电子光谱的规律性。
关键词： 富勒烯离子, Jahn-Teller畸变, 电子光谱
Deep studies on C60n- and C70n- - have been performed based on superconductivities of MxC60 (M = K, Cs,Rb) . The development of research in the Jahn- Teller distortion and spectroscopy of fullereneions C60n±、C70n±、C76n±、C78n± and C80n± is reviewed.Relevant works of other groups worldwide about experimental determination,theoretical calculation,structural exploration and spectroscopic investigation are introduced.The regularity of Jahn-Tellerdistortion and electronic spectra of fullerene ions is further explored according to authorsptheoretical research in this field.
Key words: fullerene ions, Jahn- Teller distortion, electronic spectra

中图分类号: 

()

[ 1 ] Caron C , Subramanian R , D’Souza F , et al . J . Am. Chem.Soc. , 1993 , 115 : 8505 —8506
[ 2 ] Fulara J , Jakobi M, Maier J P. Chem. Phys. Lett . , 1993 , 211 :227 —234
[ 3 ] Tanaka K, Okada M, Okahara K, et al . Chem. Phys. Lett . ,1992 , 193 : 101 —105
[ 4 ] 邱庆春(Qiu Q C) . 物理学报(Acta Physica Sinica) , 2003 , 52 :958 —969
[ 5 ] 邱庆春(Qiu Q C) . 物理学报(Acta Physica Sinica) , 2004 , 53 :2292 —2298
[ 6 ] Koga N , Morokuma K. Chem. Phys. Lett . , 1992 , 196 : 191 —196
[ 7 ] Giuffreda M, Negri G F , Orlandi G. J . Phys. Chem. A , 2001 ,105 : 9123 —9129
[ 8 ] Kato T , Kodama T , Oyama M, et al . Chem. Phys. Lett . , 1991 ,186 : 35 —39
[ 9 ] Moriyama H , Kobayashi H , Kobayashi A , et al . J . Am. Chem.Soc. , 1993 , 115 : 1185 —1187
[10] Wan W C , Liu X, Sweeney G M, et al . J . Am. Chem. Soc. ,1995 , 117 : 9580 —9581
[11] Tachibana A , Ishikawa S , Yamabe T. Chem. Phys. Lett . , 1993 ,201 : 315 —320
[12] Dubois D , Kadish K M. J . Am. Chem. Soc. , 1991 , 113 :4364 —4366
[13] Paul P , Xie Z , Bau R , et al . J . Am. Chem. Soc. , 1994 , 116 :4145 —4146
[14] Hutter J , Luthi H P. Int . J . Quantum Chem. , 1993 , 46 : 81 —86
[15] Yamaguchi K, Hayashi S , Okumura M, et al . Chem. Phys.Lett . , 1994 , 226 : 372 —380
[16] Bauch T W, Prakash G K S , Olah G A. J . Am. Chem. Soc. ,1991 , 113 : 3205 —3206
[17] Heath G A , McGrady J E , Martin R L. J . Chem. Soc. , Chem.Commun. , 1992 , 1272 —1274
[18] Lawson D R , Feldheim D L , Foss C A , et al . J . Electrochem.Soc. , 139 : L68 —L71
[19] Gasyna Z , Andrews L , Schatz P N. J . Phys. Chem. , 1992 , 96 :1525 —1527
[20] Petrie S , Javahery G, Bohme D K. J . Am. Chem. Soc. , 1993 ,115 : 1445 —1450
[21] Hrusak J , Schwarz H. Chem. Phys. Lett . , 1993 , 205 : 187 —190
[22] Yoo R K, Ruscic B , Berkowitz J . J . Chem. Phys. , 1992 , 96 :911 —918
[23] Scheier P , Robl R , Schiestl B , et al . Chem. Phys. Lett . , 1994 ,220 : 141 —144
[24] Tanaka K, Okada M, Okahara K, et al . Chem. Phys. Lett . ,1993 , 202 : 394 —398
[25] Fulara J , Jakobi M, Maier J P. Chem. Phys. Lett . , 1993 , 206 :203 —209
[26] Hase H , Miyatake Y. Chem. Phys. Lett . , 1993 , 215 : 141 —143
[27] Lawson D R , Feldheim D L , Foss C A. J . Phys. Chem. , 1992 ,96 : 7175 —7177
[28] Roduner E , Reid I D. Chem. Phys. Lett . , 1994 , 223 : 149 —154
[29] Shabtai E , Weitz A , Haddon R C , et al . J . Am. Chem. Soc. ,1998 , 120 : 6389 —6393
[30] Allen K M, Dennis T J S , Rosseinsky M J , et al . J . Am. Chem.Soc. , 1998 , 120 : 6681 —6689
[31] Limbach P A , Schweikhard L , Cowen K A , et al . J . Am. Chem.Soc. , 1991 , 113 : 6795 —6798
[32] Steger H , Holzapfel J , Hielscher A , et al . Chem. Phys. Lett . ,1995 , 234 : 455 —459
[33] Boltalina O V , Sidorov L N , Sukhanova E V. Chem. Phys.Lett . , 1994 , 230 : 567 —570
[34] Haufler R E , Conceicao J , Chibanate L P F , et al . J . Am.Chem. Soc. , 1990 , 94 : 8634 —8636
[35] Guldi D M, Asmus K D. J . Am. Chem. Soc. , 1997 , 119 :5744 —5745
[36] Okada M, Okahara K, Tanaka K, et al . Chem. Phys. Lett . ,1993 , 209 : 91 —98
[37] Suzuki T , Maruyama Y, Kato T. Angew. Chem. Int . Ed.Engl . , 1995 , 34 : 1094 —1096
[38] Suzuki S , Kawata S , Shiromaru H , et al . J . Phys. Chem. ,1992 , 96 : 7159 —7161
[39] 封继康(Feng J K) , 滕启文(Teng Q W) , 李君(Li J ) , et al .高等学校化学学报( Chem. J . Chin. Univ. ) , 1994 , 15 :1662 —1665
[40] 滕启文(Teng Q W) , 封继康(Feng J K) , 李君(Li J) 等. 化学学报(Acta Chimica Sinica) , 1995 , 53 : 105 —110
[41] 滕启文(Teng Q W) , 封继康(Feng J K) , 魏家友(Wei J Y)等. 高等学校化学学报(Chem. J . Chin. Univ. ) , 1995 , 16 :265 —269
[42] 封继康(Feng J K) , 滕启文(Teng Q W) , 魏家友(Wei J Y)等. 化学学报(Acta Chimica Sinica) , 1995 , 53 : 550 —556
[43] 滕启文(Teng Q W) , 封继康(Feng J K) , 吴师(Wu S) 等. 化学学报(Acta Chimica Sinica) , 1996 , 54 : 125 —131
[44] 滕启文(Teng Q W) , 吴师(Wu S) , 尚振锋(Shang Z F) 等. 高等学校化学学报(Chem. J . Chin. Univ. ) , 1996 , 17 : 773 —776
[45] 滕启文(Teng Q W) , 吴师(Wu S) , 赵学庄(Zhao X Z) 等. 化学学报(Acta Chimica Sinica) , 1997 , 55 : 943 —947
[46] 滕启文(Teng Q W) , 吴师(Wu S) . 高等学校化学学报(Chem. J . Chin. Univ. ) , 2001 , 22 : 1019 —1021
[47] 吴师(Wu S) , 滕启文(Teng Q W) , 陈平(Chen P) . 结构化学(Chin. J . Struc. Chem. ) , 2004 , 23 : 67 —72
[48] 吴师(Wu S) , 滕启文(Teng Q W) . 有机化学(Chin. J . Org.Chem. ) , 2004 , 24 : 822 —824
[49] 吴师(Wu S) , 滕启文(Teng Q W) . 结构化学(Chin. J . Struc.Chem. ) , 2005 , 24 : 21 —24
[50] 吴师(Wu S) , 滕启文(Teng Q W) . 化学物理学报(Chin. J .Chem. Phys. ) , 2005 , 18 : 715 —718
[51] Teng Q , Feng J , Sun C , et al . Int . J . Quantum Chem. , 1995 ,55 : 35 —45
[52] Teng Q , Zhao X, Cai Z S , et al . Int . J . Quantum Chem. ,1997 , 61 : 815 —822
[53] Teng Q , Wu S. J . Quantum. Chem. , 2005 , 104 : 279 —285
[54] Teng Q , Wu S , Zhu Z. Int . J . Quantum Chem. , 2003 , 91 :39 —45
[55] Teng Q , Wu S. J . Mol . Struc. -Theochem. , 2005 , 719 : 47 —51
[56] Henderson C C , Rohlfing C M, Cahill P A. Chem. Phys. Lett . ,1993 , 213 : 383 —388
[57] Hedberg K, Hedber L , Bethune D S , et al . Science , 1991 , 254 :410 —413
[58] David W I F , Ibberson R M, Matthewman J C , et al . Nature ,1991 , 353 : 147 —150
[59] Yannoni C S , Bernier P P , Bethune D S , et al . J . Am. Chem.Soc. , 1991 , 113 : 3190 —3192
[60] Andreoni W, Gygi F , Parrinello M. Chem. Phys. Lett . , 1992 ,189 : 241 —244
[61] Wang C Z , Chan C T , Ho K M. Phys. Rev. B , 1992 , 46 :9761 —9767
[62] Balch A L , Catalano V J , Lee J W, et al . J . Am. Chem. Soc. ,1991 , 113 : 8953 —8955
[63] Nikolaev A V , Dennis T J S , Prassides K, et al . Chem. Phys.Lett . , 1994 , 223 : 143 —148
[64] McKenzie D R , Davis C A , Cookayne D J H , et al . Nature ,1992 , 355 : 622 —624
[65] 刘书芝(Liu S Z) , 唐光诗(Tang G S) . 化学进展(Progress in Chemistry) , 2004 , 16(4) : 561 —573
[1] 孙辉,滕启文,吴师. 碳笼氧化物的结构和谱学性质[J]. 化学进展, 2006, 18(11): 1446-1451.