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化学进展 2005, Vol. 17 Issue (03): 406-411 前一篇   后一篇

• 综述与评论 •

层状嵌锂多元过渡金属氧化物的研究

黄友元1,2;周恒辉1*;陈继涛1;苏光耀2;高德淑2   

  1. 1.北京大学化学与分子工程学院 北京 100871;

    2.湘潭大学化学学院 湘潭 411105

  • 收稿日期:2004-03-01 修回日期:2004-07-01 出版日期:2005-05-24 发布日期:2005-05-24
  • 通讯作者: 周恒辉
下载PDF ( 2737 ) 引用
导出 被引次数 ( 78 | 5 )

Study of Layered Lithium Intercalation Multi-Element Transition Metal Oxides

Huang Youyuan1,2;Zhou Henghui1*;Chen Jitao1;Su Guangyao2;Gao Deshu2   

  1. 1.College of Chemistry and Molecular Engineering, Peking University,Beijing 100871,China;

    2.College of Chemistry , Xiangtan University,Xiangtan 411105,China;

  • Received:2004-03-01 Revised:2004-07-01 Online:2005-05-24 Published:2005-05-24
  • Contact: Zhou Henghui
综述了近几年来锂离子电池正极材料层状多元过渡金属氧化物的研究进展,重点讨论了具有协同作用的Ni、Co、Mn三元复合型层状正极材料LiCoxMnyNi1-x-yO2 (0<x<0.5,0<y<0.5)及部分二元过渡金属氧化物正极材料锂镍锰氧化物和锂钴锰氧化物的制备方法,以及多元素过渡金属氧化物体系的电化学反应机理及其元素配比变化对材料综合电性能的影响.进一步分析了今后几年这类层状多元过渡金属正极材料研究的可能热点及该类材料走向规模化应用的关键因素.
关键词： 层状结构, 协同作用, 多元过渡金属氧化物, 正极材料, 锂离子电池
The progress of multi-element transition metal oxides as cathode materials for lithium ion batteries is reviewed. The synthesis methods and electrochemical reaction mechanism associated with three-element (Ni^ Co^ Mn) synergetic effect of LiNi,. I_3.Coa:Mn:),O2(0 < x<0.5,0<y<0.5) are discussed in detail, and other duality transition metal oxides including LiNi^,Mn, O2 and LiCo^M^_ xO2 are discussed. The application prospect as cathode materials for lithium ion batteries and further research orientation of these lithium intercalation multi-element transition metal oxides are pointed out.
Key words: layered structure, synergetic effect, multi-element transition metal oxides, cathode materials, lithium ion batteries

中图分类号: 

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