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化学进展 2005, Vol. 17 Issue (02): 293-298 前一篇   后一篇

• 综述与评论 •

双官能团醇类化合物催化胺化反应的研究进展*

白国义1, 2   陈立功1* *   

  1. ( 1天津大学药物科学与技术学院 天津300072; 2河北大学化学与环境工程学院 保定071002)
  • 收稿日期:2004-02-01 修回日期:2004-07-01 出版日期:2005-03-24 发布日期:2005-03-24
  • 通讯作者: 陈立功 E-mail:lgchen@tju. edu. cn
  • 基金资助:

    国家自然科学基金

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Progress in the Catalytic Amination of Bifunctional Alcohols

Bai Guoyi1,2   Chen Ligong1* *   

  1. (College of Pharmaceuticals and Biotechnology, Tianjin University, Tianjin 300072, China; College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China)
  • Received:2004-02-01 Revised:2004-07-01 Online:2005-03-24 Published:2005-03-24
  • Contact: Chen Ligong E-mail:lgchen@tju. edu. cn

本文综述了由双官能团醇类化合物催化胺化合成二元胺或环胺的研究进展, 分别讨论了金属催化剂和固体酸催化剂对双官能团醇类化合物的不同作用机制, 考察了反应物结构对反应活性和选择性的影响, 重点介绍了超临界氨流体在二元醇催化胺化反应中的应用, 并指出了今后研究的方向。>

关键词： 双官能团醇类化合物, 二元胺, 环胺, 催化胺化, 超临界氨流体

The progress in the catalytic amination of bifunctional alcohols to diamines or cyclic amines is reviewed in this paper. The different catalytic mechanisms of metal catalysts and solid acids are discussed respectively. The rela2 tionship between the structures of bifunctional alcohols and the reaction results is examined. Application of supercritical ammonia in the catalytic amination of diols is intensively introduced. The further research trends are pointed out.

Key words: bifunctional alcohols, diamines, cyclic amines, catalytic amination, supercritical ammonia

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