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化学进展 2005, Vol. 17 Issue (02): 266-274 前一篇   后一篇

• 综述与评论 •

超( 近) 临界水中的化学反应

刘志敏 张建玲 韩布兴*   

  1. (中国科学院化学研究所分子科学中心　北京100080)
  • 收稿日期:2004-01-01 修回日期:2004-11-01 出版日期:2005-03-24 发布日期:2005-03-24
  • 通讯作者: 韩布兴 E-mail:hanbx@iccas. ac. cn
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导出 被引次数 ( 89 | 10 )

Chemical Reactions in Super2 and Subcritical Water

Liu Zhimin  Zhang Jianling   Han Buxin*   

  1. (Center for Molecular Science , Institute of Chemistry , Chinese Academy of Sciences , Beijing 100080 , China)
  • Received:2004-01-01 Revised:2004-11-01 Online:2005-03-24 Published:2005-03-24
  • Contact: Han Buxing E-mail:hanbx@iccas. ac. cn

水作为自然界最常用的绿色介质在化学反应中已经得到广泛应用。近年来,随着超临界技术的发展,人们对超(近) 临界水的认识逐渐深入,以超(近) 临界水为介质进行化学反应的研究引起了人们的极大兴趣,开展了许多卓有成效的工作。本文在介绍超(近) 临界水性质的基础上,主要对近年来超(近) 临界水中的有机合成、无机化学反应、生物质的转化反应及聚合物的降解等方面的研究进展进行了回顾总结。

关键词： 超临界流体, 水, 化学反应

As an environmentally benign solvent , water has been widely used in chemical reactions. With the de2 velopment of supercritical science and technology , super2 and subcritical water has attracted much attention due to its special properties , and a large amount of research work has been conducted in recent years. Chemical reactions in super2 and subcritical water , including organic reactions , preparation of inorganic particles , the transformof biomass to chemical compounds , and the decomposition of polymers are reviewed.

Key words: supercritical fluids, water, chemical reactions

中图分类号: 

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摘要

超( 近) 临界水中的化学反应