English
往期目录
新闻公告
More
化学进展 2004, Vol. 16 Issue (06): 954- 前一篇   后一篇

• 综述与评论 •

(甲基)丙烯酸氟烷基酯的“活性”/可控聚合*

易玲敏;詹晓力**;陈丰秋   

  1. (浙江大学化学工程与生物工程学系 杭州 310027)
  • 收稿日期:2003-08-01 修回日期:2004-02-01 出版日期:2004-11-24 发布日期:2004-11-24
  • 通讯作者: 詹晓力
下载PDF ( 2301 ) 引用
导出

"Living"/Controlled Polymerization of Fluoroalkyl (Meth)acrylate

Yi Lingmin;Zhan Xiaoli**;Chen Fengqiu   

  1. (Department of Chemical and Biochemical Engineering, Zhejiang University,Hangzhou 310027,China)
  • Received:2003-08-01 Revised:2004-02-01 Online:2004-11-24 Published:2004-11-24
  • Contact: Zhan Xiaoli
带氟烷基侧链的(甲基)丙烯酸氟烷基酯聚合物是一类具有独特表面性能和光学特性的氟聚合物,传统的自由基共聚合由于无法调节聚合物的微细结构和氟原子的分布,限制了该类聚合物在更广领域的应用.活性聚合为聚合物分子设计和合成提供了一个有效方法,利用活性聚合方法可以获得预期结构和性能的含氟嵌段聚合物材料.由于引入了氟烷基侧链,(甲基)丙烯酸氟烷基酯的活性聚合又有其特殊性,本文针对它的活性阴离子聚合、基因转移聚合、活性自由基聚合等方面作一综述.
关键词： (甲基)丙烯酸氟烷基酯, 氟聚合物, 活性聚合, 可控聚合
As a special kind of fhioropolymers, (meth) acrylate polymers with fluoroalkyl side chains exhibit unique surface properties and optical characteristics, but their further applications are limited because the traditional free radical polymerization is unable to control the polymer microstructure and the distribution of fluorine. Living polymerization meth-ods provide an efficient route to polymer chain architecture. Fluorine- containing block polymeric materials with anticipat-ed structures and properties can he synthesized by living polymerization techniques. Due to the fluoroalkyl side chain, the living polymerization of fluoroalkyl (meth)acrylate thus has its specialties. In this paper, the living anionic polymeriza-tion, group transfer polymerization and living radical polymerization of fluoroalkyl (meth)acrylate are reviewed.
Key words: fluoroalkyl (meth)acrylate, fluoropolymer, living polymerization, controlled polymerization

中图分类号: 

()

[ 1 ] Narita T. Prog. Polym. Sci . , 1999 , 24 : 1095 —1148
[ 2 ] Jariwala C P , Mathias L J . Macromolecules , 1993 , 26 ( 19) :5129 —5136
[ 3 ] Perrier S , Jackson S G, Haddleton D M, et al . Tetrahedron ,2002 , 58 : 4053 —4059
[ 4 ] Desimone J M, Guan Z, Elsbernd C S , et al . Science , 1992 ,257 : 945 —947
[ 5 ] Katano Y, Tomono H , Nakajima T. Macromolecules , 1994 , 27 :2342 —2344
[ 6 ] Stone M, Nevell T G, Tsibouklis J . Mater. Lett . , 1998 , 37 :102 —105
[ 7 ] Li K, Wu P , Han Z. Polymer , 2002 , 43 : 4079 —4086
[ 8 ] Shimizu T, Tanaka Y, Kutsumizu S , et al . Macromolecules ,1993 , 26 : 6694 —6696
[ 9 ] Shimizu T, Tanaka Y, Kutsumizu S , et al . Macromolecules ,1996 , 29 : 156 —164
[10] Lüning J , Stêhr J , Song K Y, et al . Macromelcules , 2001 , 34 :1128 —1130
[11] 王秀霞(Wang X X) , 曹成波(Cao C B) , 冯圣玉(Feng S Y) .化工进展(Chemical Industry and Engineering Progress) , 2002 ,21 (12) : 908 —911 , 921
[12] Schmidt D L , Coburn C E , Dekoven B M, et al . Nature , 1994 ,368 : 39 —41
[13] Linemann R F , Malner T E , Brandsch R , et al . Macromolecules ,1999 , 32 : 1715 —1721
[14] Ciardelli F , Aglietto M, Mirabello L M, et al . Prog. Org. Coat . ,1997 , 32 : 43 —50
[15] Lazzari M, Aglietto M, Castelvetro V , et al . Chem. Mater. ,2001 , 13 : 2843 —2849
[16] Yang S , Wang J , Ogino K, et al . Polym. Prepr. , 1999 , 40 (1) :416 —417
[17] Sundararajan N , Yang S , Ogino K, et al . Chem. Mater. , 2000 ,12 : 41 —48
[18] Kaino T, Katayama Y. Polym. Eng. Sci . , 1989 , 29 ( 17 ) :1209 —1214
[19] 顾陈斌(Gu C B) , 王东军(Wang D J ) , 刘世雄(Liu S X) 等.化学进展(Progress in Chemistry) , 2002 , 14 (5) : 398 —404
[20] Webster O W. Science , 1991 , 251 : 887 —893
[21] Iyengar D R , Perutz S M, Dai C A , et al . Macromolecules ,1996 , 29 : 1229 —1234
[22] Szwarc M. Nature , 1956 , 178 : 1168 —1169
[23] Webster O W, Hertler W R , Sogah D Y, et al . J . Am. Chem.Soc. , 1983 , 105 : 5706 —5708
[24] Otsu T, Yoshida M. Makromol . Chem. , Rapid Commun. , 1982 ,3 : 127 —132
[25] Otsu T, Yoshida M, Tazaki T. Makromol . Chem. , Rapid Commun. , 1982 , 3 : 133 —140
[26] Georges M K, Veregin R P N , Kazmaier P M, et al . Macromolecules , 1993 , 26 : 2987 —2988
[27] Wayland B B , Poszmik G, Mukerjee S L. J . Am. Chem. Soc. ,1994 , 116 : 7943 —7944
[28] Wang J S , Matyjaszewski K. J . Am. Chem. Soc. , 1995 , 117 :5614 —5615
[29] Wang J S , Malyjaszawski K. Macromolecules , 1995 , 28 : 7901 —7910
[30] Chiefari J , Chong (Bill) Y K, Ercole F , et al . Macromolecules ,1998 , 31 : 5559 —5562
[31] Rizzardo E , Chiefari T, Mayadunne R T A , et al . Polym.Prepr. , 1999 , 40 : 342 —343
[32] Ishizone T, Sugiyama K, Sakano Y, et al . Polym. J . , 1999 , 31(11/12) : 983 —988
[33] Allen R D , Long T E , McGrath. Polym. Bull . , 1986 , 15 :127 —134
[34] Varshney S K, Hautekeer J P , Fayt R , et al . Macromolecules ,1990 , 23 : 2618 —2622
[35] Narita T, Hagiwara T, Hamana H. Makromol . Chem. , Rapid Commun. , 1985 , 6 : 5 —7
[36] Narita T, Hagiwara T, Hamana H , et al . Polym. J . , 1989 , 21(11) : 925 —928
[37] Narita T, Hagiwara T, Hamana H , et al . Polym. Bull . , 1989 ,21 : 119 —124
[38] Narita T, Hagiwara T, Hamana H. Makromol . Chem. , Rapid Commun. , 1985 , 6 : 175 —178
[39] Narita T, Hagiwara T, Hamana H , et al . Makromol . Chem. ,1986 , 187 : 731 —737
[40] Narita T, Hagiwara T, Hamana H , et al . Makromol . Chem. ,1987 , 188 : 273 —279
[41] Narita T, Hagiwara T, Hamana H , et al . Makromol . Chem. ,1986 , 187 : 739 —744
[42] Yashida E , Wells S L , Desimone J M. Polym. Prepr. , 2000 , 41(1) : 185 —186
[43] Ye W, Wells S , DeSimone J M. J . Polym. Sci . , Part A: Polym.Chem. , 2001 , 39 : 3841 —3849
[44] Ye W, DeSimone J M. Polym. Prepr. , 2001 , 42 (2) : 340 —341
[45] Sogah D Y, Hertler W R , Webster O W, et al . Macromolecules ,1987 , 20 : 1473 —1488
[46] Krupers M J , M? ller M. J . Fluorine Chem. , 1997 , 82 : 119 —124
[47] Krupers M J , Cabelo F M E , Mê ller M. Macromol . Symp. ,1996 , 102 : 99 —106
[48] Krupers M, Mê ller M. Macromol . Chem. Phys. , 1997 , 198 :2163 —2179
[49] Xiang M, Yang S , Ober C K. Polym. Prepr. , 1998 , 39 (2) :974 —975
[50] Guan Z, Desimone J M. Macromolecules , 1994 , 27 : 5527 —5532
[51] Kassis C M, Steehler J K, Betts D E , et al . Macromolecules ,1996 , 29 : 3247 —3254
[52] Arnold M E , Nagai K, Freeman B D , et al . Macromolecules ,2001 , 34 : 5611 —5619
[53] Arnold M E , Nagai K, Spontak R J , et al . Macromolecules ,2002 , 35 : 3697 —3707
[54] Roussel J , Boutevin B. J . Fluorine Chem. , 2001 , 108 : 37 —45
[55] Zhang Z, Shi Z, Ying S. Polym. Prepr. , 1998 , 39 (2) : 820 —821
[56] Ying S K, Zhang Z B , Wang S R , et al . Polym. Prepr. , 1999 ,40 (2) :1051 —1052
[57] 张兆斌(Zhang Z B) , 施志清(Shi Z Q) , 应圣康( Ying S K) .合成橡胶工业(China Synthetic Rubber Industry) , 1999 , 22(3) : 177
[58] Zhang Z B , Ying S K, Hu Q H , et al . Polym. Prepr. , 1999 , 40(2) : 1030 —1031
[59] Zhang Z B , Ying S K, Shi Z Q. Polymer , 1999 , 40 : 5439 —5444
[60] 李虹(Li H) , 张兆斌(Zhang Z B) , 胡春圃(Hu C P) , 应圣康(Ying S K) . 合成橡胶工业(China Synthetic Rubber Industry) ,2001 , 24 (5) : 302
[61] 武兵(Wu B) , 李欣欣(Li X X) , 焦健(Jiao J ) 等. 华东理工大学学报(Journal of East China University of Science and Technology) , 2001 , 27 (1) : 60 —63 , 112
[62] 李鲲(Li K) , 郭建华(Guo J H) , 李欣欣(Li X X) 等. 高分子学报(Acta Polymerica Sinica) , 2002 , (2) : 235 —241
[63] Xia J , Johnson T, Gaynor S G, et al . Macromolecules , 1999 , 32(15) : 4802 —4805
[64] 刘兵(Liu B) , 袁才根(Yuan C G) , 胡春圃(Hu C P) . 合成橡胶工业(China Synthetic Rubber Industry) , 2000 , 23 (6) : 377
[65] Liu B , Yuan C G, Hu C P. Macromol . Chem. Phys. , 2001 ,202 : 2504 —2508
[66] Zhang Z B , Ying S K, Zhang Q L , et al . J . Polym. Sci . , Part A: Polym. Chem. , 2001 , 39 : 2670 —2676
[67] Haddleton D M, Jackson S G. Polym. Prepr. , 1999 , 40 (2) :968 —969
[1] 衡婷婷, 张慧, 陈明学, 胡欣, 方亮, 陆春华. 接枝改性PVDF基含氟聚合物[J]. 化学进展, 2021, 33(4): 596-609.
[2] 张浩, 许芳, 王合营, 姜涛, 马志. 基于聚亚甲基的新型共聚物的可控合成[J]. 化学进展, 2018, 30(2/3): 179-189.
[3] 李东翰, 齐士成, 张孝阿, 廖明义. 低分子量含氟聚合物的制备、官能化及特性[J]. 化学进展, 2016, 28(5): 673-685.
[4] 荣雷, 宁英男, 高金苹, 毛国梁, 马志. 基于叶立德同源聚合的聚烯烃功能化研究[J]. 化学进展, 2014, 26(08): 1369-1377.
[5] 张勇杰, 李化毅, 董金勇, 胡友良. 端基功能化聚烯烃的合成与应用[J]. 化学进展, 2014, 26(01): 110-124.
[6] 刘虎,王文浩,胡晓熙,彭慧,易昌凤,徐祖顺. 乳液原子转移自由基聚合*[J]. 化学进展, 2009, 21(6): 1292-1298.
[7] 王琼燕 张庆华 詹晓力 陈丰秋. 低表面能侧基含氟聚合物*[J]. 化学进展, 2009, 21(10): 2183-2187.
[8] 闫强,隋晓锋,袁金颖. 活性聚合在星形聚合物合成中的应用*[J]. 化学进展, 2008, 20(10): 1562-1571.
[9] 吕维华,王荣民,何玉凤,张慧芳. 智能涂料制备方法探索与应用*[J]. 化学进展, 2008, 20(0203): 351-361.
[10] 李虹,徐安厚,张永明. 超临界二氧化碳中含氟聚合物的合成*[J]. 化学进展, 2007, 19(10): 1562-1567.
[11] 赵群,倪沛红. pH/温度响应的两亲性嵌段共聚物的研究*[J]. 化学进展, 2006, 18(06): 768-779.
[12] 孟诗云,李光宪,杨其,黄亚江. 用于光致抗蚀剂的聚对羟基苯乙烯的合成及其进展[J]. 化学进展, 2004, 16(02): 243-.
[13] 顾陈斌,王东军,刘世雄,王歆秋,黄勇,甄珍,刘新厚. 含氟高分子材料在塑料光纤中的应用[J]. 化学进展, 2002, 14(05): 398-.
[14]

谷国团,张治军,党鸿辛,

. 低自由能固体表面的制备及其应用*[J]. 化学进展, 2002, 14(03): 158-.