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化学进展 2004, Vol. 16 Issue (04): 561- 前一篇   后一篇

• 综述与评论 •

[60]富勒烯衍生物的对称性、碳笼结构与13C NMR谱*

刘书芝 唐光诗**   

  1. (北京化工大学可控化学反应化学与技术基础教育重点实验室 北京 100029)
  • 收稿日期:2003-05-01 修回日期:2003-07-01 出版日期:2004-07-26 发布日期:2004-07-26
  • 通讯作者: 唐光诗
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Symmetry,Cage Structure of[60]Fullerene Derivatives and 13C NMR Spectroscopy

Liu Shuzhi;Tang Guangshi**   

  1. (The Key Laboratory of Science and Technology of Controlleble Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China)
  • Received:2003-05-01 Revised:2003-07-01 Online:2004-07-26 Published:2004-07-26
  • Contact: Tang Guangshi
本文全面综述了多种[60]富勒烯衍生物的结构,阐述了(13)~C NMR谱在[60]富勒烯衍生物结构表征中的应用,重点讨论了不同对称性[60]富勒烯衍生物的(13)~C NMR谱图特征.通过[60]富勒烯部分(13)~C共振线的化学位移、数目和相对强度,可以确定[60]富勒烯衍生物的对称结构和加成方式.对于C_s、C_(2v)和C_(3v)对称性的[60]富勒烯衍生物,镜面上的碳原子的相对化学位移很大程度上取决于他们距加成位置的距离.因此,(13)~C NMR谱在碳笼具体结构的确定中具有不可替代的作用.
关键词： [60]富勒烯衍生物, 13C NMR, 结构表征, 对称性
The structure of all kinds of [60]fullerene derivatives and their characterization via (13)~C NMR spectros-copy are reviewed and the (13)~C NMR spectroscopic properties of various symmetry [60]fullerene derivatives are mainly dis-cussed . From the chemical shifts, the number and the relative intensity of resonances for [60]fullerene moiety, symmetry and addition pattern of [60]fullerene derivatives can be confirmed. For the C_s, C_(2v) and C_(3v) symmetry [60]fullerene de-rivatives , the relative chemical shift of the carbon atoms on the mirror planes depends greatly upon their distance from ad-dition position on the surface of [60]fullerene. So (13)~C NMR spectroscopy plays the important role in identification of the particular structure of [60]fullerene cage.
Key words: [60]fullerene derivatives, 13C NMR spectroscopy, characterization, symmetry

中图分类号: 

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