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化学进展 2004, Vol. 16 Issue (04): 500- 前一篇   后一篇

• 综述与评论 •

有机大分子导向无机纳米粒子的分级有序自组装*

袁建军 翟锦 江雷**   

  1. (中国科学院化学研究所 分子科学中心 北京 100080)
  • 收稿日期:2003-04-01 修回日期:2004-01-01 出版日期:2004-07-26 发布日期:2004-07-26
  • 通讯作者: 江雷
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Hierarchical Self-Assembly of Inorganic Nanoparticles Mediated by Organic Macromolecules

Yuan Jianjun;Zhai Jin;Jiang Lei**   

  1. (The Center of Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences,Beijing 100080, China)
  • Received:2003-04-01 Revised:2004-01-01 Online:2004-07-26 Published:2004-07-26
  • Contact: Jiang Lei
本文主要综述了基于特定分子设计的有机大分子导向下的无机纳米粒子的分级有序自组装.可以有效导向无机纳米粒子组织的有机大分子主要包括合成大分子和生物大分子,前者如具有氢键识别功能的大分子、聚电解质、嵌段大分子、树枝状大分子;后者如DNA、糖类以及蛋白质.所涉及的无机纳米粒子通常需要通过单层修饰使之与特定的大分子具有识别功能,或者设计表面带有正或负电荷使之与带有负或正电荷的大分子相互识别.该领域的研究在先进功能材料及仿生材料方面具有重要意义.
关键词： 自组装, 无机纳米粒子, 大分子, 分级有序
The hierarchical self-assembly of inorganic nanoparticles mediated by the tailed organic macromolecules has been reviewed. The organic macromolecules used for the mediators include the synthetic polymers and the biopoly-mers. Up to now, the polymers with hydrogen-bond recognition functionality, polyelectrolytes, block copolymers and den-drimers have been developed as synthetic polymers for the assembly of the inorganic nanoparticles. At the same time, DNA, amylose and proteins also present the impressive ability for the ordered aggregation of inorganic nanoparticles. It is necessary for the hierarchical assembly of inorganic nanoparticles to modify them to afford their surfaces tailored function-ality , for example hydrogen-bond recognition groups, positive charges, negative charges, and so on, which can recognize with the organic mediators. This research field is very essential for the construction of advanced functional materials and biomimetic materials.
Key words: self-assembly, inorganic nanoparticles, macromolecules, hierarchical order

中图分类号: 

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