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化学进展 2004, Vol. 16 Issue (01): 68- 前一篇   后一篇

• 综述与评论 •

高灵敏度高选择性气敏材料--金属酞菁配合物

左霞1,2;韦永德1;吴谊群2**   

  1. (1. 哈尔滨工业大学应用化学系 哈尔滨 150001; 2. 黑龙江大学功能材料实验室 哈尔滨 150080)
  • 收稿日期:2002-10-01 修回日期:2003-04-01 出版日期:2004-01-24 发布日期:2004-01-24
  • 通讯作者: 吴谊群
下载PDF ( 2750 ) 引用
导出 被引次数 ( 82 | 2 )

High Sensitive and Selective Gas Sensing Materials --Metallophthalocyanines

Zuo Xia1,2;Wei Yongde1;Wu Yiqun2**   

  1. (1. Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China; 2. Laboratory of Functional Materials, Heilongjiang University, Harbin 150001, China)
  • Received:2002-10-01 Revised:2003-04-01 Online:2004-01-24 Published:2004-01-24
  • Contact: Wu Yiqun
酞菁配合物是一类重要的光电功能材料.由于它的特殊结构使其成为高灵敏度高选择性气敏材料,具有极好的应用前景.本文在介绍酞菁配合物的结构特点、合成方法、气敏特性及其最新研究进展的基础上,讨论了酞菁配合物的气敏机理及膜结构、中心金属和取代基对气敏性的影响,并对酞菁配合物作为气敏材料的发展趋势进行了展望。
关键词： 酞菁配合物, 膜结构, 气敏特性
Metallophthalocyanine is important photoelectronic functional material. Its unique structure has resulted in the application to sensor materials with high sensitivity and selectivity. The synthetic methods, thin film structures, sensing characteristics and the development of metallophthalocyanines are reviewed in this paper. The gas-sensing mecha-nism and influence of central atoms, thin film structure and substituents on gas-sensitivity are illustrated. The recent de-velopment and the trends of metallophthalocyanine gas sensor materials are discussed.
Key words: metallophthalocyanines, thin film structures, gas sensing characteristics

中图分类号: 

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