新型无机聚合物的设计合成、结构规律与性能研究*

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化学进展 ›› 2003, Vol. 15 ›› Issue (04) : 249.

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洪茂椿,吴新涛,曹荣,黄群,苏伟平. 新型无机聚合物的设计合成、结构规律与性能研究^[J]. 化学进展, 2003, 15(04): 249 Hong Maochun^,Wu Xintao,Cao Rong,Huang Qun,Su Weiping. Syntheses, Structures and Properties of Three Series of Novel Inorganic Polymers[J]. Progress in Chemistry*, 2003, 15(04): 249

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新型无机聚合物的设计合成、结构规律与性能研究^*

洪茂椿^**;吴新涛;曹荣;黄群;苏伟平

作者信息 +

Syntheses, Structures and Properties of Three Series of Novel Inorganic Polymers

Hong Maochun^**;Wu Xintao;Cao Rong;Huang Qun;Su Weiping

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文章历史 +

摘要

本文以新型无机聚合物的合理合成和物理性能研究为主线, 总结3个系列具有新颖结构聚合物的组装与结构化学规律: (1)通过化学自组装法设计合成出系列金属-有机纳米笼、金属-有机纳米管和金属-有机纳米线.研究了合成金属-有机纳米分子的规律,开辟了一条合成金属-有机纳米分子的新途经.(2)通过结构调控、金属与桥联基元作用,把团簇单元活化后合成一维新型无机聚合物.在研究反应机理过程中分离和表征了大量的中间态产物,从而得到了这类聚合物合理合成的规律.(3)设计合成出二维层状(石墨型)、三维大孔(分子筛型)、金属聚硫及稀土与过渡金属混合4个系列新型的无机聚合物,总结了它们的结构规律和反应规律.在制备合成中既有结构单元自组装的反应又有设计合成的方法.通过系列化合物的结构表征和光、电或磁性能的研究, 探索出系列聚合物具有半导体性能和非线性光学性能,总结出聚合物的结构规律与基本结构单元组装的关系以及结构与性能的关系.

Abstract

The syntheses, structures and properties, including conductivity and magnetic properties of three series of novel inorganic polymers prepared using transition metal ions and organic ligands are summarized. The following aspects are discussed: (1) the self-assembly reactions and structures of the novel nano-cages, nano-tubes and nano-wire; (2) the design, syntheses, structures and conducting properties of a series of ID W(Mo)/Ag/S thiometalate polymers; (3) the synthetic approach, structural rule, and physical properties of coordination polymers having 2D lamellar structures constructed by organosulfur ligands and transition metal salts.

关键词

无机聚合物 / 设计合成 / 自组装合成 / 结构

Key words

inorganic polymer / synthesis design / self-assembly / structure

中图分类号： O611.4 O635

参考文献

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