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可逆型化学振荡器
- 翟俊红;贺占博*
作者信息
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versible Chemical Oscillators
- Zhai Junhong;He Zhanbo*
Author information
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文章历史
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摘要
该文给出了可逆型化学振荡器的定义、意义和可能存在的类型。这些类型包括：（1）自发乳化，通电破乳；（2）乳液中自发产生的甘油三酯水解振荡反应及通电逆向酯化反应；（3）用表面活性剂有机溶液代替盐桥，形成新型的电化学振荡，通电逆向电解。文章对这3种类型可逆型化学振荡器的来源、组成、实验方法、理论分析方法和应用前景进行了深入的讨论和分析。它们还可以进一步组合，形成更多的类型。其主要的研究方法为用正交实验确定最佳配方，由相关分析确定影响因素。这些可逆型化学振荡器的关键组分都是表面活性剂，是表面活性剂在非线性化学动力学研究中的又一应用。对可逆型化学振荡器的研究必将大大促进远离平衡态的复杂反应动力学研究及新型交流蓄电池的开发设计。
Abstract
The definition, significance and possible type of reversible chemical oscillator has been given. The types include: (l)spontaneous emulsion and electrifying demulsion; (2Spontaneous oscillatory reaction of triglyceriedes hydrolysis in the emulsion and electrifying esterification; (3Substitution of salt bridge with surfactant solution to form new type electric chemical oscillator and then electrolyze to converse reaction. The sources, components, experimental methods, theoritical analysis methods and potential application of the three reversible chemical oscillators have been disscussed and analyzed thoroughly. They can be combined further and form more types. Surfactant is key component of the reversible chemical oscillator which is another application of surfactant in the study of nonlinear chemical kinetics. The study of reversible chemical oscillator will accelerate greatly and consequentially the research of complexity reaction kinetics removed from equilibrium state and the design of new kind of secondary batteries.
关键词
可逆 / 化学振荡器 / 自发振荡 {{custom_keyword}} /
Key words
eversibility / chemical oscillators / spontaneous oscillation {{custom_keyword}} /
中图分类号：
O643.1
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参考文献
[ 1 ] 辛厚文. 非线性化学. 中国科学技术大学出版社, 1999
[ 2 ] 刘君利(Liu J L ). 化学通报(Chem. Bull. ) , 1987, (11) :1—4
[ 3 ] 贺占博(He Z B). 化学通报(Chem. Bull. ) , 1992, (2) :57—62
[ 4 ] 贺占博(He Z B). 化学工业与工程(Chem. Ind. Eng. ) ,1992, 9 (4) : 29— 32
[ 5 ] Winfree A T. Science, 1994, (266) : 1003—1006
[ 6 ] 吉久宽, 宫村一夫. 分析(日) (Bunseki) , 1996, 8: 609—615
[ 7 ] 张庆元(Zhang Q Y). 分析实验室(Anal. Lab. ) , 1988, 7(9) : 4—7
[ 8 ] 荒井健介(Kensuke Arai). 分析化学( 日) (Bunseki Kagaku) , 1996, 45 (1) : 41—53
[ 9 ] 林振山(Lin Z S). 北京大学博士学位论文(Doctoral Dissertation in Peking University) , 1991
[ 10 ] 黄仲涛(Huang Z T ). 化工进展(Chem. Eng. Progress) ,1987, (5) : 10
[ 11 ] 贺占博(He Z B). 化学通报网络版(Chem. Bull. W. ) ,2001, (6) : 55
[ 12 ] Field R J , Koros E, Noges R M. J. Am. Soc. , 1972, 94:8649—8664
[ 13 ] Epstein I R. Chem. Eng. N ew s, 1987, 65 (13) : 24—36
[ 14 ] Nicolis G, Prigogine I. Self-organization in Nonequilibrium Systems, New York: Wiley, 1977
[ 15 ] Gray P, Scott S K. Chemical Oscillations and Instabilities:Nonlinear Chemical Kinetics. Oxford: Oxford Univ.Press, 1994
[ 16 ] Epstein I R, Showalter K. J. Phys. Chem. 1996, 100(31) : 13132—13147
[ 17 ] 贺占博(He Z B) , 阎喜龙(Yan X L ) , 聂玉敏(Nie Y). 物理化学学报, (Acta Phys. -Chim. Sin. ) , 1999, 15 (4) :370—374
[ 18 ] He Z B, Zhang B, Li G M. Ch in. Sci. Bull. , 1997, 42(14) : 1525—1528
[ 19 ] Field R J , Burger M. Oscillations and Traveling Waves in Chemical Systems. John Wiley & Sons Inc. , 1985
[ 20 ] 贺占博(He Z B). 化学通报(Chem. Bull. ) , 2000, 63 (8) :54 —59
[ 21 ] Yukihiro S, et al. Curr. Top. Electrochem. , 1998, 6:75—95
[ 22 ] 贺占博(He Z B) , 张向华(Zhang X H ) , 曹汇川(Cao H C). 物理化学学报(Acta Phys. -Chim. Sin. ) , 2001, 17(3) : 238—240
[ 23 ] Yoshikawa K, Matsubara Y. J. Am. Chem. Soc. , 1983,105 (19) : 5967—5969
[ 24 ] Cervellati R, Solda R. Am. J. Phys. 2001, 69 (5) : 543—545
[ 25 ] Yosihiro I. CN 1 120 063A , U S 5 620 570A , JP 240 775/94
[ 26 ] Kohji M , Sorin K. Surfactant Sci. Ser. , 2001, 95: 609—628
[ 27 ] Yoshikawa K. Matsubara Y. Langmuir, 1985, 1 ( 2 ) :230—232
[ 28 ] 吉川研一(Yoshikawa K). 表面(日) (Hyomen) , 1988, 26(10) : 786—795
[ 29 ] Dupeyrat M , Nakache E. Bioelectrochem. Bioenerg. ,1978, 5 (1) : 134—141
[ 30 ] Yoshikawa K, Matsubara Y. J. Am. Chem. Soc. , 1984,106 (16) : 4423—4427
[ 31 ] 赵国玺. 表面活性剂物理化学. 北京: 北京大学出版社,1984
[ 32 ] Larter R. Chem. Rev. , 1990, 90 (2) : 355 —381
[ 33 ] 贺占博(He Z B). 大学化学(Univ. Chem. ) , 1992, 7 (6) :29—42
[ 34 ] Hennenberg M , et al. J. Coll. Interf. Sci. , 1980, 74 (2) :495—508
[ 35 ] Nakache E, Dupeyrat M. J. Chem. Soc. : Faraday Discuss, 1984, (77) : 189—196
[ 36 ] Davies T V , R ideal E K. Interfacial Phenomena. New York and London: Academic Press, 1961
[ 37 ] 顾惕人, 朱步瑶, 马季铭等. 表面化学. 北京: 科学出版社, 1994
[ 38 ] Hitoshi S, Yoshimi T. Physica D. , 1995, 84: 276—279
[ 39 ] Bekki S, Vignes-Adler M , Nakache E. J. Colloid Interface Sci. , 1992, 152 (2) : 314—24
[ 40 ] Slavtchev S, Hennenberg M , et al. J. Colloid Interface Sci. , 1998, 203: 354—368
[ 41 ] Tan E, Thoroddsen S T. Phys. Fluids, 1998, 10 ( 2) :3038—3040
[ 42 ] Slavtchev S G. Microgravity Sci . Technol. , 1998, 11(1) : 29—34
[ 43 ] Mendes-Tatsis M A , Agble D. J. Non-Equilib. Thermoddyn. , 2000, 25 (3/4) : 239—249
[ 44 ] Agble D, Mendes-Tatsis M A. Int. J. Heat Mass Transfer, 2001, 44 (7) : 1439—1449
[ 45 ] Zuo X B, Hou Z H, Xin H W. J. Chem. Phys. , 1998,109 (14) : 6063—6066
[ 46 ] 贺占博(He Z B) , 化学通报(Chem. Bull. ) , 1990, 2: 50— 53
[ 47 ] 邱志新(Qiu Z X) , 王寿祥(Wang S X). 化学学报(Acta Chim. Sinica) , 1992, 50 (12) : 1169—1172
[ 48 ] Yoshikawa K, Makino M. Chem. Phys. Lett. , 1989,160 (5, 6) : 623—626
[ 49 ] Yoshikawa K, Kawakami H. Ferroelectrics, 1988, 86:281—298
[ 50 ] 王寿祥(Wang S X) , 邱志新(Qiu Z X) , 物理化学学报(Acta Phys. -Chim. Sin. ) , 1993, 9 (2) : 273—275
[ 51 ] Nakache E, Dupeyrat M , Viges-Adler M. J. Colloid Interface Soc. , 1983, 94 (1) : 187—200
[ 52 ] Kovalchuk V I, Kamusewitz H. Phys. Rev. E, 1999, 60(22B) : 2029—2036
[ 53 ] Kovalchuk N M , Vollhardt D. J. Phys. Chem. B, 2000,104 (33) : 7987—7992
[ 54 ] Kovalchuk N M , Vollhardt D. J. Phys. Chem. B, 2001,105 (20) : 4709—4714
[ 55 ] Kovalchuk N M , Kovalchuk V I, Vollhardt D. Phys.Rev. E, 2001, 63 (321) : 031604/1—10
[ 56 ] Egbogah E O , Dave R A. J. Chem. Technol. Biotechnol. , 1985, 35A (3) : 132—144
[ 57 ] 戴乐蓉(Dai L R) , 苏晓燕(Su X Y). 物理化学学报(Acta Phys. -Chim. Sin. ) , 1995, 11 (9) : 831—835
[ 58 ] Miller A. Colloids Surf. , 1988, 29 (1) : 89—102
[ 59 ] Vermeulen M , Joos P, Gkosh L. J. Colloid Interface Sci. , 1990, 140 (1) : 41—47
[ 60 ] Granek R, et al. J. Phys. ê. , 1993, 3 (6) : 829—849
[ 61 ] Rudin J , W asan D T. Chem. Eng. Sci. , 1993, 48 ( 2) :2225—2238
[ 62 ] Shahidzadeh N , Bonn D, Meunier J. Europhys. Lett. ,1997, 40 (4) : 459—464
[ 63 ] Shahidzadeh N , Bonn D, et al. Langmuir, 2000, 16 (25) :9703—9707
[ 64 ] Prince L-M. J. Colloid Interface Sci. , 1967, 23: 165—173
[ 65 ] Gurwitsch L. Wissenschaftliche Grundlagender Erdolbearitung, 1913. 200 ( translation by Moore, London:Chapman and Hull Ltd, 1932. 430)
[ 66 ] Ruschak K J , Miller S C. Ind. Eng. Chem. Fundam. ,1972, 11 (4) : 534—540
[ 67 ] Groves M J. Chemistry and Industry, 1978, 12: 417—423
[ 68 ] Wakerly M G, Pouton C W , et al. Phenomena in Mixed Surfactant Systems. ACS Symp. Ser. 311 (ed. Scamehorn J F). 242ff
[ 69 ] 贺占博(He Z B) , 阎喜龙(Yan X L ) , 聂玉敏(Nie Y M ).化学工业与工程(Chem. Ind. Eng. ) , 2001, 18 (3) : 130—136
[ 70 ] 胡学铮(Hu X Z) , Vignes-Alder M 等. 无锡轻工业学院学报(J. Wuxi Light-industry College) , 1994, 13 (2) : 129
[ 71 ] 胡学铮(Hu X Z) , Vignes-Alder M 等. 物理化学学报(Acta Phys. -Chim. Sin. ) , 1997, 13 (10) : 873—877
[ 72 ] 金利通(Ji L T) , 宋丰斌(Song F B) 等. 自然杂志(J. Nature) , 1992, 15 (8) : 587
[ 73 ] 金利通(Jin L T) , 毛煜(Mao Y) , 刘彤(Liu T) 等. 分析科学学报(Acta Anal. Sci. ) , 1994, 10 (2) : 16—20
[ 74 ] 金利通(Jin L T) , 毛煜(Mao Y) , 刘彤(Liu T) 等. 分析科学学报(Acta Anal. Sci. ) , 1995, 11 (4) : 11—14
[ 75 ] 邱志新(Qiu Z X) , 王寿祥(Wang Z X) 等. 化学研究与应用(Chem. Res. Appl. ) , 1992, 4: 103
[ 76 ] 王寿祥(Wang S X) , 邱志新(Qiu Z X) 等. 上海师范大学学报(J. Shanghai Norm. Univ. ) , 1991, 20 (3) : 35
[ 77 ] Li H X, Lu J , Li P H. Chin. Sci. Bull. , 1998, 43 (12) :1008—1011
[ 78 ] Qi F, Xin H. Biophys. Chem. , 2001, 90 (2) : 175—182
[ 79 ] 祁丰(Qi F) , 辛厚文(Xin H W ). 自然杂志(J. Nature) ,2000, 22 (5) : 308—309
[ 80 ] Elfie P. Ger. Offen. DE 4 003 731 (Cl. B01D17)
[ 81 ] Drelich J , et al. Fuel Process. Technol. , 1992, 31 (2) :105—113
[ 82 ] 王连成(Wang L C) , 严忠(Yan Z). 石油炼制(Oil Proc. ) ,1992, (7) : 47—53
[ 83 ] 井野一(Hajime I) , 今石宣之(Nobuyuk i I) , 宝泽光纪(Mitsunori H ). 化学工学论文集(Kagaku Kogaku Ronbunshu) , 1992, 18 (6) : 819—826
[ 84 ] 谢琦(Xie Q ) , 严忠(Yan Z). 化学物理学报(Acta Chim Phys. Sin. ) , 1992, 5 (3) : 212—217
[ 85 ] 谢琦(Xie Q ) , 严忠(Yan Z). 膜科学与技术(Membrane Sci. Techn. ) , 1993, 13 (1) : 51—55
[ 86 ] Ogutveren U B, Koparal S. J. Environ. Sci. Health,1997, A 32 (9&10) : 2507—2520
[ 87 ] Pearce C A R, et al. Brit. J. Appl. Phys. , 1954, 5 (4)
[ 88 ] 沈钟, 王国庭. 胶体表面化学. 北京: 化学工业出版社,1997
[ 89 ] 贺占博(He Z B). 自然杂志(J. Nature) , 2001, 23 (4) :231—234
[ 90 ] 贺占博(He Z B). 化学通报网络版(Chem. Bull. W. ) ,2001, 6: 55
[ 91 ] He Z B, Qi G. J. Chin. Chem. , 2001, 19 (7) : 710—713
[ 92 ] 贺占博(He Z B) , 周莹辉(Zhou Y H) , 李冬梅(Li D M ).高等学校化学学报(Chem. J. Chin. Univ. ) , 2001, 22 (10Suppl) : 188—191
[ 93 ] 村形忠弘(Murakata T ) , 化学工学论文集(日) (Kagaku Kogaku Ronbunshu) , 1999, 25 (5) : 728—734
[ 94 ] Fechner G T. Schweigg J. fur Chemie Physik, 1828, 53:129
[ 95 ] Hudson J L , Tsotsis T T. Chem. Eng. Sci. , 1994, 49(10) : 1493—1572
[ 96 ] Suzuki H, Kawakubo T. Biophys. Chem. , 1992, 45 (2) :153—159
[ 97 ] Koper M T M. A dv. Chem. Phys. , 1996, 92: 161—298
[ 98 ] Delgado E J , M unster A F. J. Braz. Chem. Soc. , 1999,10 (6) : 492—496
[ 99 ] Fecher F rank, et al. J. Phys. Chem. A. , 2000, 104(78) : 8715—8722
[ 100 ] Inzclt G. Stud. Univ. BABES2Bo lyai, Chem. , 1996, 41(2) : 47—69
[ 101 ] Belarus G A. Khim. Probl. Sozdaniya Nov. Mater.Tekhnol. , 1998, 451—460
[ 102 ] 徐远航(Xu Y H). 化学通报(Chem. Bull. ) , 1993, (1) :1—7
[ 103 ] Otawara K, Fan L T. Comput. Chem. Eng. , 2001, 25 (223) : 333—335
[ 104 ] ChtainiA , Takky D. ITE Lett. Batteries, New Technol.M ed. , 2000, 1 (6) : 931—937
[ 105 ] Sazou D, Pagitsas M. J. Electroanal. Chem. , 1993, 354(122) : 105—127
[ 106 ] 贺占博(He Z B) , 黄智(Huang Z) , 顾惕人(Gu T R). 自然杂志(J. Nature) , 1991, 14 (6) : 477—478
[ 107 ] He Z B, Huang Z, Gu T R, Ch in. Sci. Bull. , 1996, 41(5) : 380—384
[ 108 ] 贺占博(He Z B) , 黄智(Huang Z) , 顾惕人(Gu T R). 北京大学学报(J. Peking Univ. ) , 1993, 29 (4) : 452—457
[ 109 ] 贺占博(He Z B). 化学通报网络版(Chem. Bull. W. )2000, 3: 26
[ 110 ] 贺占博(He Z B). 化学工业与工程(Chem. Ind. Eng. ) ,2001, 18 (2) : 93 — 98
[ 111 ] Gear C W. Numerical Initial Value Problems in Ordinary Differential Equations. P rentice Hall Inc. , 1971
[ 112 ] 郑重知. 不可逆热力学及现代反应动力学导论. 北京: 高等教育出版社, 1990. 90—97, 491—497
[ 113 ] 赵学庄. 化学反应动力学原理. 北京: 高等教育出版社,1984. 192—197
[ 114 ] 王贵昌(Wang G C) , 赵学庄(Zhao X Z). 计算机与应用化学(Computer and Appl. Chemistry) , 1996, 13 (1) : 65—70
[ 115 ] 王贵昌(Wang G C) , 赵学庄(Zhao X Z). 计算机与应用化学(Computer and Appl. Chemistry) , 1997, 14 (1) : 70—71, 74
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