English
新闻公告
More
化学进展 2003, Vol. 15 Issue (02): 135- 前一篇   后一篇

• 综述与评论 •

有机染料-层状硅酸盐光活性纳米复合材料*

李海艳;李强**   

  1. (中国科学院化学研究所分子科学中心工程塑料国家重点实验室 北京 100080)
  • 收稿日期:2002-01-01 修回日期:2002-11-01 出版日期:2003-03-24 发布日期:2003-03-24
  • 通讯作者: 李强

Organic Dye-Layered Silicate Optical Functional Nanocomposites*

Li Haiyan;Li Qiang**   

  1. (State Key Laboratory of Engineering Plastics, Center for Molecular Science, Institute of Chemistry,Chinese Academy of Sciences, Beijing 100080, China)
  • Received:2002-01-01 Revised:2002-11-01 Online:2003-03-24 Published:2003-03-24
  • Contact: Li Qiang
有机-无机纳米复合材料,尤其是有机客体插层入无机层状固体自组装形成的纳米复合材料,因其独特的微观结构与性能,在超分子构筑纳米材料领域中具有特殊地位。本文主要介绍了光致变色与光致发光光功能性有机染料插层层状硅酸盐纳米复合材料的研究进展,着重讨论了螺吡喃、偶氮、二芳基乙烯、芘、香豆素等染料在二维纳米片层间独特的光学行为、有序排列形态、构筑的多层功能性薄膜及其在光功能性材料开发方面的应用前景。
Organo-inorganic nanocomposites, particularly the self-organized nanocomposites produced by the intercalation of the organic dye guests into the inorganic layered solids, due to their special microstructure and properties, have occupied important place in the field of nanocomposites. In this paper, recent developments in the study of the intercalation of photochromic and photoluminescent dyes, including spiropyran, azobenzene, diarylethenes, coumarine and pyrene, into layered silicates are reviewed. The focus is on the special optical behavior and the highly ordered microstructure of the dyes in the two dimensional layers of silicates. Their applications in optical functional materials are also discussed.

中图分类号: 

()

[ 1 ] Otruba J P, Weiss R G. Mol. Cryst. Liq. Cryst. , 1982,80: 165
[ 2 ] Seki T, Ichimura K. J. Chem. Soc. , Chem. Commun. ,1987, 1187
[ 3 ] Holden D A , Ringsdorf H, Deblauwe V , Smets G. J.Phys. Chem. , 1984, 88: 71
[ 4 ] Ogawa M , Kuroda K. Chem. Rev. , 1995, 95: 399—438
[ 5 ] Takagi K, Kuwahara T, Sawaki Y. J. Chem. Soc. ,Perk in Trans. 2, 1991, 1517
[ 6 ] Tomioka H, Itoh T. J. Chem. Soc. , Chem. Commun. ,1991, 532
[ 7 ] Seki T, Ichimura K. Macromolecules, 1990, 23: 31
[ 8 ] Ogawa M , Fujii K, Kuroda K, Kato C. Mater. Res. Soc.Symp. Proc. , 1991, 233: 89
[ 9 ] Ogawa T, Shigematsu K. J. Am. Chem. Soc. , 1981,103: 111
[ 10 ] Tachibana H, Goto A. J. Am. Chem. Soc. , 1989, 111:3080
[ 11 ] Ogawa M. Chem. Mater. , 1996, 8 (7) : 1347—1349
[ 12 ] Ogawa M , Ishikawa A. J. Mater. Chem. , 1998, 8 (2) :463—467
[ 13 ] Irie M. Chem. Rev. , 2000, 100: 1685
[ 14 ] Sasai R, Ogiso H, Shindachi I, et al. Tetrahedron, 2000,56: 6979—6984
[ 15 ] Sasai R, Itoh H, Shindachi I, et al. Chem. Mater. , 2001,13: 201222016
[ 16 ] Ahmadi M F, Rusling J F. Langmuir, 1995, 11: 94
[ 17 ] Ogawa M , Takahashi M , Kuroda K. Langmuir, 1995,11: 4598
[ 18 ] Endo T, N akada N , Sato T, Shimada M. J. Phys. Chem.Solids, 1989, 50 (2) : 133—137
[ 19 ] Kim D W , Blumstein A , Downey M. Poly. Mater. Sci.Eng. , 2000, 83: 200
[ 20 ] Decher G. Science, 1997, 277: 1232
[ 21 ] Wang X G, Balasubramanian S. Macromol. Rapid Commun. , 1997, 18: 451
[ 22 ] Kim D W , Blumstein A , Downey M. Poly. Mater. Sci.Eng. , 2001, 84: 182
[ 20 ] Wlodarezyk P, Komarneni S, Roy R, White W B. J.Mater. Chem. , 1996, 6 (12) : 1967—1969

[1] 王琦桐, 丁嘉乐, 赵丹莹, 张云鹤, 姜振华. 储能薄膜电容器介电高分子材料[J]. 化学进展, 2023, 35(1): 168-176.
[2] 袁传军, 王猛, 李明, 包金鹏, 孙鹏瑞, 高荣轩. 基于碳点的发光材料在潜在手印显现中的应用[J]. 化学进展, 2022, 34(9): 2108-2120.
[3] 郑明心, 谭臻至, 袁金颖. 光响应Janus粒子体系的构建与应用[J]. 化学进展, 2022, 34(11): 2476-2488.
[4] 冯业娜, 刘书河, 张书博, 薛彤, 庄鸿麟, 冯岸超. 基于聚合诱导自组装制备二氧化硅/聚合物纳米复合材料[J]. 化学进展, 2021, 33(11): 1953-1963.
[5] 施剑林, 华子乐. 无机纳米与多孔材料合成中的凝聚态化学[J]. 化学进展, 2020, 32(8): 1060-1075.
[6] 黄晚秋, 高苗苗, 窦红静. 聚吡咯及其纳米复合材料在光热治疗领域的应用[J]. 化学进展, 2020, 32(4): 371-380.
[7] 贾潞, 马建中, 高党鸽, 吕斌. 层状双氢氧化物/聚合物纳米复合材料[J]. 化学进展, 2018, 30(2/3): 295-303.
[8] 康永印, 宋志成, 乔培胜, 杜向鹏, 赵飞. 光致发光胶体量子点研究及应用[J]. 化学进展, 2017, 29(5): 467-475.
[9] 霍志铭, 李攻科*, 肖小华*. 有机光致变色材料在快速可视化检测中的应用[J]. 化学进展, 2017, 29(2/3): 252-261.
[10] 茹静, 耿璧垚, 童聪聪, 王海英, 吴胜春, 刘宏治. 纳米纤维素基吸附材料[J]. 化学进展, 2017, 29(10): 1228-1251.
[11] 朱世琴, 李文龙, 朱为宏. 新型烯桥二芳基乙烯光致变色体系[J]. 化学进展, 2016, 28(7): 975-992.
[12] 高党鸽, 梁志扬, 吕斌, 马建中. 细乳液聚合法制备有机/无机纳米复合材料[J]. 化学进展, 2016, 28(7): 1076-1083.
[13] 张勇杰, 李化毅, 董金勇, 胡友良. 聚烯烃共价键接枝纳米材料及其聚烯烃纳米复合材料[J]. 化学进展, 2015, 27(1): 47-58.
[14] 周素坤, 毛健贞, 许凤. 微纤化纤维素的制备及应用[J]. 化学进展, 2014, 26(10): 1752-1762.
[15] 仇实, 郑景伟, 杨贵堂, 郑经堂, 吴明铂, 吴文婷. 三维有序大孔炭的设计构筑、性能及应用研究[J]. 化学进展, 2014, 26(05): 772-783.