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化学进展 2003, Vol. 15 Issue (02): 101- 前一篇   后一篇

• 综述与评论 •

锂无机固体电解质*

郑子山1,2**;张中太1;唐子龙1;沈万慈1   

  1. （1. 清华大学材料系新型陶瓷与精细工艺国家重点实验室 北京 100084； 2. 福建省漳州师范学院化学系 漳州 363000）
  • 收稿日期:2002-01-01 修回日期:2002-03-01 出版日期:2003-03-24 发布日期:2003-03-24
  • 通讯作者: 郑子山
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Lithium Inorganic solid Electrolytes

Zheng Zishan1,2**;Zhang Zhongtai1;Tang Zilong1;Shen Wanci1   

  1. (1. State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering,Tsinghua University, Beijing 100084, China; 2. Department of Chemistry, Zhangzhou Teachers College, Zhangzhou 100084, China)
  • Received:2002-01-01 Revised:2002-03-01 Online:2003-03-24 Published:2003-03-24
  • Contact: Zheng Zishan
全固态锂离子二次电池具有更大能量密度和更高的安全使用性能，在未来的电动汽车和蓄能电站上有很好的应用前景。本文对一些典型的锂无机固体电解质进行分类讨论，对它们的性能、结构和导电机理进行评述。这些固体电解质具有较高的离子导电率，是目前的研究热点。文章总结了影响其导电率的几个重要因素以及作为理想锂无机固体电解质的几个基本要求。
关键词： 锂离子电池, 锂快离子导体, 固体电解质
Solid state lithium ion batteries have the advantages of high energy capacity and safety. They have potential applications in electric vehicle and energy storage. Some typical lithium inorganic solid electrolytes were classified and discussed in this paper. Their electrochemical properties, structural characteristics and conduction mechanisms are reviewed. These electrolytes have been widely studied because of their high ionic conductivity. Some key influence factors on the ionic conductivity and some basic requirement for an ideal lithium solid electrolyte are concluded.
Key words: ithium ion batteries, lithium superionic conductors, solid electrolyte

中图分类号: 

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锂无机固体电解质*