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化学进展 2003, Vol. 15 Issue (01): 60- 前一篇   后一篇

• 综述与评论 •

新型后过渡金属烯烃聚合催化剂－－镍系烯烃聚合催化剂*

沈昊宇;金国新**   

  1. (复旦大学化学系 上海 200433)
  • 收稿日期:2001-12-01 修回日期:2002-02-01 出版日期:2003-01-24 发布日期:2003-01-24
  • 通讯作者: 金国新
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New Type Late Transition Metal Catalysts for Olefin Polymerization ——Nickel-based Olefin Polymerization Catalysts

Shen Haoyu;Jin Guoxin**   

  1. (Department of Chemistry,Fudan University, Shanghai 200433, China)
  • Received:2001-12-01 Revised:2002-02-01 Online:2003-01-24 Published:2003-01-24
  • Contact: Jin Guoxin
镍系烯烃聚合催化剂是近年来受到广泛关注的一类新型催化剂，是配位催化研究的热点之一。这类催化剂具有高催化活性、单活性中心和良好的分子剪栽性，可以在分子层次上实现烯烃聚合的分子设计与组装。本文介绍了镍系烯烃聚合催化剂的发展和研究概况，并评述了聚合特性及最新研究进展。
关键词： 镍系催化剂, 后过滤金属催化剂, 烯烃聚合反应
Nickel-baded olefin polymerization catalysts are new-type catalysts ,which have been attracted much attention in recent years .Nickel-based catalysts possess high catalytic activity for olefin polymerization ,with single active center and wonderful molecular molecular tailoring properties .in the present review ,the discovery ,development ,the polymerization characteristics and thde most significant studies on the nickel-based olefin polymerization catalysts are reported .
Key words: nikel-based catalysts, late transition metal catalysts, olefin polymerization

中图分类号: 

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[2] 张宝军,王延吉. 乙烯齐聚合成线性 α-烯烃镍系催化剂*[J]. 化学进展, 2006, 18(01): 51-58.