English
新闻公告
More
化学进展 2003, Vol. 15 Issue (01): 51- 前一篇   后一篇

• 综述与评论 •

FeZSM-5/N2O催化氧化苯制苯酚

季东;任通;张小明;索继栓*;丁勇   

  1. (中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室 兰州 730000)
  • 收稿日期:2001-12-01 修回日期:2002-03-01 出版日期:2003-01-24 发布日期:2003-01-24
  • 通讯作者: 索继栓

Catalytic Oxidation of Benzene to Phenol by FeZSM-5/N2O

Ji Dong;Ren Tong;Zhang Xiaoming;Suo Jishuan*;Ding Yong   

  1. ( State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academyof Sciences, Lanzhou 730000, China)
  • Received:2001-12-01 Revised:2002-03-01 Online:2003-01-24 Published:2003-01-24
  • Contact: Suo Jishuan
苯一步氧化制苯酚,是有机物氧化合成中富有挑战性的研究课题之一。该文着重论述了在FeZSM-5及其一系列沸石催化剂上,应用氧化亚氮作为氧化剂使苯直接氧化制苯酚的研究进展。这一系列催化剂体系的特殊之处在于通过氧化亚氮在沸石分子筛上的分解获得具有催化活性的a-氧。详细讨论了在沸石分子筛上形成特殊结构的铁氧化物作为催化活性中心这一观点。由于这种催化体系对苯直接氧化制苯酚的反应有着很高的选择性,因此,这种比较经济和安全的制备苯酚的方法引起了人们的广泛关注。
One step oxidation of benzene to phenol has been a challenging subject in organic synthesis.In this review,the focus is on the recent advances in gas-phase catalytic oxidation over zeolites using nitrous oxide as oxidant.The remarkbleness of this catalyst system lies in catalytic α-oxygen that is got from N2O decomposed over zeolites.The specific structure of Fe-containing active sites and the mechanism of the reaction were considered. This process of one step oxidation of phenol over FeZSM-5/N2O seems to be quite promising and promotes the development of new ecologically safe technologies for organic synthesis.

中图分类号: 

()

[ 1 ] Panov G I. CA TTECH, 2000, 40: 1
[ 2 ] Kruzhalov B D, Golovanenko B I. Phenol and Acetone Coproduction. Moscow , 1963: 200
[ 3 ] 邢其毅(Xing Q Y) , 徐瑞秋(Xu R Q ) , 周政(Zhou Z) , 裴伟伟(Pei W W ). 基础有机化学(第二版). 高等教育出版社, 1994
[ 4 ] Brownstain A M. Chemtech, September 1994, 58
[ 5 ] Tedder J M , Nechvatal A , Jubb A H. Basic Organic Chemistry, London: John Wiley, 1975
[ 6 ] Tomyuk K. Bull. Chem. Soc. Jpn. , 1994, 67: 2850—2855
[ 7 ] Hamado M. Aromailzkuic, 1994, 46 (1/2 ) : 373—377
[ 8 ] Kharitonov A S, Panov G I, Ione K G. U S 5 110 995,1992
[ 9 ] Nemeth L T. U S, 5 233 097, 1993
[ 10 ] Thungaraj A , Kumar R, Ratnasomy P. J. Appl. Catal. ,1990, 57: L 1—L 3
[ 11 ] Tuel A , Moussa Khouzamic S, Bentoarit Y, et al. J.Mol. Catal. , 1991, 68 (1) : 45—72
[ 12 ] Kirk-Othmer, Encyclopedia of Chemical Technology (3rd edition) , 17: 373
[ 13 ] Thangavj A , Kumar R, Ratnasamy P. J. Catal. , 1991,131: 294
[ 14 ] Bellussi G, Carati A , Clerici M , Millini R. J. Catal.1992, 133: 220
[ 15 ] Bellussi G, Rigutto M S. Stud. Surf. Sci. Catal. , 1994,85: 177
[ 16 ] DeVos D E, Buskens P L , Vanoppen D L , et al. Compr.Supramol. Chem. , 1996, 7: 674
[ 17 ] Sheldon R A , Arends I W C E, Lempers H E B. Catal.Today, 1998, 41: 387
[ 18 ] Marek L F, Hahn D A. The Catalytic Oxidation of Organic Compounds in the Vapour Phase. New York: The Chemical Catalog Company Inc. 1932
[ 19 ] Matsuda F, Kto K. Jpn. Kokai Tokyo Koho, JP 62 67,038 (Chem. Abstract, 1987, 107 No. 17, p. 674, No.154068t)
[ 20 ] Cao S C, et al. , Chin. J. Petrochem. Tech. , 1995, 10:708
[ 21 ] Iwamoto M , Matsukami K, Kagawa S. JP 58-146522,1982
[ 22 ] Iwamoto M , Matsukami K, Kagawa S. J. Phys. Chem. ,1983, 87: 903
[ 23 ] Suzuki E, Makashiro K, Ono Y. Chem. Soc. Jap. Chem.Commun. , 1988, 953
[ 24 ] Gubelmann M H, Tirel P J. FP 2 630 735, 1988
[ 25 ] Kharitonov A S, A lek sandrova T N , Vostrikova L A , et al. U SSR 1 805 127
[ 26 ] Yoshizawa K, Shiota Y, Yumura T, Yamabe T. J. Phys.Chem. B, 2000, 104: 734
[ 27 ] Kharitonov A S, Yartsev A I, Paukshtis E A , et al. React. Kinet. Catal. Lett. , 1988, 37: 7
[ 28 ] Gubelmann M , Tirel P. EP 341 165, 1989
[ 29 ] Gubelmann M , Tirel P. Fr 2 648 810, 1990
[ 30 ] Kharitonov A S, Romannikov V N , Panov G I, et al.U SSR Authorship Certificate, 4 673 039, 1989
[ 31 ] Kharitonov A S, Panov G I, Ione K G, et al. U S 5 110 995, 1992
[ 32 ] Gubelmann M , Tirel P. U S 5 001 280, 1991
[ 33 ] Gubelmann M , Popa J , Tirel P. U S 5 055 623, 1991
[ 34 ] Louis B, Reuse P, Kiwi-Minsker L , Renken A. Appl.Catal. A: General, 2001, 210: 103—109
[ 35 ] Ribera A , Arends I W C E, Devries S, Perez-Ramirez J ,et al. J. Catal. , 2000, 195: 287
[ 36 ] Panov G I, Kharitonov A S, Sobolev V I. App l. Catal.A , 1993, 98: 1
[ 37 ] Panov G I, Sheveleva G A , Kharitonov A S, et al. Appl.Catal. A , 1992, 82: 31
[ 38 ] Sobolev V I, Panov G I, Kharitonov A S, et al. J. Catal. ,1993, 139: 435
[ 39 ] Panov G I, Sobolev V I, Kharitonov A S. J. Mol. Catal. ,1990, 61: 85
[ 40 ] Panov G I, Uriarte A K, Rodkin M A , Sobolev V I.Catal. Today, 1998, 41: 365
[ 41 ] Lunsford J H. Catal. Rev. , 1973, 8: 135
[ 42 ] Che M , Tench A J. Adv. Catal. , 1982, 31: 77
[ 43 ] Che M , Tench A J. Adv. Catal. , 1983, 32: 1
[ 44 ] Iwamoto M , Hamada H. Catal. Today, 1991, 10: 57
[ 45 ] Chen L , Chen H Y, Lin J , Tan K L. Surface and Interface Analysis, 1999, 28: 115
[ 46 ] Dandekar A , Vannice M A. Appl. Catal. B: Environmental, 1999, 22: 179
[ 47 ] Li Y, Armor J N. Appl. Catal. B 1992, 1: L 21
[ 48 ] Leanza R, Rossetti I, Mazzola I, Forni L. Appl. Catal.A: General, 2001, 205: 93
[ 49 ] Sobolev V I, Kharitonov A S, Paukshtis Ye A , Panov G I. J. Mol. Catal. , 1993, 84: 117
[ 50 ] Panov G I, Sobolev V I, Dubkov K A , et al. React. Kinet.Catal. Lett. , 1997, 61 (2) : 251
[ 51 ] Huybrechts D R C, Parton R F, Jacobs P A. Stud. Surf.Sci. Catal. , 1991, 60: 225
[ 52 ] Burch R, Howitt C. Appl. Catal. A: General, 1992, 86(2) : 139
[ 53 ] Yoo J S, Sohall A R, Grimmer S S, Chin C F. Catal.Lett. , 1994, 29: 299
[ 54 ] Sobolev V I, Dubkov K A , Paukshtis Ye A , et al. Appl.Catal. A , 1996, 141: 185
[ 55 ] Kustov L M , Tarasov A L , Bogdan V I, Tyrlov A A , Fulmer J W. Catal. Toady, 2000, 61: 123
[ 56 ] Bogdan V I, Kustov L M , Batizat D B, et al. Stud. Surf.Sci. Catal. , 1995, 94: 635
[ 57 ] Zholobenko V L , Kustov L M , Kazansky V B. in Proceedings of the Ninth International Conference on Zeolites,Vol. 2, Butterworth, Montreal, 1992: 299
[ 58 ] Zholobenko V L , Senchenya I N , Kustov L M , Kazansky V B. Kinet. Catal. , 1991, 32: 151
[ 59 ] Shimokawabe M , Takahata N , Chuki T, Takezawa N.Reaction Kinetics and Catalysis Letters, 2000, 71 (2) : 313
[ 60 ] Kitajima N , Ito M , Fukui H, Morooka Y. J. Chem.Soc. , Chem. Commum. , 1991, 102
[ 61 ] Kharitonov A S, Sheveleva G A , Panov G I, et al. Appl.Catal. A. 1993, 98: 33
[ 62 ] Feng X, Hall W K. J. Catal. , 1997, 166: 368
[ 63 ] Voskoboinikov T V , Chen H Y, Sach tler W M H. Appl.Catal. B: Environmental, 1998, 19: 279
[ 64 ] Chen H Y, Wang X, Sachtler W M H. Appl. Catal. A:General, 2000, 195: 159
[ 65 ] Pasquone I. Catal. Today, 1987, 1: 297
[ 66 ] Sheldon R A. Catal. Today, 1987, 1: 351
[ 67 ] Perot G, Guisnet M. J. Mol. Catal. , 1990, 61: 173
[ 68 ] Ratnasamy P, Cummar R. Catal. Today, 1991, 9: 328
[ 69 ] Ione K G. Polyfunctional Catalysison Zeolites. Novosibirsk:Nauka. 1982
[ 70 ] Topsoe N , Joensen F, Derouane E D. J. Catal. , 1988,110: 404
[ 71 ] Rongsheng L , Wuyang Z, Daorong L , Quon W. Appl.Catal. , 1991, 71: 185

[1] 王乐壹, 李牛. 从铜离子、酸中心与铝分布的关系分析不同模板剂制备Cu-SSZ-13的NH3-SCR性能[J]. 化学进展, 2022, 34(8): 1688-1705.
[2] 施剑林, 华子乐. 无机纳米与多孔材料合成中的凝聚态化学[J]. 化学进展, 2020, 32(8): 1060-1075.
[3] 潘迪, 刘鹏, 张宏斌, 唐颐. 沸石的连续流动相合成[J]. 化学进展, 2020, 32(7): 873-881.
[4] 赵新红, 高向平, 郝志鑫, 张晓晓. 多级孔磷酸铝分子筛的合成、表征及催化应用[J]. 化学进展, 2016, 28(5): 686-696.
[5] 范功端, 林茹晶, 苏昭越, 许仁星. 沸石咪唑酯骨架材料用于水中污染物的去除[J]. 化学进展, 2016, 28(12): 1753-1761.
[6] 谢利娟, 石晓燕, 刘福东, 阮文权. 菱沸石在柴油车尾气NOx催化净化中的应用[J]. 化学进展, 2016, 28(12): 1860-1869.
[7] 历阳, 孙洪满, 王有和, 许本静, 阎子峰. 沸石分子筛的绿色合成路线[J]. 化学进展, 2015, 27(5): 503-510.
[8] 寇龙, 王有和, 彭鹏, 阎子峰. 介孔沸石分子筛的制备[J]. 化学进展, 2014, 26(04): 522-528.
[9] 彭鹏, 张占全, 王有和, Fazle Subhan, 阎子峰. 多级孔分子筛的制备与催化应用[J]. 化学进展, 2013, 25(12): 2028-2037.
[10] 李孟丽, 杨晓龙*, 唐立平, 熊绪茂, 任嗣利, 胡斌*. N2O的催化分解研究[J]. 化学进展, 2012, (9): 1801-1817.
[11] 陈立峰, 史静, 张亚红, 唐颐*. 核壳型沸石复合材料和反应器[J]. 化学进展, 2012, 24(07): 1262-1269.
[12] 杜晓明 李静 吴尔冬. 沸石吸附储氢研究进展[J]. 化学进展, 2010, 22(01): 248-254.
[13] 汪洋,马利勇,朱宁,陈丰秋,詹晓力. 分级孔沸石材料的合成、表征及其催化应用* [J]. 化学进展, 2009, 21(09): 1722-1733.
[14] 王聪,刘秀凤,崔瑞利,张宝泉. 沸石分子筛膜缺陷的形成及修复*[J]. 化学进展, 2008, 20(12): 1860-1867.
[15] 王德举,刘仲能,李学礼,谢在库. 介孔沸石材料*[J]. 化学进展, 2008, 20(05): 637-643.
阅读次数
全文


摘要

FeZSM-5/N2O催化氧化苯制苯酚