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化学进展 2002, Vol. 14 Issue (06): 438- 前一篇   后一篇

• 综述与评论 •

轴向手性膦氮配体及其在不对称催化合成中的应用

高爽;胡信全;郑卓*   

  1. 中国科学院大连化学物理研究所 大连 116023
  • 收稿日期:1900-01-01 修回日期:2002-04-01 出版日期:2002-11-24 发布日期:2002-11-24
  • 通讯作者: 郑卓
下载PDF ( 1437 ) 引用
导出 被引次数 ( 21 | 1 )

Application of Axially Chiral Phosphinamine Ligands in Asymmetric Catalysis

Gao Shuang;Hu Xinquan;Zheng Zhuo*   

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Received:1900-01-01 Revised:2002-04-01 Online:2002-11-24 Published:2002-11-24
  • Contact: Zheng Zhuo
本文较为详细地综述了轴向手性膦氮配体合成及其在不对称烯丙基取代反应、不对称1，4－共轭加成反应及不对称硼氢化反应中的应用。
关键词： 轴向手性, 膦氮配体, 不对称烯丙基取代反应, 不对称1,4-共轭加成反应, 不对称硼氢化反应
The progress in synthesis of chiral phosphinamine ligands is reviewed. Their applications in asymmetric allylic substitution, asymmetric 1, 4-conjugate addition and asymmetric hydroboration are described.
Key words: axial chirality, phosphinamine ligands, asymmetric allylic substitution, asymmetric 1,4-conjugate addition, asymmetric hydroboration

中图分类号: 

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