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化学进展 2002, Vol. 14 Issue (02): 141- 前一篇   后一篇

• 综述与评论 •

无机物表面引发聚合反应制备端接枝聚合物膜*

周峰;刘维民   

  1. 中国科学院兰州化学物理研究所固体润滑国家重点实验室 兰州 730000
  • 收稿日期:2001-03-01 修回日期:2001-07-01 出版日期:2002-03-24 发布日期:2002-03-24
  • 通讯作者: 周峰
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Surface-initiated Polymerization on Inorganic Substrates and Its Use to the Fabrication of End-grafted Polymer Films

Zhou Feng;Liu Weimin   

  1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
  • Received:2001-03-01 Revised:2001-07-01 Online:2002-03-24 Published:2002-03-24
  • Contact: Zhou Feng
无机物表面引发聚合反应是聚合物合成化学的又一新领域。分子自组装技术的发展使得各种类型的聚合反应都有转移到固体表面进行的可能。本文综述了无机物表面引发聚合反应用于制备高键合密度端接枝聚合物膜的研究进展，并对其今后的发展提出了见解。
关键词： 表面引发聚合反应, 引发剂-自组装分子, 自组装单分子层, 端接枝聚合物
Surface-initiated polymerization on the surface of inorganic substances has been considered as a new research field in polymer synthetic chemistry. Self-assembling techniques on the molecular level make nearly all kinds of polymerization to be carried out on the surface of inorganic substances possible. The surface-initiated polymerization and its use for the formation of end-grafted polymer films were reviewed. The authors' own opinions with respect to the future development of this research field were proposed.
Key words: surface-initiated polymerization, initiator-self-assembly molecules, self-assembled monolayers, end-grafted polymer films

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