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化学进展 2002, Vol. 14 Issue (01): 8- 前一篇   后一篇

• 综述与评论 •

手性金属Salen配合物在不对称催化中的应用*

孙伟;夏春谷**   

  1. 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室 兰州 730000
  • 收稿日期:2000-11-01 修回日期:2001-03-01 出版日期:2002-01-24 发布日期:2002-01-24
  • 通讯作者: 夏春谷
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Application of Chiral Metal-Salen Complexes in Asymmetric Catalysis

Sun Wei;Xia Chungu   

  1. State Key Laboratory of Oxo Synthesis & Selective Oxidation, Lanzhou Institute of Chemical Physcis, Chinese Academy of Sciences, Lanzhou 730000, China
  • Received:2000-11-01 Revised:2001-03-01 Online:2002-01-24 Published:2002-01-24
  • Contact: Xia Chungu
手性Salen金属配合物已在不对称催化中得到了广泛的应用。本文主要介绍了可溶性的手性金属Salen配合物在不对称催化反应中的应用以及手性金属Salen配合物固载化研究取得的进展。
关键词： 手性Salen金属配合物, 不对称催化, 不对称环氧化, 应用, 非官能化烯烃, 消旋化合物, 动力学拆分
hiral metalsalen complexes have been recognized as one of the most promising catalysts for various asymmetric reactions. This review summarizes the applications of soluble and solid-phase supported chiral metalsalen complexes in asymmetric reactions.
Key words: chiral metalsalen complexes, asymmetric catalysis, asymmetric epoxidation

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