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化学进展 2001, Vol. 13 Issue (06): 472- 前一篇   后一篇

• 综述与评论 •

第二代氨合成催化体系--钌系氨合成催化剂及其工业应用*

郑晓玲;魏可镁   

  1. 福州大学化肥催化剂国家工程研究中心 福州 350002

  • 收稿日期:2000-07-01 修回日期:2000-12-01 出版日期:2001-11-24 发布日期:2001-11-24
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The Second Generation Catalysis System for Ammonia Synthesis——Ruthenium-based Ammonia Synthesis Catalyst and Its Industrial Application

Zheng Xiaoling;Wei Kemei   

  1. National Engineering Research Center of Chemical Fertilizer Catalyst,Fuzhou University, Fuzhou 350002, China
  • Received:2000-07-01 Revised:2000-12-01 Online:2001-11-24 Published:2001-11-24
本文综述了第二代氨合成催化体系——钌系氨合成催化剂的研制、开发及工业应用情况。介绍了钌系氨合成催化剂的载体、促进剂、钌活性前身物对氨合成催化活性的影响。比较了钌系氨合成催化剂与铁系氨合成催化剂的反应机理与性能特点。新型氨合成催化工艺流程的成功开发为钌系氨合成催化剂的工业应用提供了有力的保障。
关键词： 钌催化剂, 铁催化剂, 氢抑制作用, 新型氨合成流程
Ruthenium catalysts are considered as the second generation catalysts for ammonia synthesis following iron catalysts. The article summarizes advances in research and industrial application of ruthenium based ammonia synthesis catalysts. Ruthenium catalysts are known to be quite sensitive to the nature of supports, promoters and precursors in ammonia synthesis. The different characterist ics and kinet ics between ruthenium catalyst and iron catalyst are described. Kellogg advanced ammonia p rocess(KAAP) supplies the strong support for industrial application of ruthenium catalysts.
Key words: ruthenium catalyst, iron catalyst, hydrogen inhibition, advanced ammonia synthesis process

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