English
往期目录
新闻公告
More
化学进展 2001, Vol. 13 Issue (03): 224- 前一篇   后一篇

• 综述与评论 •

“活性”/控制自由基聚合的研究进展

丘坤元;陈小平   

  1. 北京大学化学与分子工程学院高分子科学与工程系
  • 收稿日期:2000-05-01 修回日期:2000-08-01 出版日期:2001-05-24 发布日期:2001-05-24
下载PDF ( 5133 ) 引用
导出 被引次数 ( 16 )

Study of“Living” Controlled Radical Polymerization

Chen Xiaoping;Qiu Kunyuan   

  1. Department of Polymer Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
  • Received:2000-05-01 Revised:2000-08-01 Online:2001-05-24 Published:2001-05-24
本文对“活性” 控制自由基聚合的研究进展做了综述, 并讨论了其主要聚合引发体系的应用现状和前景。
关键词： “活性”自由基聚合, 引发转移终止剂, 2, 2, 6, 6-四甲基-1-哌啶氮氧自由基, 可逆加成-裂解链转移, 原子转移自由基聚合
This review focuses on the recent studies of“living” controlled radical polymerization. The applications and the prospects of the important polymerizat ion systems are also discussed.
Key words: “living”radical polymerization, iniferter, TEMPO, reversible addition fragmentation chaint ransfer, atomt ransfer radical polymerization

中图分类号: 

()

[ 1 ] Webster O W. Science, 1991, 251 (4996) : 887—893
[ 2 ] Szwarc M , Levy M , Milkovich R. J. Am. Chem. Soc. , 1956,78: 2656—2657
[ 3 ] Szwarc M. ACS Symp. Ser. , 1981, 166 (Anionic polymerization) : 1—15
[ 4 ] Morton M. Anionic Polymerization: Principles and Practice,New York: Academic Press, 1983
[ 5 ] Webster O W , Hertler W R, Sogah D Y, et al. J. Am. Chem.Soc. , 1983, 105 (17) : 5706—5708
[ 6 ] Miyamoto M , SawamotoM , Higashimura T. Macromolecules,1984, 17 (3) : 265—268
[ 7 ] Faust R, Kennedy J P. Polym. Bull. , 1986, 15 (4) : 317—323
[ 8 ] Wang J S, Jérodme R, Teyssié Ph. J. Phys. Org. Chem. ,1995, 8 (4) : 208—221
[ 9 ] Kobayashi S, Saegusa T. Ring Opening Polymerization ( eds.Ivin K J , Seagusa T) , New York: Elsevier, 1984
[ 10 ] Grubbs R H, Tumas W. Science, 1989, 243 (4893) : 907—915
[ 11 ] Schrock R R. Acc. Chem. Res. , 1990, 23 (5) : 158—165
[ 12 ] Masuda T, Yoshimura T, Fujimori J , Higashimura T. J.Chem. Soc. , Chem. Commun. , 1987, (23) : 1805—1806
[ 13 ] Doi Y, Velci S, Keii T. Macromolecules, 1979, 12 ( 5 ) :814—819
[ 14 ] Asano S, Aida T, Inoue S. J. Chem. Soc. , Chem. Commun. , 1985 (17) : 1148—1149
[ 15 ] Matyjaszewski K, Müller A H E. Polym. Prepr. , 1997, 38(1) : 6—9
[ 16 ] Daring T R, Davis T P, Fryd M , et al. J. Polym. Sci.Polym. Chem. , 2000, 38: 1706—1708; 1709—1752
[ 17 ] Matyjaszewski K, Gaynor S, Greszta D, Mardare D, Shigemoto T. J. Phys. Org. Chem. , 1995, 8 (4) : 306—315
[ 18 ] Otsu T, Yoshida M. Makromol. Chem. Rapid. Commun. ,1982, 3 (2) : 127—132
[ 19 ] Otsu T, Yoshida M , Tazaki T. Makromol. Chem. Rapid.Commun. , 1982, 3 (2) : 133—140
[ 20 ] Otsu T, Matsunaga T, Kuriyama A. Eur. Polym. J. , 1989,25 (7&8) : 643—650
[ 21 ] Otsu T, Matsumo to A. in Macromolecular Design, Concept and Practice (ed. Mishra M K). Polymer Frontiers International, New York, Chapter 12 (1994)
[ 22 ] Otsu T, Matsumo to A. Adv. Polym. Sci. , 1998, 166: 75—137
[ 23 ] Bledzki A , Braun D. Makromol. Chem. , 1981, 182 ( 4 ) :1047—1056
[ 24 ] Bledzki A , Braun D, Titzschkau K. Makromol. Chem. ,1983, 184: 745—754
[ 25 ] Qin S H, Qiu K Y, Sw ift G, et al. J. Polym. Sci. Polym.Chem. , 1999, 37: 4610—4615
[ 26 ] Qin S H, Qiu K Y, Westmoreland D G, et al. Polym.Prepr. , 2000, 41 (2) : 346—347
[ 27 ] Chen X P, Qiu K Y, Graham Swift, Westmoreland D G, Wu S. Eur. Polym. J. , 2000, 36 (8) : 1547—1554
[ 28 ] Nair C P R, Clouet G. Polymer, 1988, 29 (10) : 1909—1917
[ 29 ] Nair C P R, Clouet G. Macromolecules, 1990, 23 (5) : 1361—1369
[ 30 ] Tharanikkarasu K, Radhakrishnan G. Eur. Polym. J. , 1994,30 (12) : 1351—1355
[ 31 ] Tharanikkarasu K, Radhakrishnan G. J. Macromol. Sci. Pure Appl. Chem. , 1997, A 34 (4) : 559—571
[ 32 ] Yang X M , Qiu K Y. J. Macromol. Sci. -Pure Appl. Chem. ,1997, A 34 (2) : 315—325
[ 33 ] Yang X M , Qiu K Y. J. Appl. Polym. Sci. , 1996, 61 (3) :513—518
[ 34 ] 田士英(Tian S Y) , 董建华(Dong J H) , 丘坤元(Qiu K Y) , 高分子学报(Acta Polym. Sinica) , 1999, 5: 571—575
[ 35 ] Yang X M , Qiu K Y. J. Macromol. Sci. -Pure Appl.Chem. , 1997, A 34 (3) : 543—549
[ 36 ] Yang X M , Qiu K Y. J. Appl. Polym. Sci. , 1997, 64 (6) :1169—1174
[ 37 ] Yang X M , Qiu K Y. J. Macromol. Sci.-Pure Appl.Chem. , 1997, A 34 (6) : 991—1001
[ 38 ] Qin S H, Qiu K Y. Polym. Bull. , 2000, 44: 123—128
[ 39 ] Qin S H, Qiu K Y. J. Polym. Sci. , Po lym. Chem. , 2000,38: 2115—2120
[ 40 ] Georges M K, Veregin R P N , Kazmaier P M , Hamer G K.Macromolecules, 1993, 26 (11) : 2987—2988
[ 41 ] Veregin R P N , Odell P G, Michalak L M , Georges M K.Macromolecules, 1996, 29 (8) : 2746—2754
[ 42 ] Veregin R P N , Odell P G, Michalak L M , Georges M K.Macromolecules, 1996, 29 (10) : 3346—3352
[ 43 ] Hawker C J. J. Am. Chem. Soc. , 1994, 116 (24) : 11185—11186
[ 44 ] Hawker C J , Barcley G G, Orellana A , Dao J , Devonport W.Macromolecules, 1996, 29 (16) : 5245—5254
[ 45 ] Mansky P, Liu Y, Hung E, Russell T P, Hawker C J. Science, 1997, 275 (5305) : 1458—1460
[ 46 ] Mardare D, Matyjaszewski K. Macromolecules, 1994, 27(3) : 645—649
[ 47 ] Greszta D, Matyjaszewski K. Macromolecules, 1996, 29(24) : 7661—7670
[ 48 ] Hawker C J. Trends in Polymer Science, 1996, 4 (6) : 183—188
[ 49 ] Wan X H, Tu H L , Tu Y F, Zhang D, Sun L , Zhou Q F.Chinese J. Polym. Sci. , 1999, 17 (2) : 189—192
[ 50 ] Wan X H, Tu Y F, Zhang D, Zhou Q F. Chinese J. Polym.Sci. , 1998, 16 (4) : 377—380
[ 51 ] Wan X H, Tu Y F, Zhang D, Zhou Q F. Polym. Inter. ,2000, 49 (3) : 243—247
[ 52 ] He J P, Li L , Yang Y L. Macromolecules, 2000, 33 (6) :2286—2289
[ 53 ] Li C M , He J P, Li L , Cao J Z, Yang Y L. Macromolecules,1999, 32 (21) : 7012—7014
[ 54 ] Fisher A , Brembilla A , Lochon P. Macromolecules, 1999, 32(19) : 6069—6072
[ 55 ] Listigovers N A , Georges M K, Odell P G, Keoshkerian B.Macromolecules, 1996, 29 (27) : 8992—8993
[ 56 ] Benoit D, Grimald S, Finet J P, Tordo P, Fontanille M ,Gnanou Y. Controlled Radical Polymerization ( ed. Matyjaszewski K) , ACS Symp. Ser. 685. Washington DC: American Chemistry Society, 1998, Chapter14
[ 57 ] Goto A , Fukuda T. Macromolecules, 1999, 32 (3) : 618—623
[ 58 ] Li D, Brittain W J. Macromolecules, 1998, 31 (12) : 3852—3855
[ 59 ] Keoshkerian B, Georges M K, Boilsboissier D. Macromolecules, 1995, 28 (18) : 6381—6382
[ 60 ] Gabaston L I, Jackson R A , Armes S P. Macromolecules,1998, 31 (9) : 2883—2888
[ 61 ] Marestin C, Nol C, Guyot A , Claverie J. Macromolecules,1998, 31 (12) : 4041—4044
[ 62 ] Malmstrm E E, Hawker C J. Macromol. Chem. Phys. ,1998, 19 (6) : 923—935
[ 63 ] Fréchet J M J , Henmi M , Gitsov I, Aaoshima S, Leduc M R,Grubbs R B. Science, 1995, 269: 1080—1083
[ 64 ] Hawker C J , Fréchet J M J , Grubbs R B, Dao J. J. Am.Chem. Soc. , 1995, 117 (43) : 10763—10764
[ 65 ] Chong (Bill) Y K, Ercole F, Moad G, Rizzardo E, Thang S H. Macromolecules, 1999, 32 (21) : 6895—6903
[ 66 ] Wayland B B, Poszmilk G, Mukerjee S L. J. Am. Chem.Soc. , 1994, 116 (17) : 7943—7944
[ 67 ] Mardare D, Matyjaszewski K. Polym. Prepr. , 1994, 35 (2) :555—556
[ 68 ] Chiefari J , Chong (Bill)Y K, Erco le F, Rizzardo E, Moad G,Thang S H, et al. Macromolecules, 1998, 31 (16) : 5559—5562
[ 69 ] Mayadunne R T A , Rizzardo E, Chiefari J , Chong (Bill)Y K,Moad G, Thang S H. Macromolecules, 1999, 32 ( 21 ) :6977—6980
[ 70 ] Chong (Bill) Y K, Le T P T, Moad G, Rizzardo E, Thang S H. Macromolecules, 1999, 32 (6) : 2071—2074
[ 71 ] Wang J S, Matyjaszewski K. J. Am. Chem. Soc. , 1995, 117(20) : 5614—5615
[ 72 ] Wang J S, Matyjaszewski K. Macromolecules, 1995, 28 (23) :7901—7910
[ 73 ] Kato M , Kamigaito M , Sawamoto M , Higashimura T.Macromolecules, 1995, 28 (5) : 1721—1723
[ 74 ] Percec V , Barboiu B. Macromolecules, 1995, 28 ( 23 ) :7970—7972
[ 75 ] Matyjaszewski K, Jo M S, Paik H, Shipp D A. Macromolecules, 1999, 32 (20) : 6431—6438
[ 76 ] Patten T E, Xia J , Abernathy T, Matyjaszewski K. Science,1996, 272: 866—868
[ 77 ] Coca S, Jasieczek C B, Beers K L , Matyjaszewski K. J.Polym. Sci. , Polym. Chem. , 1998, 36 (9) : 1417—1424
[ 78 ] Beers K L , Boo S, Gaynor S G, Matyjaszewski K. Macromolecules, 1999, 32 (18) : 5772—5776
[ 79 ] Zhang X, Xia J , Matyjaszewski K. Macromolecules, 1998, 31(15) : 5167—5169
[ 80 ] Xia J , Zhang X, Matyjaszewski K. Macromolecules, 1999, 32(10) : 3531—3533
[ 81 ] Huang X, Wirth M J. Macromolecules, 1999, 32 (5) : 1694—1696
[ 82 ] Teodorescu M , Matyjaszewski K. Macromolecules, 1999, 32(15) : 4826—4831
[ 83 ] Roos S G, Müller A H E. Macromolecules, 1999, 32 (25) :8331—8335
[ 84 ] Arehart S V , Matyjaszewski K. Macromolecules, 1999, 32(7) : 2221—2231
[ 85 ] Chen G Q , Wu Z Q , Wu J R, Li Z C, Li F M. Macromolecules, 2000, 33 (2) : 232—234
[ 86 ] Wang J S, Greszta D, Matyjaszewski K. Abstract of PM SE Division, American Chemical Society, Annual Meeting,Chicogo, Septemper 1995, 416
[ 87 ] Nakagawa Y, Gaynor S G, Matyjaszewski K. Polym. Prepr. ,1996, 37 (1) : 577—578
[ 88 ] Zhang X, Matyjaszewski K. Macromolecules, 1999, 32 (6) :1763—1766
[ 89 ] Li Z C, Liang Y Z, Li F M. Chem. Commun. , 1999, 16:1557—1558
[ 90 ] Pairk H, Teodorescu M , Xia J , Matyjaszewski K. Macromolecules, 1999, 32 (21) : 7023—7031
[ 91 ] Liu Y, Wang L , Pan C. Macromolecules, 1999, 32 ( 25) :8301—8305
[ 92 ] A shfo rd E J , N aldi V , O’Dell R, et al. Chem. Commn. ,1999: 1285—1286
[ 93 ] 傅志峰(Fu Z F) , 石艳(Shi Y) , 焦书科(Jiao S K) , 黄明智(Huang M Z) , 高分子学报(Acta Polym. Sinica) , 1999, 6:692—696
[ 94 ] Gaynor S G, Matyjaszewski K. Macromolecules, 1997, 30(14) : 4241—4245
[ 95 ] Gao B, Chen X, Iván B, Kops J , Batsberg W. Polym. Bull. ,1997, 39 (5) : 559—565
[ 96 ] Jankova K, Chen X, Kops J , Batsberg W. Macromolecules,1998, 31 (2) : 538—541
[ 97 ] Zhang Z B, Ying S K, Shi Z Q. Polymer, 1999, 40 ( 5) :1341—1345
[ 98 ] Zhang Z B, Ying S K, Shi Z Q. Polymer, 1999, 40 ( 19) :5439—5444
[ 99 ] Kasko A M , Heintz A M , Pugh C. Macromolecules, 1998,31 (2) : 256—271
[ 100 ] Weimer M W , Fréchet J M J , Gitsov I. J. Polym. Sci. ,Po lym. Chem. , 1998, 36 (6) : 955—970
[ 101 ] Gaynor S, Edelman S, Matyjaszewski K. Macromolecules,1996, 29 (3) : 1079—1081
[ 102 ] Coca S, Matyjaszewski K. Macromolecules, 1997, 30 (9) :2808—2810
[ 103 ] Kajiwara A , Matyjaszewski K. Macromolecules, 1998, 31(11) : 3489—3493
[ 104 ] Liu B, Liu F, Luo N , Ying S K, Liu Q. Chinese J. Polym.Sci. , 2000, 18 (1) : 39—43
[ 105 ] Xu Y J , Pan C Y. J. Polym. Sci. , Polym. Chem. , 2000, 38(2) : 337—344
[ 106 ] Xu Y J , Pan C Y, Tao L. J. Polym. Sci. , Polym. Chem. ,2000, 38 (3) : 436—443
[ 107 ] Xia J , Matyjaszewski K. Macromolecules, 1997, 30 ( 25) :7697—7700
[ 108 ] DiRenzo G M , Messerschmidt M , Mülhaupt R. Macromol.Rapid. Commun. , 1998, 19: 381—384
[ 109 ] Xia J , Matyjaszewski K. Macromolecules, 1999, 32 ( 8) :2434—2437
[ 110 ] Haddleton D M , Kukulj D, Duncalf D J , Heming A M ,Shooter A J. Macromolecules, 1998, 31 (16) : 5201—5205
[ 111 ] Xia J , Gaynor S G, Matyjaszewski K. Macromolecules,1998, 31 (16) : 5958—5959
[ 112 ] Wang X S, Luo N , Ying S K. Polymer, 1999, 40 ( 14) :4157—4161
[ 113 ] Haddleton D M , Duncalf D J , Kukulj D, Heming A M ,Shooter A , Clark A J. J. Mater. Chem. , 1998, 8 ( 7) :1525—1532
[ 114 ] Kotani Y, Kato M , Kamigaito M , Sawamoto M. Macromolecules, 1996, 29 (22) : 6979—6982
[ 115 ] Sawamoto M , Kamigaito M. Polym. Prepr. , 1998, 39 (1) :625.
[ 116 ] Nishikawa T, Kamigaito M , Sawamoto M. Macromolecules,1999, 32 (7) : 2204—2209
[ 117 ] Senoo M , Kotani Y, Kamigaito M , Sawamoto M. Macromolecules, 1999, 32 (24) : 8005—8009
[ 118 ] Matyjaszewski K, Wei M , Xia J , McDermott N E. Macromolecules, 1997, 30 (26) : 8161—8164
[ 119 ] Wang J S, Matyjaszewski K. Macromolecules, 1995, 28(22) : 7572—7573
[ 120 ] Xia J , Matyjaszewski K. Macromolecules, 1997, 30 ( 25) :7692—7696
[ 121 ] Xia J , Matyjaszewski K. Macromolecules, 1999, 32 ( 16) :5199—5202
[ 122 ] Zhu S M , Wang W X, Tu W P, Yan D Y. Acta Polymerica,1999, 50 (7) : 267—269
[ 123 ] Qiu J , Gaynor S G, Matyjaszewski K. Macromolecules,1999, 32 (9) : 2872—2875
[ 124 ] 万小龙(Wan X L ) , 应圣康(Ying S K) , 高分子学报(Acta Polym. Sinica) , 2000, 1: 27—31
[ 125 ] Moineau G, Dubois Ph, Jérodme R, Senninger T, Teyssié Ph. Macromolecules, 1998, 31 (2) : 545—547
[ 126 ] Chen X P, Qiu K Y. Polymer International, 2000, 49:1529—1538
[ 127 ] Chen X P, Qiu K Y. Chinese J. Polym. Sci. ( in English) ,2000, 18 (2) : 149—153
[ 128 ] Chen X P, Qiu K Y. Macromolecules, 1999, 32: 8711—8715
[ 129 ] Chen X P, Qiu K Y. J. Appl. Polym. Sci. , 2000, 77:1607—1613
[ 130 ] Qin D Q , Qin S H, Qiu K Y. J. Polym. Sci. , Polym.Chem. , 2000, 38 (1) : 101—107
[ 131 ] 秦东奇(Qin D Q ) , 钦曙辉(Qin S H) , 丘坤元(Qiu K Y). 高等学校化学学报(Chemical J. Chinese Universities) , 2000,21: 650—652
[ 132 ] Qin D Q , Qin S H, Chen X P, Qiu K Y. Polymer, 2000,41: 7347—7353
[ 133 ] Chen X P, Qiu K Y. Chem. Commun. , 2000: 233—234
[ 134 ] Chen X P, Qiu K Y. Chem. Commun. , 2000: 1403—1404
[1] 李佳烨, 张鹏, 潘原. 在大电流密度电催化二氧化碳还原反应中的单原子催化剂[J]. 化学进展, 2023, 35(4): 643-654.
[2] 王丹丹, 蔺兆鑫, 谷慧杰, 李云辉, 李洪吉, 邵晶. 钼酸铋在光催化技术中的改性与应用[J]. 化学进展, 2023, 35(4): 606-619.
[3] 刘雨菲, 张蜜, 路猛, 兰亚乾. 共价有机框架材料在光催化CO2还原中的应用[J]. 化学进展, 2023, 35(3): 349-359.
[4] 顾顺心, 姜琴, 施鹏飞. 发光铱(Ⅲ)配合物抗肿瘤活性研究及应用[J]. 化学进展, 2022, 34(9): 1957-1971.
[5] 薛宗涵, 马楠, 王炜罡. 大气中的单环芳香族硝基化合物[J]. 化学进展, 2022, 34(9): 2094-2107.
[6] 贾斌, 刘晓磊, 刘志明. 贵金属催化剂上氢气选择性催化还原NOx[J]. 化学进展, 2022, 34(8): 1678-1687.
[7] 范倩倩, 温璐, 马建中. 无铅卤系钙钛矿纳米晶:新一代光催化材料[J]. 化学进展, 2022, 34(8): 1809-1814.
[8] 夏博文, 朱斌, 刘静, 谌春林, 张建. 电催化氧化制备2,5-呋喃二甲酸[J]. 化学进展, 2022, 34(8): 1661-1677.
[9] 王慧悦, 胡欣, 胡玉静, 朱宁, 郭凯. 酶催化原子转移自由基聚合[J]. 化学进展, 2022, 34(8): 1796-1808.
[10] 高文艳, 赵玄, 周曦琳, 宋雅然, 张庆瑞. 提高非均相芬顿催化活性策略、研究进展及启示[J]. 化学进展, 2022, 34(5): 1191-1202.
[11] 李振兴, 骆支旺, 王平, 余振强, 陈尔强, 谢鹤楼. 发光液晶高分子:分子构筑、结构与性能及其应用[J]. 化学进展, 2022, 34(4): 787-800.
[12] 赵洁, 邓帅, 赵力, 赵睿恺. 湿气源吸附碳捕集: CO2/H2O共吸附机制及应用[J]. 化学进展, 2022, 34(3): 643-664.
[13] 庞欣, 薛世翔, 周彤, 袁蝴蝶, 刘冲, 雷琬莹. 二维黑磷基纳米材料在光催化中的应用[J]. 化学进展, 2022, 34(3): 630-642.
[14] 吴巧妹, 杨启悦, 曾宪海, 邓佳慧, 张良清, 邱佳容. 纤维素基生物质催化转化制备二醇[J]. 化学进展, 2022, 34(10): 2173-2189.
[15] 白文己, 石宇冰, 母伟花, 李江平, 于嘉玮. Cs2CO3辅助钯催化X—H (X=C、O、N、B)官能团化反应的理论计算研究[J]. 化学进展, 2022, 34(10): 2283-2301.