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化学进展 2001, Vol. 13 Issue (03): 192- 前一篇   后一篇

• 综述与评论 •

均相催化多相化新进展--氟两相体系

鲁福身;晁建平;杨春育   

  1. 北京石油化工学院化工系
  • 收稿日期:2000-04-01 修回日期:2000-09-01 出版日期:2001-05-24 发布日期:2001-05-24

Current Development in the Heterogenization of Homogeneous Catalysis——Fluorous Biphase System

Lu Fushen;Chao Jianping;Yang Chunyu   

  1. Chemical Department, Beijing Institute of Petrochemical Technology, Beijing 102600, China
  • Received:2000-04-01 Revised:2000-09-01 Online:2001-05-24 Published:2001-05-24
氟两相体系实现了均相催化多相化, 可以方便地分离溶解在PFC 中的催化剂。本文综述了氟两相体系及氟合成领域, 包括氟溶配体、催化剂和反应物等方面的最新进展。对氟两相体系在烯烃的氢甲酰化反应、硼氢化反应以及其它有机反应中的广泛应用作了讨论。
The FBS (fluorous biphase system ) makes homogeneous catalysis and heterogeneous separation possible and easy to separate the catalysts dissolved in PFC (perfluo rocarbons). Current developments in the chemistry of FBS and fluorous syntheses, including fluorous soluble ligands, catalysts and reagents are summarized. Numerous applications of FBS in hydroform ylation, hydroboration and other organic reactions are also discussed.

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