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化学进展 2001, Vol. 13 Issue (01): 33- 前一篇   后一篇

• 综述与评论 •

修饰型多相手性催化剂在不对称合成中的应用

陈新滋;吕士杰;李晓东   

  1. 香港理工大学应用生物与化学科技系;中科院兰州化学物理所
  • 收稿日期:1999-12-01 修回日期:2000-02-01 出版日期:2001-01-24 发布日期:2001-01-24
  • 通讯作者: 吕士杰
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导出 被引次数 ( 16 | 4 )

The Application of Modified Heterogeneous Chiral Catalysts in Asymmetric Synthesis

Li Xiaodong;Lü Shijie;Chan Albert SC   

  1. State KeyLaboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China Department of Applied Biology and Chemical Technology,HongKong Polytechnic University, HongKong, China"
  • Received:1999-12-01 Revised:2000-02-01 Online:2001-01-24 Published:2001-01-24
  • Contact: Lü Shijie
本文评述了修饰型多相手性催化剂在不对称合成中的应用。按照不同的制备方法及催化反应对一些多相催化体系进行了归类总结, 包括过渡金属手性配合物的固相化、修饰型手性固体催化剂、手性分子筛及嵌入型粘土手性催化剂。对酒石酸及金鸡纳碱修饰型金属催化剂的反应机理也进行了探讨。
关键词： 不对称合成, 多相催化, 固相化, 手性修饰, 手性分子筛, 嵌入型粘土手性催化
The application of modified heterogeneous chiral catalysts in asymmetric synthesis is described in this review. Several types of heterogeneous catalytic systems, including immobilized transition metal complexes, chirally modified metal catalys s, chiral zeolite and clay2intercalated chiral catalysts, are summarized according to different preparative methods and catalytic reactions. The reaction mechanism intart rate modified catalysts and cinchona modified catalysts are also discussed.
Key words: asymmetric synthesis, heterogeneous catalysis, immobilization, chiral modification, chiral zeolite, clay2intercalated chiral catalysts

中图分类号: 

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