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化学进展 2001, Vol. 13 Issue (01): 19- 前一篇   后一篇

• 综述与评论 •

钛硅催化材料的研究进展Ⅰ.钛硅混合氧化物的制备与催化性能

郭新闻;王祥生;张义华   

  1. 大连理工大学
  • 收稿日期:2000-01-01 修回日期:2000-03-01 出版日期:2001-01-24 发布日期:2001-01-24
下载PDF ( 1383 ) 引用
导出 被引次数 ( 83 | 9 )

Development of Titanium Silicon Catalytic Materials.Preparation of Titania-Silica Mixed Oxides and Its Catalytic Properties

Zhang Yihua;Wang Xiangsheng;Guo Xinwen   

  1. Lab of Comprehensive Utilization of Carbonaceous Resources,Dalian University of Technology, Dalian 116012, China
  • Received:2000-01-01 Revised:2000-03-01 Online:2001-01-24 Published:2001-01-24
钛硅催化材料的发展为研究有机选择氧化反应和开发环境友好化工工艺提供了新途径。钛硅混合氧化物由于制备简单、可操作性强等优点, 引起了人们的广泛重视。本文综述了钛硅混合氧化物的制备研究进展及其在催化有机选择氧化方面的应用, 讨论了制备方式、干燥方法、钛含量、表面修饰等影响钛硅混合氧化物性质和催化性能等的关键因素, 并展望了其应用前景。
关键词： 钛硅混合氧化物, 溶胶凝胶法, 环氧化反应
Titanium silicon catalytic materials gives new ways for the studies of the catalytic oxidizing reactions and the exploitation of the environmental benign chemical engineering processes. Titan ia2silica mixed oxides has at tracted more at tention because of its tailor preparing method and the easy operating process. This article summarizes the preparation of titania2silica mixed oxides. The factors effecting on the character and catalytic properties of the materials,such as preparing method,drying method, content of titanium and surface modification, as well as the prospect of application have been discussed.
Key words: titania2silica mixed oxides, sol2gel method, epoxidation

中图分类号: 

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[ 1 ] U. S. Patent, 3 923 843, 1975; Brit. Patent, 1 249 079, 1971
[ 2 ] Sharpless K B, Woodard S S, Finn M G. Pure Appl. Chem. ,1983, 55: 1823- 1836
[ 3 ] Sohn J R, Jang H J. J. Catal. , 1991, 132: 563- 565
[ 4 ] Lange C, De Caro D, Gamez A. et al. Langmuir, 1999, 15(16) : 5333- 5338
[ 5 ] Kamiya K, Sakka S. J. Mater. Sci. , 1980, 15 (11) : 2937-2939
[ 6 ] Breval E, Deng Z, Pantano C G. J. Non-Cryst. Solids, 1990,125: 50- 57
[ 7 ] Van der Pool A J H P, Van Hoof J H C. Appl. Catal. A ,1992, 92: 93- 111
[ 8 ] Jokinen M , Patsi M , Rahiala H J. Biomedical Materials Research, 1998, 42 (2) : 295- 302
[ 9 ] Mizukami F, Matsuzaki S Y, Furukori K, et al. J. Chem.Soc. Chem. Commun. , 1986, 678- 679
[ 10 ] Toba M , Mizukami F, Niwa S. J. Chem. Soc. Chem.Commun. , 1990, 1211- 1212
[ 11 ] Aizawa M , Nosaka Y, Fujii N. J. Non-Cyst. Solids, 1991,128: 77- 85
[ 12 ] Nakabayashi H. Bull. Chem. Soc. Jpn. , 1992, 65 (3) : 914-916
[ 13 ] Hayashi T, Yamada T, Saito H. J. Mater. Sci. , 1983, 18:3137- 3142
[ 14 ] Yamane M , Inoue S, Nakazawa K. J. Non-Cryst. Solids,1982, 48 (1) : 153- 159
[ 15 ] Brinker Y C J. J. Non-Cryst. Solids, 1988, 100: 31- 50
[ 16 ] Neumann R, Levin-Elad M. J. Catal. , 1997, 166: 206- 217
[ 17 ] Ying J Y, Benziger J B, Narrotsky A. J. Am. Ceram. Soc. ,1993, 76 (10) : 2571- 2582
[ 18 ] Hench L L , West J K. Chem. Rev. , 1991, 90: 33- 72
[ 19 ] Brinker C J. J. Non-Cryst. Solids, 1985, 70: 301- 322
[ 20 ] 余桂郁(Yu G Y) , 杨南如(Yang N R ). 硅酸盐通报(Bull.Chin. Silicate Soc. ) , 1993, 6: 60- 66
[ 21 ] Niwa S, Mizukami F, Isoyama S, et al. J. Chem. Technol.Biotechnol. , 1986, 36: 236- 246
[ 22 ] Mizukami F, Niwa S, et al. J. Mol. Catal. , 1994, 91: 277-289
[ 23 ] Dutoit D C M , Schneider M , Baiker A. J. Catal. , 1995, 153:165- 176.
[ 24 ] Lacourse C W , Kim S. Ceram. Eng. Sci. Proc. , 1987, 8:1129- 1134
[ 25 ] Shelden R A. J. Mol. Catal. , 1980, 7 (1) : 107- 126
[ 26 ] Tanabe K. Catalysis Science and Technology. Berlin:Springer, 1981, 231
[ 27 ] Liu Z, Tabora J , Davis R J. J. Catal. , 1994, 149: 117- 126
[ 28 ] Liu Z, Davis R J. J. Phys. Chem. , 1994, 98: 1253- 1261
[ 29 ] Odenbrand C U , Brandin J G, Busca G. J. Catal. , 1992,135: 505- 517
[ 30 ] No tariB. A dv. Catal. , 1996, 41: 253- 334
[ 31 ] Scherer G. J. Non-Cryst. Solids, 1988, 100: 77- 92
[ 32 ] Scherer G. J. Am. Ceram. Soc. , 1990, 73 (1) : 3- 14
[ 33 ] Deshpande R, Hua D, Smith D M , Brinker C J. J. Non Crsyt. Solids, 1992, 144: 32- 44
[ 34 ] Schneider M , Baiker A. Encyclopedia of Advanced Materials,Vol. 1, Oxford: Pergamon Press, 1994
[ 35 ] Cogliati G, Guglielmi M , Che T M , et al. Mater. Res. Soc.Symp. Proc. , 1990, 180: 329- 334
[ 36 ] Brntigam U , Meyer K, Bürger H, EUROGEL ’91.Am sterdam: Elsevier, 1992, 335
[ 37 ] Matsuda A , Kogurve T, Matsuno Y, et al. J. Am. Ceram.Soc. , 1993, 76 (11) : 2899- 2903.
[ 38 ] Müller C A , Maciejewski M , Mallat T, Baiker A. J. Catal. ,1999, 184: 280- 293
[ 39 ] Kochkar H, Figueras F. J. Catal. , 1997, 171: 420- 430
[ 40 ] Klein S, Maier W F. Angew. Chem. , 1996, 35 (19) : 2230-2233
[ 41 ] Itoh M , Hattori H, Tanabe K. J. Catal. , 1974, 35: 225-231
[ 42 ] Klein S, Thorimbert S, Maier W F. J. Catal. , 1996: 163,476- 488
[ 43 ] Corma A , Camblor M A , Esteve P, et al. J. Catal. , 1994,145: 151- 157
[ 44 ] Neumann R, Chava M , Levin M. J. Chem. Soc. , Chem.Commun. , 1993, 1685- 1686
[ 45 ] Khouw C B, Li H X, Darrt C B. Catalytic Selective Oxidation, ACS Symp. Ser. , Vol. 523. Washington, DC,1993, 273
[ 46 ] Hutter R, Mallat T, Baiker A. J. Catal. , 1995, 153: 177-189
[ 47 ] Hutter R, Mallat T, Baiker A. J. Catal. , 1995, 157: 665-675
[ 48 ] Hutter R, Mallat T, Peterhans A. J. Mol. Catal. A: Chem.1999, 138: 241- 247
[ 49 ] Dusi M , Mallat T, Baiker A. J. Mol. Catal. A: Chem.1999, 138: 15- 23
[ 50 ] Cativiela J M , Fraile J I, Garcia J A , et al. J. Mol. Catal. A:Chem. 1996, 112: 259- 267
[ 51 ] Kumar R, Pais G C G, Pandey B, Kumar P. J. Chem. Soc. ,Chem. Commun. , 1995, 1315- 1316
[ 52 ] Keshavaraja A , Ranaswamy V , Soni H S, et al. J. Catal. ,1995, 157: 501- 511
[ 53 ] 王洪林(Wang H L ). 博士论文, 大连理工大学, 1999
[ 54 ] 辛勤, 吴自力. 第七届全国青年催化学术会议论文集, 1999,3- 4
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