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化学进展 2001, Vol. 13 Issue (01): 1-   后一篇

• 综述与评论 •

带同种电荷胶体颗粒间的相互吸引*

张波;刘洪来**;胡英   

  1. 华东理工大学化学系 上海 20237
  • 收稿日期:2000-01-01 修回日期:2000-02-01 出版日期:2001-01-24 发布日期:2001-01-24
  • 通讯作者: 刘洪来
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Attraction between Like-Charge Particles

Zhang Bo;Liu Honglai**;Hu Ying   

  1. Department of Chemistry, East China University of Science and Technology, Shanghai 200237, China
  • Received:2000-01-01 Revised:2000-02-01 Online:2001-01-24 Published:2001-01-24
  • Contact: Liu Hong lai
带同种电荷颗粒间存在静电吸引是当前胶体科学领域的一大研究热点, 也是颇有争议的一个课题。经典的DLVO 理论认为, 电解质溶液中一对孤立、带同种电荷的球型胶粒将表现出纯粹的库仑排斥。以往的实验事实也证实了DLVO 理论的正确性。然而, 近十几年来的实验研究表明, 在一定条件下, 同性颗粒间的有效相互作用势能可能表现出静电吸引。对此, 至今还没有一个令人信服的理论描述, 甚至连其产生根源也未有定论。带同种电荷颗粒的静电吸引将是一个很值得探讨的问题。
关键词： 胶体颗粒, 静电作用, 实验测定, 理论模型, 计算机模拟
The existence of long2range electro static attraction between particles with like charge is one of the great current cont roversies of colloidal science. The classicalDLVO theory predicts that an isolated pair of like2charged colloidal spheres in elect rolyte should experience apurely repulsive Coulombic interaction. Direct measurements of such interactions have shown excellent agreement with DLVO theory.Recent experiments, however, provide evidence that the effective in terparticle potential show a long2range attraction under certain condition s. A satisfactory theoretical explanation for this behavio r has proven elusive. There are even some doubts about its origin. Further experimental and theoretical investigations of this surprising phenomenon could be very rewarding.
Key words: colloidal particle, electrostatic in teraction, experimental measurement, theoretical model, computer simulation

中图分类号: 

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